Chem. Commun.

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Lewis Acid-free and Phenolate-based Magnesium Electrolyte for Rechargeable Magnesium Batteries

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC01225B, CommunicationBaofei Pan, Junjie Zhang, JINHUA HUANG, Jack Vaughey, Lu Zhang, Sang-Don Han, Anthony K Burrell, Zhengcheng Zhang, Chen Liao
A novel Lewis acid-free and phenolate-based magnesium electrolyte has been established. The excellent reversibility and stability of this electrolyte in battery cycling render this novel Lewis acid-free synthetic approach as...
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One-pot synthesis of doxorubicin-loaded multiresponsive nanogels based on hyperbranched polyglycerol

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC00644A, CommunicationAna Sousa-Herves, Stefanie Wedepohl, Marcelo Calderon
Doxorubicin-loaded nanogels with multiresponsive properties are prepared using hyperbranched polyglycerol as a biocompatible scaffold. The nanogels are synthesized in a single step combining free-radical polymerization and a mild nanoprecipitation technique....
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Uthrene, a Radically New Molecule?

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC01276G, CommunicationManuel Melle-Franco
We have studied uthrene with a large range of quantum chemical models. Uthrene is predicted to be naturally twisted and to possess a triplet ground state, making it the smallest...
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A Cyclic Octithiophene Containing [small beta],[small beta]'-Linkages

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC00570A, CommunicationKengo Asai, Aiko Fukazawa, Shigehiro Yamaguchi
A cyclic octithiophene containing two [small beta],[small beta]'-linkages was synthesized. Due to the large structural change in the excited state, this compound exhibited bathochromically shifted fluorescence. It also showed a small difference...
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Correction: 9,9[prime or minute]-Anthryl-anthroxyl radicals: strategic stabilization of highly reactive phenoxyl radicals

3 March, 2015 - 22:54
Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC90112J, CorrectionTatsuya Aotake, Mitsuharu Suzuki, Naoki Aratani, Junpei Yuasa, Daiki Kuzuhara, Hironobu Hayashi, Haruyuki Nakano, Tsuyoshi Kawai, Jishan Wu, Hiroko Yamada
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Postsynthetic ligand exchange for the synthesis of benzotriazole-containing zeolitic imidazolate framework

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC00366K, CommunicationJun-Qing Jiang, Cheng-Xiong Yang, Xiu-Ping Yan
Introduction of triazole-based ligand to the zeolitic imidazolate framework-7 via a postsynthetic ligand exchange strategy not only keeps its framework, high stability and morphology, but also provides extra uncoordinated nitrogen...
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Boosting of activity enhancement of K+-responsive quadruplex hammerhead ribozyme

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00961H, CommunicationYudai Yamaoki, Tsukasa Mashima, Takashi Nagata, Masato Katahira
Second-generation quadruplex hammerhead ribozymes, whose activity enhances in response to K+, were developed. New strategies suppressed the basal activity and boosted the activity enhancement upon the addition of K+ to 21-fold.
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Excellent electrochemical performance of NiV3O8/natural graphite anodes via novel in situ electrochemical reconstruction

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00486A, CommunicationShibing Ni, Jianjun Ma, Jicheng Zhang, Xuelin Yang, Lulu Zhang
NiV3O8/natural graphite anodes show excellent electrochemical performance via a novel in situ electrochemical reconstruction.
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Catalytic one-electron reduction of uranyl(VI) to Group 1 uranyl(V) complexes via Al(III) coordination

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00867K, CommunicationMarkus Zegke, Gary S. Nichol, Polly L. Arnold, Jason B. Love
Reactions between [(UO2)(py)(H2L)], the uranyl(VI) Pacman complex of the polypyrrolic macrocycle L and Tebbe's reagent or DIBAL result in the first reductive functionalisation of the uranyl oxo by Al to form [(py)R2AlOUO(py)(H2L)] (R = Me or iBu).
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Separation of polar compounds using a flexible metal-organic framework

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00113G, CommunicationRadha Kishan Motkuri, Praveen K. Thallapally, Harsha V. R. Annapureddy, Liem X. Dang, Rajamani Krishna, Satish K. Nune, Carlos A. Fernandez, Jian Liu, B. Peter McGrail
A flexible metal-organic framework, TetZB, shows remarkable affinity and separation capability of polar compounds (propanol isomers).
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A Sustainable and Simple Catalytic System for Direct Alkynylation of C(sp2)-H Bond with Low Nickel Loadings

