Chem. Commun.

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Photoinduced thiol-ene polymerization reaction for fast preparation of macroporous hybrid monoliths and their application in capillary liquid chromatography

8 July, 2014 - 11:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03451A, CommunicationZhongshan Liu, Junjie Ou, Hui Lin, Zheyi Liu, Hongwei Wang, Jing Dong, Hanfa Zou
Macroporous hybrid monoliths were directly prepared via a photoinduced thiol-ene polymerization reaction and demonstrated good separation performance in cLC.
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Robust Pt-Sn alloy decorated graphene nanohybrid cocatalyst for photocatalytic hydrogen evolution

8 July, 2014 - 11:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03711A, CommunicationChao Kong, Shixiong Min, Gongxuan Lu
A novel platinum-tin alloy decorated graphene nanohybrid (Pt-Sn/G) as a robust photocatalyst exhibited higher hydrogen evolution activity than Pt/G under visible light irradiation.
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Kinetic approach to hyper-doped optical quality thin films

8 July, 2014 - 11:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC01746C, CommunicationAdam L. O. Campbell, Qiong Lei, Wai Tak Yip
Kinetic doping of 0.5 mM R6G to silica thin films dramatically enhances doping efficiency compared to traditional approaches such as pre- and post-doping.
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Copper-mediated aromatic amination reaction and its application to the total synthesis of natural products

6 July, 2014 - 11:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC03895A, Feature ArticleKentaro Okano, Hidetoshi Tokuyama, Tohru Fukuyama
Herein, we review copper-mediated aromatic amination reactions including the classical Ullmann coupling and the recently developed mild aryl amination with an effective ligand as well as the C-H amination reaction....
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Surface plasmon-enhanced zeolite catalysis under light irradiation and its correlation with molecular polarity of reactants

6 July, 2014 - 11:17

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC03225J, CommunicationXingguang Zhang, Aijun Du, Huaiyong Zhu, Jianfeng Jia, Jun Wang, Xuebin Ke
The catalytic performance of zeolites can be boosted by the electric near-field enhancement (ENFE) of plasmonic Au-NPs induced by the localised surface plasmon resonance (LSPR) under visible light irradiation.
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Bromide-bridged palladium(III) chain complexes showing charge bistability near room temperature

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8382-8384
DOI: 10.1039/C4CC02547D, CommunicationShohei Kumagai, Shinya Takaishi, Brian K. Breedlove, Hiroshi Okamoto, Hisaaki Tanaka, Shin-ichi Kuroda, Masahiro Yamashita
We synthesized and characterized bromide-bridged Pd(III) chain complexes, [Pd(en)2Br](MalCn-Y)2[middle dot]H2O (en = ethylenediamine; MalCn-Y = dialkyl sulfomalonate; n: the number of carbon atoms) (n = 7 and 12), which were in averaged valence states at room temperature.
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Pd-Catalyzed C-H activation/oxidative cyclization of acetanilide with norbornene: concise access to functionalized indolines

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8370-8373
DOI: 10.1039/C4CC03062A, CommunicationYang Gao, Yubing Huang, Wanqing Wu, Kefan Huang, Huanfeng Jiang
An efficient Pd-catalyzed C-H activation/oxidative cyclization reaction of acetanilide with norbornene for the synthesis of functionalized indolines has been developed.
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Plasma synthesis of stoichiometric Cu2S nanocrystals stabilized by oleylamine

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8346-8349
DOI: 10.1039/C4CC00998C, CommunicationElijah Thimsen, Uwe R. Kortshagen, Eray S. Aydil
Nonthermal plasmas can produce high quality metal-sulfide nanocrystals in a continuous process without requiring solvents.
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Automated synthesis of backbone protected peptides

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8316-8319
DOI: 10.1039/C4CC03065F, CommunicationAbu-Baker M. Abdel-Aal, George Papageorgiou, Martin Quibell, John Offer
The automated introduction of removable substitution along a peptide backbone prevents chain-association and synthesis failure.
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Poly [small beta]-cyclodextrin inclusion-induced formation of two-photon fluorescent nanomicelles for biomedical imaging

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8398-8401
DOI: 10.1039/C4CC02412E, CommunicationHuijuan Yan, Leiliang He, Cheng Ma, Jishan Li, Jinfeng Yang, Ronghua Yang, Weihong Tan
A novel two-photon absorption (TPA) nanomicelle through the "host-guest" chemistry has been developed and successfully applied in tumor tissue imaging in this work.
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Modulating supramolecular helicity and electrical conductivity of perylene dyes through an achiral alkyl chain

