Chem. Commun.

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Charge density mismatch synthesis of MEI- and BPH-type zeolites in the TEA+-TMA+-Li+-Sr2+ mixed-structure-directing agent system

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3671-3673
DOI: 10.1039/C4CC10351C, CommunicationMin Bum Park, Sang Hyun Ahn, Nak Ho Ahn, Suk Bong Hong
The charge density mismatch synthesis of MEI- and BPH-type zeolites in the TEA+-TMA+-Li+-Sr2+ mixed-structure-directing agent system is described.
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Selective enrichment of proteins for MALDI-TOF MS analysis based on molecular imprinting

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3541-3544
DOI: 10.1039/C4CC10205C, CommunicationWei Wan, Qiang Han, Xiaoqiong Zhang, Yuming Xie, Jieping Sun, Mingyu Ding
Molecularly imprinted polymers were applied for selective enrichment of proteins in MALDI-TOF MS analysis for the first time.
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Localized polyselenides in a graphene-coated polymer separator for high rate and ultralong life lithium-selenium batteries

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3667-3670
DOI: 10.1039/C5CC00089K, CommunicationRuopian Fang, Guangmin Zhou, Songfeng Pei, Feng Li, Hui-Ming Cheng
A graphene-coated polymer separator was developed for lithium-selenium batteries with pure selenium powder as the active material.
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Fused polycyclic aromatics incorporating boron in the core: fundamentals and applications

15 February, 2015 - 19:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00175G, Feature ArticleAude Escande, Michael J. Ingleson
The incorporation of boron into the core structure of fused polycyclic aromatics generates compounds with highly attractive properties. This feature article summarises the recent key developments in this field.
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Visible-light-induced photocatalytic oxytrifluoromethylation of N-allylamides for the synthesis of CF3-containing oxazolines and benzoxazines

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3537-3540
DOI: 10.1039/C4CC10217G, CommunicationQiao-Hui Deng, Jia-Rong Chen, Qiang Wei, Quan-Qing Zhao, Liang-Qiu Lu, Wen-Jing Xiao
A visible-light-induced photocatalytic oxytrifluoro-methylation reaction of N-allylamides has been described for the efficient synthesis of CF3-containing oxazolines and benzoxazines in generally high yields.
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A new, cheap, and productive FeP anode material for sodium-ion batteries

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3682-3685
DOI: 10.1039/C4CC09604E, CommunicationWei-Jie Li, Shu-Lei Chou, Jia-Zhao Wang, Hua-Kun Liu, Shi-Xue Dou
A novel and low-cost FeP anode with a high capacity of 764.7 mA h g-1 is reported for sodium ion batteries.
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From competition to cooperation: a highly efficient strategy towards well-defined (co)polypeptides

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3663-3666
DOI: 10.1039/C4CC09055A, CommunicationWei Zhao, Yves Gnanou, Nikos Hadjichristidis
A highly efficient strategy towards well-defined (co)polypeptides.
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SnO2 nanocrystals anchored on N-doped graphene for high-performance lithium storage

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3660-3662
DOI: 10.1039/C4CC08650C, CommunicationWei Zhou, Jinxian Wang, Feifei Zhang, Shumin Liu, Jianwei Wang, Dongming Yin, Limin Wang
A SnO2-N-doped graphene composite with high-performance lithium storage properties is synthesized by a fast, facile and one-pot microwave-assisted solvothermal method.
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The synthesis and electrochemical characterization of bis(fluorosulfonyl)imide-based protic ionic liquids

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3656-3659
DOI: 10.1039/C4CC09665G, CommunicationS. Menne, T. Vogl, A. Balducci
The use of PYRH4FSI represents a significant step towards the realization of high performance IL-based systems, which are able to fill the performance gap existing between these innovative electrolytes and the conventional ones.
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Single crystalline hollow metal-organic frameworks: a metal-organic polyhedron single crystal as a sacrificial template

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3678-3681
DOI: 10.1039/C4CC10051D, CommunicationHyehyun Kim, Minhak Oh, Dongwook Kim, Jeongin Park, Junmo Seong, Sang Kyu Kwak, Myoung Soo Lah
Single crystalline hollow MOFs with cavity dimensions on the order of several micrometers and hundreds of micrometers were prepared using a metal-organic polyhedron single crystal as a sacrificial hard template.
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A tunable process: catalytic transformation of renewable furfural with aliphatic alcohols in the presence of molecular oxygen

