Chem. Commun.

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Facile one-pot synthesis of MoS2 quantum dots/graphene/TiO2 composites for highly enhanced photocatalytic property

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08984G, CommunicationWeiyin Gao, Minqiang Wang, Chenxin Ran, Le Li
We reported a simple one-pot solvothermal approach to fabricate MoS2 quantuam dots (QDs)/Graphene/TiO2 (MGT) composite photocatalyst with significant improved photocatalysis property, which is caused by the increased charge separation, visible-light...
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Red luminescence and ferromagnetism in europium oxynitridosilicates with [small beta]-K2SO4 structure

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08548E, CommunicationAshley Phillip Black, Kristin Denault, Judith Oro-Sole, Alejandro R Goni, Amparo Fuertes
The new compounds LaSrSiO3N and LaBaSiO3N activated with Eu2+ are orange-red light emitting luminescent materials under excitation in the UV-blue range. They represent the first examples of stoichiometric alkaline earth...
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Linear assembly of porphyrin-C60 complex confined in vertical nanocylinders of amphiphilic block copolymer films

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC09262G, CommunicationTakuya Kamimura, Motonori Komura, Hideaki Komiyama, Tomokazu Iyoda, Fumito Tani
Linear assemblies of 1:1 porphyrin-fullerene C60 complex were formed in vertical cylindrical polyether nanodomains of amphiphilic block copolymer films by a simple spin coating-annealing method. The nanocylinder structures were kept...
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Self-organization of star-shaped columnar liquid crystals with a coaxial nanophase segregation revealed by a combined experimental and simulation approach

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08602C, CommunicationEduardo Beltran, Matteo Garzoni, Beatriz Feringan, Alberto Vancheri, Barbera Joaquin, J L Serrano, Giovanni Pavan, Raquel Gimenez, Teresa Sierra
Fully consistent X-ray data and molecular dynamics simulations on new star-shaped liquid crystals yield two nanosegregated architectures with a coaxial stacking of two functional discotic units: tris(triazolyl)triazine and triphenylene. Analysis...
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Peptide-catalyzed, bioinspired silicification for single-cell encapsulation in the imidazole-buffered system

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08544B, CommunicationJi Hun Park, Insung S. Choi, Sung Ho Yang
Cytoprotective silica encapsulation of individual yeast cells is achieved by a peptide-catalyzed silicification under mild conditions, inspired by glass sponges.
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Electrospun nanofibers: A prospective electro-active material for constructing high performance Li-ion batteries

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC07824A, Feature ArticleVanchiappan Aravindan, Jayaraman Sundaramurthy, Palaniswamy Suresh Kumar, Yun-Sung Lee, Seeram Ramakrishna, Srinivasan Madhavi
The present review outlines high performance Li-ion cells fabricated with all one-dimensional materials as the cathode and anode, as well as a separator-cum-electrolyte prepared by an electrospinning technique.
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Coordination responsive tellurium-containing multilayer film for controlled delivery

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08588D, CommunicationWei Cao, Lu Wang, Huaping Xu
A coordination-responsive tellurium-containing film was fabricated to load cisplatin by Te-Pt coordination, and competitive bio-ligands could trigger the release of cisplatin.
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Asymmetric core-expanded aza-BODIPY analogues: facile synthesis and optical properties

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC06704E, CommunicationHui Liu, Hua Lu, Zhikuan Zhou, Soji Shimizu, Zhifang Li, Nagao Kobayashi, Zhen Shen
Significant large Stokes shifts and enhanced solid state emission were achieved in a novel series of asymmetric core-expanded aza-BODIPY analogues, 4a-4d, synthesized by a facile and scalable two step reaction...
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Laser activating gold catalyst for liquid-phase growth of cadmium selenide nanowires

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC09276G, CommunicationCheng Huang, Jing Mao, Xue-Min Chen, Jing Yang, Xiwen Du
A laser-activating-catalyst (LAC) technique was developed to grow CdSe nanowires in liquid medium at room temperature. The gold catalysts dispersed in the precursor solution were activated by a pulsed laser...
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Polyoxometalate-Organic Supermolecular Nanotube with High Chemical Stability and Proton-Conducting Properties

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08445D, CommunicationGao-Juan Cao, Jing-Dong Liu, Xiu-Hong Cai, Ting-Ting Zhuang, Shou-Tian Zheng
Employment of 1H-1,2,4-Triazole-3-thiol (H2trzS) has led to a rare inorganic-organic hybrid supermolecular nanotube built from novel Ni5-substituted polyoxotungstates, which presents interesting structural characteristics, high chemical stability, and proton-conducting properties.
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Aligned macroporous monoliths with intrinsic microporosity via a frozen-solvent-templating approach

