Chem. Commun.

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Towards a methanol economy based on homogeneous catalysis: methanol to H2 and CO2 to methanol

7 April, 2015 - 07:54

Chem. Commun., 2015, 51,6714-6725
DOI: 10.1039/C4CC09471A, Feature ArticleE. Alberico, M. Nielsen
Homogeneous catalytic systems are able to promote either the dehydrogenation of aqueous methanol to hydrogen and CO2 or the hydrogenation of CO2 to methanol and water. Here, we review and discuss these recent developments in this field.
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9,9[prime or minute]-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

7 April, 2015 - 07:54

Chem. Commun., 2015, 51,6734-6737
DOI: 10.1039/C4CC10104A, CommunicationTatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada
Stable anthroxyl radical with a half-life over 10 days in solution.
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A green route to fabricate MoS2 nanosheets in water-ethanol-CO2

7 April, 2015 - 07:54

Chem. Commun., 2015, 51,6726-6729
DOI: 10.1039/C5CC00106D, CommunicationYuhang Qi, Nan Wang, Qun Xu, Hongxiang Li, Pengshang Zhou, Xin Lu, Guoqiang Zhao
The ultrathin and highly crystalline MoS2 nanosheets fabricated via a green route can be directly used as a label for bioimaging.
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One-pot synthesis of sub-3 nm gold nanoparticle networks connected by thio-based multidentate fullerene adducts

7 April, 2015 - 07:54

Chem. Commun., 2015, 51,6730-6733
DOI: 10.1039/C5CC00204D, CommunicationGuillaume Rousseau, Christophe Lavenn, Luis Cardenas, Stephane Loridant, Yanhui Wang, Uwe Hahn, Jean-Francois Nierengarten, Aude Demessence
Self-assembly of homogeneous ultra-small gold nanoparticles thanks to the design of a new hexaadduct fullerene bearing 12 thiocyanate functions.
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