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3674-3677
DOI: 10.1039/C4CC09562F, CommunicationXinli Tong, Zonghui Liu, Linhao Yu, Yongdan Li
The tunable efficient transformation of furfural with aliphatic alcohols in the presence of molecular oxygen is achieved in the presence of a nano Au catalyst.
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Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3582-3585
DOI: 10.1039/C4CC10431E, CommunicationKe Yang, Yuqi Wang, Xinyong Chen, Adnan A. Kadi, Hoong-Kun Fun, Hao Sun, Yan Zhang, Hongjian Lu
A nickel-catalyzed direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group has been developed.
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Palladium-catalysed carbonylative [small alpha]-arylation of nitromethane

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3600-3603
DOI: 10.1039/C5CC00123D, CommunicationZhong Lian, Stig D. Friis, Troels Skrydstrup
A palladium-catalysed approach to [small alpha]-nitroketones via carbonylative [small alpha]-arylation of nitromethane is presented, thus providing easy access to key intermediates and important heterocycles.
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New D-A-[small pi]-A organic sensitizers for efficient dye-sensitized solar cells

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3590-3592
DOI: 10.1039/C4CC08539F, CommunicationXiangguang Li, Zhiwei Zheng, Wei Jiang, Wenjun Wu, Zhaohui Wang, He Tian
New metal-free D-A-[small pi]-A organic sensitizers based on N-annulated perylene derivatives are promising for efficient dye-sensitized solar cells.
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Reversible C-C coupling in phenanthroline complexes of divalent samarium and thulium

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3578-3581
DOI: 10.1039/C5CC00289C, CommunicationGregory Nocton, Louis Ricard
The phenanthroline adducts of organosamarium and organothulium fragments feature a reversible C-C bond on the phenanthroline ligand.
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Regioselective C-H bond amination by aminoiodanes

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3574-3577
DOI: 10.1039/C4CC10246K, CommunicationAbhishek A. Kantak, Louis Marchetti, Brenton DeBoef
A new approach for the direct amination of 2-phenylpyridine derivatives using a diphthalimide-iodane and copper triflate has been developed. A series of different 2-phenylpyridine derivatives were aminated with yields up to 88%. Mechanistic investigations indicate that the reaction proceeds via a copper-mediated single electron transfer.
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A pillar[5]arene-fused cryptand: from orthogonal self-assembly to supramolecular polymer

15 February, 2015 - 19:54

Chem. Commun., 2015, 51,3623-3626
DOI: 10.1039/C5CC00130G, CommunicationQi Wang, Ming Cheng, Yue Zhao, Lin Wu, Juli Jiang, Leyong Wang, Yi Pan
A supramolecular polymer based on a novel pillar[5]arene-fused cryptand host was successfully constructed by the orthogonal self-assembly of two host-guest interactions.
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Water-soluble dopamine-based polymers for photoacoustic imaging

11 February, 2015 - 18:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00039D, CommunicationTatjana Repenko, Stanley Fokong, Laura De Laporte, Dennis Go, Fabian Kiessling, Twan Lammers, Alexander J. C. Kuehne
Here we present a facile synthetic method yielding a linear form of polydopamine via Kumada-coupling, which can be converted into water-soluble melanin, generating high contrast in photoacoustic imaging.
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Transformers: The Changing Phases of Low-Dimensional Vanadium Oxide Bronzes

11 February, 2015 - 18:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C4CC08673B, Feature ArticlePeter M Marley, Gregory A Horrocks, Kate E Pelcher, Sarbajit Banerjee
In this feature article, we explore the electronic and structural phase transformations of ternary vanadium oxides with the composition MXV2O5 where M is an intercalated cation. The periodic arrays of...
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Indium triflate-catalyzed stereoselective tandem intramolecular conjugate addition of secondary amines to [small alpha],[small beta]-bisenones

11 February, 2015 - 18:54

Chem. Commun., 2014, Advance Article
DOI: 10.1039/C4CC10016F, CommunicationBodakuntla Thirupathaiah, SungYong Seo
We report an indium triflate-catalyzed stereoselective intramolecular tandem conjugate addition of secondary amines to [small alpha],[small beta]-bisenones to afford a 1,2,3-trisubstituted six-membered ring bearing diketone substituents in good to excellent yields at room temperature.
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