Chem. Commun.

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Epitaxial growth of few-layer MoS2(0001) on FeS2{100}

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC06628F, CommunicationT. Liu, I. Temprano, D. A. King, S. M. Driver, S. J. Jenkins
Depositing Mo on FeS2{100} surfaces and heating to 600 K leads to epitaxial growth of few-layer MoS2(0001) films.
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Near infrared-modulated propulsion of catalytic Janus polymer multilayer capsule motors

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07182D, CommunicationYingjie Wu, Tieyan Si, Xiankun Lin, Qiang He
The use of a near-infrared (NIR) laser for reversible modulation of a bubble-driven Janus polymer capsule motor is demonstrated.
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TiO2-B nanorods on reduced graphene oxide as anode materials for Li ion batteries

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07446G, CommunicationMengmeng Zhen, Shengqi Guo, Guandao Gao, Zhen Zhou, Lu Liu
TiO2-B nanorods combined with 2D RGO nanosheets presented a good high-rate performance for lithium ion batteries.
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Unprecedented directed lateral lithiations of tertiary carbons on NHC platforms

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08434A, CommunicationAndreas A. Danopoulos, Pierre Braunstein, Elixabete Rezabal, Gilles Frison
Deprotonation of the tautomeric mixture of 4-amido-imidazoliums and 4-amino-N-heterocyclic carbenes led to dilithiated dianionic functional NHCs, via an unprecedented regioselective, directed remote lateral lithiation of a tertiary CHMe2 carbon. DFT calculations support that the nature of products is under thermodynamic control.
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Ag(I)-catalyzed tandem [6+3] annulation/isomerization of isocyanoacetates with fulvenes: an expedient approach to synthesize fused dihydropyridines

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08382B, CommunicationZhao-Lin He, Chun-Jiang Wang
An unprecedented Ag(I)-catalyzed tandem [6+3] cycloaddition/isomerization of isocyanoacetates with fulvenes has been developed, affording the fused dihydropyridine derivatives in good yields with exclusive regioselectivities.
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A mild TCEP-based para-azidobenzyl cleavage strategy to transform reversible cysteine thiol labelling reagents into irreversible conjugates

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08515A, CommunicationAntoine Maruani, Shamim Alom, Pierre Canavelli, Maximillian T. W. Lee, Rachel E. Morgan, Vijay Chudasama, Stephen Caddick
A mild TCEP-based para-azidobenzyl cleavage strategy transforms reversible cysteine thiol labelling reagents into irreversible conjugates.
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Carbaborane-based alkynylphosphanes and phospholes

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08449G, CommunicationAnika Kreienbrink, Menyhart B. Sarosi, Robert Kuhnert, Peter Wonneberger, Anna I. Arkhypchuk, Peter Lonnecke, Sascha Ott, Evamarie Hey-Hawkins
1,2-Bis(N,N-dimethyl-aminochlorophosphanyl)-1,2-dicarba-closo-dodecaborane(12) reacts with lithiated phenylacetylene to give a carbaboranyl-based phosphane, while alkynylchlorophosphanes and dilithiated carbaborane give bis(alkynylphosphanyl)carbaboranes.
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Copper nanoparticles generated from aggregates of a hexarylbenzene derivative: a reusable catalytic system for 'click' reactions

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08589B, CommunicationSharanjeet Kaur, Vandana Bhalla, Manoj Kumar
Copper nanoparticles stabilized by aggregates of a hexaphenylbenzene derivative display excellent catalytic activity in 'click' reactions under solvent-free conditions.
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Frustrated Lewis pair behavior of monomeric (boryl)iminomethanes accessed from isocyanide 1,1-hydroboration

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08037H, CommunicationBrandon R. Barnett, Curtis E. Moore, Arnold L. Rheingold, Joshua S. Figueroa
The activation of carbon dioxide, organonitriles, and terminal acetylenes by (boryl)iminomethanes derived from isocyanide 1,1-hydroboration is described.
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Evidence for the interaction between tBuOK and 1,10-phenanthroline to form the 1,10-phenanthroline radical anion: a key step for the activation of aryl bromides by electron transfer

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07299E, CommunicationHong Yi, Anny Jutand, Aiwen Lei
Electron paramagnetic resonance and electrochemistry are utilized to the interaction between 1,10-phenanthroline (Phen) and KOtBu to form the radical anion Phen[radical dot]- via an inner-sphere electron transfer. An aryl radical is then formed from aryl bromide via outer-sphere electron transfer from Phen[radical dot]-.
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Pt-free solar driven photoelectrochemical hydrogen fuel generation using 1T MoS2 co-catalyst assembled CdS QDs/TiO2 photoelectrode