3 March, 2015 - 22:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC01163A, CommunicationYuejin Liu, Yan-Hua Liu, Sheng-Yi Yan, Bing-Feng Shi
A sustainable and simple catalytic system for the atom-economical alkynylation of benzamides with low nickel loadings is described. No organic or metallic oxidants and expensive ligands are required. A broad...
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Effective separation of the actinides Am(III) and Cm(III) by electronic modulation of bis-(1,2,4-triazin-3-yl)phenanthrolines

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00567A, CommunicationAshfaq Afsar, Laurence M. Harwood, Michael J. Hudson, James Westwood, Andreas Geist
It has been shown that modification of the phenanthroline backbone of CyMe4-BTPhen leads to subtle electronic modulation, permitting differential ligation of Am(III) and Cm(III) resulting in separation factors up to 7.
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A sensitive whole-cell biosensor for the simultaneous detection of a broad-spectrum of toxic heavy metal ions

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00981B, CommunicationS. Cerminati, F. C. Soncini, S. K. Checa
Design, construction and validation of the first whole-cell fluorescent biosensors reporting, simultaneously and with high sensitivity, bioavailable mercury, lead and cadmium in water samples.
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Synthesis and indole coupling reactions of azetidine and oxetane sulfinate salts

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00975H, CommunicationAnne-Chloe M. A. Nassoy, Piotr Raubo, Joseph P. A. Harrity
Azetidine and oxetane sulfinate salts are easily prepared from commercially available 3-iodoheterocycle precursors in a three-step sequence.
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Surface confined synthesis of porphyrin containing two-dimensional polymers: the effect of rigidity and preferential adsorption of building blocks

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00659G, CommunicationXiuling Sun, Lixia Fan, Xin Zhou, Wei Quan Tian, Zongxia Guo, Zhibo Li, Xiaokang Li, Shengbin Lei
The rigidity and affinity of building blocks to the surface show essential effects on the topology of the 2D polymers.
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Highly durable carbon-supported Pt catalysts prepared by hydrosilane-assisted nanoparticle deposition and surface functionalization

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC10298C, CommunicationAkinori Saito, Hiromi Tsuji, Iwao Shimoyama, Ken-ichi Shimizu, Yuta Nishina
Hydrosilane enabled the formation of Pt nanoparticles and the silane functionalization of a carbon support material in one pot.
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Mesostructured amorphous manganese oxides: facile synthesis and highly durable elimination of low-concentration NO at room temperature in air

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00269A, CommunicationYanyan Du, Zile Hua, Weimin Huang, Meiying Wu, Min Wang, Jin Wang, Xiangzhi Cui, Lingxia Zhang, Hangrong Chen, Jianlin Shi
98% removal of 10 ppm NO is achieved for 237 h with no sign of deactivation with amorphous manganese oxides.
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High activity and stability in the cross-coupling of aryl halides with disulfides over Cu-doped hierarchically porous zeolite ZSM-5

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC10417J, CommunicationWenqian Fu, Taotao Liu, Zhongxue Fang, Yuli Ma, Xiang Zheng, Wenchang Wang, Xiaojun Ni, Maolin Hu, Tiandi Tang
A Cu-doped zeolite ZSM-5 (Cu-ZSM-5-M) with a micro-meso-macroporous structure was directly synthesized, and it exhibits excellent catalytic activity and good recyclability in the cross-coupling of aryl halides with diphenyl disulfides.
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Synthesis of 3-bromosubstituted pyrroles via palladium-catalyzed intermolecular oxidative cyclization of bromoalkynes with N-allylamines

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC10322J, CommunicationJia Zheng, Liangbin Huang, Zun Li, Wanqing Wu, Jianxiao Li, Huanfeng Jiang
A novel Pd-catalyzed intermolecular oxidative cyclization of bromoalkynes with N-allylamines to construct 3-bromo-pyrrole derivatives has been developed.
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Copper-catalyzed oxidative C(sp3)-H/N-H coupling of sulfoximines and amides with simple alkanes via a radical process

3 March, 2015 - 22:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00839E, CommunicationFan Teng, Song Sun, Yan Jiang, Jin-Tao Yu, Jiang Cheng
A copper-catalyzed oxidative C(sp3)-H/N-H coupling of sulfoximines and amides with simple alkanes via a radical pathway was developed.
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