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08919G, CommunicationAdham Ahmed, Tom Hasell, Rob Clowes, Peter Myers, Andrew Cooper, Haifei Zhang
Aligned macroporous monoliths of organic cage, polymer of intrinsic microporosity (PIM-1), and metal-organic framework (HKUST-1) are prepared by a controlled freezing approach. In addition to macropores, all the monoliths contain...
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Spiroguanidine rhodamines as fluorogenic probes for lysophosphatidic acid

11 December, 2014 - 02:17
Chem. Commun., 2014, Accepted Manuscript
DOI: 10.1039/C4CC08818B, CommunicationLei Wang, Martha Sibrian-Vazquez, Jorge Omar Escobedo, Jialu Wang, Richard Moore, Robert Strongin
Direct determination of total lysophosphatidic acid (LPA) was accomplished using newly developed spiroguanidines derived from rhodamine B as universal fluorogenic probes. Optimum conditions for the quantitative analysis of total LPA...
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Parafilm-assisted microdissection: a sampling method for mass spectrometry-based identification of differentially expressed prostate cancer protein biomarkers

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08331H, CommunicationJ. Quanico, J. Franck, J. P. Gimeno, R. Sabbagh, M. Salzet, R. Day, I. Fournier
Profiling of tumors using a combined MALDI MS imaging and parafilm-assisted microdissection (PAM) workflow identified candidate biomarkers of prostate cancer.
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Controllable luminescence of layered rare-earth hydroxide composites with a fluorescent molecule: blue emission by delamination in formamide

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08380F, CommunicationQingyang Gu, Feifei Su, Shulan Ma, Genban Sun, Xiaojing Yang
Intercalation of fluorescent molecule HPTS into LRH (R = Eu, Gd) to form composites showing tuned luminescence and blue emission at delamination in formamide.
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Iron-mediated Markovnikov-selective hydro-trifluoromethylthiolation of unactivated alkenes

11 December, 2014 - 02:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C4CC08655D, CommunicationTao Yang, Long Lu, Qilong Shen
An iron-mediated hydro-trifluoromethylthiolation of unactivated olefins under mild conditions was described for the first time.
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Supramolecular assemblies of novel aminonucleoside phospholipids and their bonding to nucleic acids

11 December, 2014 - 02:17

Chem. Commun., 2015, 51,469-472
DOI: 10.1039/C4CC07538B, CommunicationDelin Pan, Jing Sun, Hongwei Jin, Yating Li, Liyu Li, Yun Wu, Lihe Zhang, Zhenjun Yang
A novel class of aminonucleoside phospholipids has been developed for potential use as non-viral vectors for gene delivery.
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Artificial concurrent catalytic processes involving enzymes

11 December, 2014 - 02:17

Chem. Commun., 2015, 51,450-464
DOI: 10.1039/C4CC07277D, Feature ArticleValentin Kohler, Nicholas J. Turner
Various aspects of simultaneous enzymatic catalysis are reviewed with an emphasis on the combination of biocatalysts with transition metal catalysts.
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Mesomeric betaine - N-heterocyclic carbene interconversions of 1,2,4-triazolium-phenolates. Sulfur, selenium, and borane adduct formation

11 December, 2014 - 02:17

Chem. Commun., 2015, 51,477-479
DOI: 10.1039/C4CC08032G, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Ming Liu, Martin Nieger, Andreas Schmidt
Triazolium-phenolates form carbenic tautomers which can be trapped with boranes as a new heterocyclic ring system.
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A phthalimidation protocol that follows protein defined parameters

11 December, 2014 - 02:17

Chem. Commun., 2015, 51,473-476
DOI: 10.1039/C4CC08503E, CommunicationRohith Singudas, Srinivasa Rao Adusumalli, Pralhad Namdev Joshi, Vishal Rai
This work outlines the first phthalimidation protocol suitable for protein labeling and performed in aqueous media at room temperature and neutral pH with no catalyst or co-reagent required.
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Direct asymmetric vinylogous Michael addition of 3-alkylidene oxindoles to chalcones catalyzed by a chiral N,N[prime or minute]-dioxide ytterbium(III) complex

11 December, 2014 - 02:17

Chem. Commun., 2015, 51,580-583
DOI: 10.1039/C4CC07204A, CommunicationXiao Xiao, Hongjiang Mei, Quangang Chen, Xiaohu Zhao, Lili Lin, Xiaohua Liu, Xiaoming Feng
A chiral ytterbium(III)-N,N[prime or minute]-dioxide complex was applied in the catalytic direct asymmetric vinylogous Michael addition of 3-alkylidene oxindoles to chalcones, giving the corresponding [gamma]-addition products with high yields, enantioselectivities and Z/E selectivities.
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