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07304E, CommunicationR. Raja, P. Sudhagar, Anitha Devadoss, C. Terashima, L. K. Shrestha, K. Nakata, R. Jayavel, K. Ariga, A. Fujishima
Herein, Pt-free solar hydrogen generation was achieved using TiO2-CdS photoelectrodes with a metallic-type 1T MoS2 co-catalyst in a back-to-back electrode architecture.
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Single primer-triggered isothermal amplification for double-stranded DNA detection

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07845D, CommunicationCuiping Ma, Dianang Han, Meilian Deng, Jingfei Wang, Chao Shi
We have developed a single primer-triggered isothermal amplification (SAMP) for double-stranded DNA detection method with its simplicity, sensitivity, and robustness.
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Ag-Si artificial microflowers for plasmon-enhanced solar water splitting

22 November, 2014 - 21:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07935C, CommunicationChih-Jung Chen, Ming-Guei Chen, Chih Kai Chen, Pin Chieh Wu, Po-Tzu Chen, Mrinmoyee Basu, Shu-Fen Hu, Din Ping Tsai, Ru-Shi Liu
The solar water splitting efficiency of Ag-Si microflowers was enhanced through the synergistic effects of co-catalytic and plasmonic assistance.
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Proton reduction by molecular catalysts in water under demanding atmospheres

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15995-15998
DOI: 10.1039/C4CC06159D, CommunicationDavid W. Wakerley, Manuela A. Gross, Erwin Reisner
The electrocatalytic proton reduction activity of a Ni bis(diphosphine) and a cobaloxime catalyst has been studied in water in the presence of the gaseous inhibitors O2 and CO.
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P-modified and carbon shell coated Co nanoparticles for efficient alkaline oxygen reduction catalysis

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15940-15943
DOI: 10.1039/C4CC07143C, CommunicationJaeyune Ryu, Namgee Jung, Dong-Hee Lim, Dong Yun Shin, Sae Hume Park, Hyung Chul Ham, Jong Hyun Jang, Hyoung-Juhn Kim, Sung Jong Yoo
The present carbon shell coated Co nanoparticles of which the surface composites are modified by phosphorus incorporation, exhibit efficient and durable oxygen reduction activities in alkaline medium.
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Correction: Copper-mediated oxidative trifluoromethylthiolation of unactivated terminal alkenes

22 November, 2014 - 21:54
Chem. Commun., 2014, 50,15999-15999
DOI: 10.1039/C4CC90460E, CorrectionKe Zhang, Jian-Bo Liu, Feng-Ling Qing
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Engineering lead-sensing GFP through rational designing

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15979-15982
DOI: 10.1039/C4CC07163H, CommunicationSaravanan Prabhu Nadarajan, Yuvaraj Ravikumar, Kanagavel Deepankumar, Chong-Soon Lee, Hyungdon Yun
A lead biosensor (PbGFP) was developed by engineering lead binding site near the chromophore of green fluorescent protein. The specific binding of lead to chromophore of PbGFP resulted in turn-off mechanism.
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Highly-effective gating of single-molecule junctions: an electrochemical approach

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15975-15978
DOI: 10.1039/C4CC06519K, CommunicationMasoud Baghernejad, David Zsolt Manrique, Chen Li, Thomas Pope, Ulmas Zhumaev, Ilya Pobelov, Pavel Moreno-Garcia, Veerabhadrarao Kaliginedi, Cancan Huang, Wenjing Hong, Colin Lambert, Thomas Wandlowski
We report an electrochemical gating approach with [similar]100% efficiency to tune the conductance of single-molecule 4,4[prime or minute]-bipyridine junctions.
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Unprecedented synthesis of aza-bridged benzodioxepine derivatives through a tandem Rh(II)-catalyzed 1,3-rearrangement/[3+2] cycloaddition of carbonyltriazoles

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15971-15974
DOI: 10.1039/C4CC08339C, CommunicationYong-Sheng Zhang, Xiang-Ying Tang, Min Shi
Rh(II)-catalyzed novel tandem intramolecular cycloisomerizations of aldehydes or ketones with 1-sulfonyl 1,2,3-triazoles have been disclosed, providing a facile protocol to access a series of functionalized aza-bridged benzodioxepine heterocycles.
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Zirconium complexes of bipyrrolidine derived salan ligands for the isoselective polymerisation of rac-lactide

22 November, 2014 - 21:54

Chem. Commun., 2014, 50,15967-15970
DOI: 10.1039/C4CC07871C, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Matthew D. Jones, Stuart L. Hancock, Paul McKeown, Pascal M. Schafer, Antoine Buchard, Lynne H. Thomas, Mary F. Mahon, John P. Lowe
We report a series of Zr(IV) 2,2[prime or minute]-bipyrrolidine-salan derived complexes and their exploitation for the ROP of rac-lactide to afford highly isotactically enriched PLA.
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