Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC41858H, CommunicationLuigi Margarucci, Maria Chiara Monti, Chiara Cassiano, Matteo Mozzicafreddo, Mauro Angeletti, R Riccio, Alessandra Tosco, Agostino Casapullo
Hsp90, a key target in cancer therapy, has been identified as the main partner of oleocanthal, an olive oil bioactive compound. Combination of chemical and biological assays disclosed its action...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC41934G, CommunicationZhengwen Fu, Jili Yue, Qian Sun
A simple fabrication route of a chalcogenide type compound Cu2Se electrode and its electrochemical behavior of Na storage with promising electrochemical activity is reported for the first time. Our findings...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42841A, CommunicationMartin Oschatz, Soren Thieme, Lars Borchardt, Martin R. Lohe, Tim Biemelt, Jan Bruckner, Holger Althues, Stefan Kaskel
A novel synthesis method for the preparation of highly mesoporous carbon materials is described based on reactive carbochlorination etching of titania nanoparticles inside a dense carbon matrix. For the first...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC40779A, CommunicationXiangshi Tan
The differences between mouse mA[small beta]1-42 and human hA[small beta]1-42, explored by CD and fluorescence spectroscopy, transmission electron microscope, ROS fluorescent assay, and neuronal cell viability, revealed that the mA[small beta]1-42 as a...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42296H, CommunicationGuangyi Li, Ning Li, Shanshan Li, Ai-Qin Wang, Yu cong, Xiaodong Wang, Tao Zhang
Diesel or jet fuel range branched alkanes were firstly synthesized by the combination of the hydroxyalkylation/alkylation (HAA) of 2-methylfuran with hydroxyacetone and subsequent hydrodeoxygenation. Due to the electron- withdrawing effect...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42639D, CommunicationYufei Liu, Ming Luo, Ji Yan, Xia Xiang, Xinghu Ji, Guohua Zhou, Zhike He
A highly sensitive and selective DNA biosensor based on hybridization chain reaction is described, which combines CdTe quantum dots (QDs) and ruthenium complex. Based on the variation of fluorescence signals...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC43019G, CommunicationLaurent Trembleau, Tim Andrew Smith, Mostafa H. Abdelrahman
Fluoride binding by artificial receptors in water remains a challenging task due to the high hydration enthalpy of this anion. A cationic boron-based tripodal receptor featuring three flexible ammonium-containing arms...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42416B, CommunicationValeriu Mereacre, Hua Xiang, Yanhua Lan, Tong-Bu Lu, Christopher E Anson, Annie K Powell
[FeIII2LnIII2(OH)2(L1)2(HL2)2(NO3)4(H2O)11/2(MeOH)1/2]∙6MeCN (Ln = Y (1), Dy (2); H2L1 = 2,3-dihydroxybenzaldehyde and H2L2 is the Schiff base of this aldehyde with furfurylamine) have unusually weak antiferromagnetic interactions between the FeIII centres...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42307G, CommunicationLingkui Meng, Kun Wu, Chao Liu, Aiwen Lei
The first palladium-catalysed aerobic oxidative intramolecular alkenylation of Csp3-H bond was described. The reaction conditions were mild and molecular oxygen was used as the terminal oxidant. Kinetic study showed that...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42653J, CommunicationSankarprasad Bhuniya, Min Hee Lee, Hyun Mi Jeon, Ji Hye Han, Jae Hong Lee, Nayoung Park, Sukhendu Maiti, Chulhun Kang, Jong Seung Kim
We present the design, synthesis, optical properties and in vitro biological assessments of the theranostic prodrug 6 where a near IR fluorophore is conjugated with cancer cell-directing biotin unit, further...
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Chem. Commun., 2013, Accepted Manuscript
DOI: 10.1039/C3CC42273A, CommunicationHui Han, Jim Yang Lee, Xianmao Lu
Magnetic nanoparticles functionalized with thermoresponsive polymer become photoresponsive when attached with plasmonic nanoparticles to form heterodimers. Under solar illumination, the plasmonic particles absorb sunlight and induce localized heating, causing collapse...
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Chem. Commun., 2013, 49,5106-5131
DOI: 10.1039/C3CC41143E, Feature ArticleNicolas P. E. Barry, Peter J. Sadler
Exploration of medicinal chemistry of the elements of the periodic table, and especially metals, offers the promise of new drugs and diagnostic agents with novel targets and new mechanisms of action.
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Chem. Commun., 2013, 49,5231-5233
DOI: 10.1039/C3CC42365D, CommunicationWonchul Lee, Joo-Hack Youn, Sung Ho Kang
Total synthesis of (-)-kaitocephalin has been completed through desymmetrization for the quaternary carbon, mercuriocyclization for the pyrrolidine, epoxidation followed by epoxide opening for the amino hydroxy functionality and concurrent oxidation for the three carboxylic acids.
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Chem. Commun., 2013, 49,5147-5149
DOI: 10.1039/C3CC41962B, CommunicationGuanjia Zhao, Hong Wang, Samuel Sanchez, Oliver G. Schmidt, Martin Pumera
Ferromagnetic microjets can pick-up paramagnetic beads while not showing any interaction with diamagnetic silica microparticles for active separation of microparticles.
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Chem. Commun., 2013, 49,5210-5212
DOI: 10.1039/C3CC41993B, CommunicationGen Watanabe, Ken Ohmori, Keisuke Suzuki
The first regiocontrolled synthesis of procyanidin B₆, a dimer with a rare 4,6-interflavan linkage, is described. Regioselective linking was achieved by the halo-capping strategy followed by removal of all the benzyl protecting groups and the halo-caps by one-pot hydrogenolysis.
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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42488J, CommunicationTaichi Kano, Hisashi Sugimoto, Osamu Tokuda, Keiji Maruoka
Unusual anti-selectivity was observed in the chiral amine-catalyzed conjugate addition of aldehydes to nitroalkenes, and anti-adducts were obtained as major diastereomers in excellent enantioselectivity by use of a biphenyl-based chiral secondary amine (S)-3 as catalyst.
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Chem. Commun., 2013, 49,5201-5203
DOI: 10.1039/C3CC41966E, CommunicationMei Zhang, Zi-Jie Pu, Xing-Lian Chen, Xiao-Li Gong, Ai-Xin Zhu, Li-Ming Yuan
A chiral nanoporous MOF was used as a chiral stationary phase in HPLC with excellent enantioselectivity.
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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42280A, CommunicationLarissa Bergmann, Jana Friedrichs, Mathias Mydlak, Thomas Baumann, Martin Nieger, Stefan Brase
Strongly luminescent, neutral Cu(I) complexes bearing 5-(2-pyridyl)tetrazolate and various phosphine ligands were synthesized. While the cationic counterparts do not exceed photoluminescence quantum yields (PLQY) of 4-46%, the neutral Cu(I) complexes show PLQYs of up to 89%.
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Chem. Commun., 2013, Advance Article
DOI: 10.1039/C3CC42152J, CommunicationLun Pan, Ji-Jun Zou, Songbo Wang, Zhen-Feng Huang, Ao Yu, Li Wang, Xiangwen Zhang
Anatase nanosheets self-decorated with quantum-size TiO₂ dots were synthesized by a hydrothermal strategy and showed much higher photoactivity than clean nanosheets.
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Chem. Commun., 2013, 49,5144-5146
DOI: 10.1039/C3CC42214C, CommunicationJessica R. Kramer, Timothy J. Deming
A procedure for reversible, chemoselective tagging and functionalization of methionine residues in peptides and polypeptides has been described.
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