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8343-8345
DOI: 10.1039/C4CC03563A, CommunicationYongwei Huang, Junchao Wang, Zhixiang Wei
Supramolecular helicity and electrical conductivity of chiral perylene amphiphiles can be modulated by changing the length of an alkyl chain at the imide nitrogen.
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High-yield electro-oxidative preparation of graphene oxide

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8402-8404
DOI: 10.1039/C4CC03260H, CommunicationA. M. Abdelkader, I. A. Kinloch, R. A. W. Dryfe
A green and scalable electrochemical process to produce graphene oxide in gram quantities is reported.
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Lotus leaf-like dual-scale silver film applied as a superhydrophobic and self-cleaning substrate

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8405-8407
DOI: 10.1039/C4CC03878A, CommunicationYunwen Wu, Tao Hang, Zheyin Yu, Lan Xu, Ming Li
The structure and the mechanism of the lotus leaf-like and petal-like surfaces.
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Temperature-responsive telechelic dipalmitoylglyceryl poly(N-isopropylacrylamide) vesicles: real-time morphology observation in aqueous suspension and in the presence of giant liposomes

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8350-8352
DOI: 10.1039/C4CC03199G, CommunicationNobuyuki Morimoto, Yu Sasaki, Kouki Mitsunushi, Evgeniya Korchagina, Tetsuichi Wazawa, Xing-Ping Qiu, Shin-ichiro M. Nomura, Makoto Suzuki, Francoise M. Winnik
Telechelic dipalmitoylglyceryl PNIPAM vesicles fuse at the CP and form hybrid vesicles with phospholipid liposomes.
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High-throughput production of two disulphide-bridge toxins

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8408-8411
DOI: 10.1039/C4CC02679A, CommunicationGregory Upert, Gilles Mourier, Alexandra Pastor, Marion Verdenaud, Doria Alili, Denis Servent, Nicolas Gilles
A quick and efficient production method compatible with high-throughput screening was developed using 36 toxins belonging to four different families of two disulphide-bridge toxins. Final toxins were characterized using HPLC co-elution, CD and pharmacology studies.
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Portable pH-inspired electrochemical detection of DNA amplification

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8416-8419
DOI: 10.1039/C4CC03011G, CommunicationFang Zhang, Jian Wu, Rui Wang, Liu Wang, Yibin Ying
Protons can be detected as readouts for DNA amplification.
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Face to face activation of a phenylselenium borane with [small alpha],[small beta]-unsaturated carbonyl substrates: facile synthesis of C-Se bonds

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8420-8423
DOI: 10.1039/C4CC02098G, CommunicationXavier Sanz, Christopher M. Vogels, Andreas Decken, Carles Bo, Stephen A. Westcott, Elena Fernandez
The direct reactivity between phenylselenium pinacolborane (PhSeBpin) and activated olefins opens a non existing pathway towards the selective [small beta]-(phenylseleno) substituted carbonyl compounds.
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Pd(II)-Catalyzed arylation of unactivated methylene C(sp3)-H bonds with aryl halides using a removable auxiliary

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8353-8355
DOI: 10.1039/C4CC03615H, CommunicationQi Zhang, Xue-Song Yin, Sheng Zhao, Sheng-Long Fang, Bing-Feng Shi
Pd(II)-catalyzed arylation of methylene C(sp3)-H bonds with ArBr directed by our newly developed PIP auxiliary was reported.
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A luminescent heptanuclear DyIr6 complex showing field-induced slow magnetization relaxation

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8356-8359
DOI: 10.1039/C4CC02951H, CommunicationDai Zeng, Min Ren, Song-Song Bao, Li Li, Li-Min Zheng
The first example of iridium/lanthanide phosphonates with formulae [DyIr6(ppy)12(bpp)2(bppH)4](CF3SO3)[middle dot]8H2O (1) (ppy- = 2-phenylpyridine, bpp2- = 2-pyridylphosphonate) is reported, which shows photoluminescence and field-induced slow magnetization relaxation.
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The X-ray structure of the complex formed in the reaction between oxaliplatin and lysozyme

6 July, 2014 - 11:17

Chem. Commun., 2014, 50,8360-8362
DOI: 10.1039/C4CC02254H, CommunicationLuigi Messori, Tiziano Marzo, Antonello Merlino
The X-ray structure of the adduct formed between oxaliplatin and the model protein hen egg white lysozyme is reported here.
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