Chem. Commun.

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Microengine-assisted electrochemical measurements at printable sensor strips

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02222C, CommunicationStefano Cinti, Gabriela Valdes-Ramirez, Wei Gao, Jinxing Li, Giuseppe Palleschi, Joseph Wang
A new microengine-based built-in-platform exploiting a surprising dual action with solution mixing and control of the reaction parameters, has been applied for accelerating chemical reactions (organophosphorous nerve agents hydrolysis) and electrochemical detection of non-hazardous by-product (p-nitrophenol) using printable sensor strip.
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Intramolecular thiol-yne cyclisation as a novel strategy for thioglycal synthesis

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02162F, CommunicationVincent Corce, Lauren McSweeney, Aoife Malone, Eoin M. Scanlan
Intramolecular thiol-yne cyclisation reactions has been developed for the synthesis of both exo- and endo-thioglycals.
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Separation of liquid domains in model membranes induced with high hydrostatic pressure

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02134K, CommunicationNicola L. C. McCarthy, Oscar Ces, Robert V. Law, John M. Seddon, Nicholas J. Brooks
We have imaged the formation of membrane microdomains immediately after their induction using a novel technology platform coupling high hydrostatic pressure to fluorescence microscopy.
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A flow cytometer-based whole cell screening toolbox for directed hydrolase evolution through fluorescent hydrogels

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC01791B, CommunicationNina Lulsdorf, Christian Pitzler, Michael Biggel, Ronny Martinez, Ljubica Vojcic, Ulrich Schwaneberg
A high-throughput whole cell flow cytometer screening toolbox for hydrolases was validated by identification of improved esterase, lipase and cellulase variants.
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Creating extra pores in microporous carbon via a template strategy for a remarkable enhancement of ambient-pressure CO2 uptake

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC01828E, CommunicationBaiyan Li, Yiming Zhang, Dingxuan Ma, Liangkui Zhu, Daliang Zhang, Matthew Chrzanowski, Zhan Shi, Shengqian Ma
The creation of extra pores by removal of the silicon template in a porous carbon material derived from carbonizing silicon-containing POP has afforded a remarkable enhancement of ambient-pressure CO2 uptake capacity.
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Surface roughness-induced speed increase for active Janus micromotors

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC01607J, CommunicationUdit Choudhury, Lluis Soler, John G. Gibbs, Samuel Sanchez, Peer Fischer
Fabrication protocol and surface morphology.
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Mechanochemical surface functionalisation of superparamagnetic microparticles with in situ formed crystalline metal-complexes: a fast novel core-shell particle formation method

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC01961C, CommunicationF. A. Brede, K. Mandel, M. Schneider, G. Sextl, K. Muller-Buschbaum
An innovative mechanochemical method is reported for the in situ formation of crystalline metal-complexes on the surface of superparamagnetic nanocomposite microparticles.
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Highly emissive, solution-processable and dynamic Eu(III)-containing coordination polymers

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC01793A, CommunicationAndre Duerrbeck, Sergey Gorelik, Jonathan Hobley, Ji'En Wu, Andy Hor, Nicholas Long
Preparation of new soluble dynamic coordination networks based on Eu(III) and a new, rigid ditopic pybox-related ligand.
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Characterization and real-time imaging of the FTLD-related protein aggregation induced by amyloidogenic peptides

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC00513B, CommunicationRuei-Yu He, Yi-Chen Huang, Chao-Wei Chiang, Yu-Ju Tsai, Ting-Juan Ye, Hua-De Gao, Chu-Ya Wu, Hsien-Ming Lee, Joseph Jen-Tse Huang
Q/N- and G-rich polypeptides from the TDP-43 C-terminus formed amyloid fibers in vitro and induced the aggregation of the transfected TDP-43-EGFP in live cells.
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Side-functionalized two-dimensional polymers synthesized via on-surface Schiff-base coupling

25 April, 2015 - 12:17

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC02232K, CommunicationLirong Xu, Lili Cao, Zongxia Guo, Zeqi Zha, Shengbin Lei
An imine-based 2D polymer side-functionalized with o-hydroxyl group was designed and synthesized on a highly oriented pyrolytic graphite surface.
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Pushing the limits of signal resolution to make coupling measurement easier

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7939-7942
DOI: 10.1039/C5CC01305D, CommunicationJose Enrique Herbert Pucheta, Daisy Pitoux, Claire M. Grison, Sylvie Robin, Denis Merlet, David J. Aitken, Nicolas Giraud, Jonathan Farjon
Novel band selective decoupled pure shift selective refocusing experiments allowed simplification of the measurement of all [small delta]1H, and JHH couplings with an ultrahigh spectral resolution in peptides.
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The first zinc phosphite with remarkable structural and functional transformations

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7824-7826
DOI: 10.1039/C5CC01886B, CommunicationChih-Min Wang, Tsung-Yuan Chang, Li-Wei Lee, Hsiu-Mei Lin, Kuang-Lieh Lu, Kwang-Hwa Lii
An organic-inorganic hybrid zinc phosphite with remarkable structural and functional transformations.
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Functional membranes via nanoparticle self-assembly

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7770-7780
DOI: 10.1039/C5CC01388G, Feature ArticleErica Green, Emily Fullwood, Julieann Selden, Ilya Zharov
Nanoporous and ion conductive materials can be prepared by the self-assembly of nanoparticles, providing membranes with size and charge selectivity suitable for separation and possessing proton or lithium transport properties suitable for fuel cells and batteries.
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A multifunctional phosphorescent iridium(III) complex for specific nucleus staining and hypoxia monitoring

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7943-7946
DOI: 10.1039/C5CC01978H, CommunicationShujuan Liu, Hua Liang, Kenneth Yin Zhang, Qiang Zhao, Xiaobo Zhou, Wenjuan Xu, Wei Huang
A multifunctional phosphorescent iridium(III) complex has been synthesized for specific nucleus staining and hypoxia monitoring through time-resolved luminescence imaging.
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A fluorescent histone deacetylase (HDAC) inhibitor for cellular imaging

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7827-7830
DOI: 10.1039/C5CC02059J, CommunicationOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Cassandra L. Fleming, Trent D. Ashton, Cameron Nowell, Mark Devlin, Anthony Natoli, Jeannette Schreuders, Frederick M. Pfeffer
Fluorescent 4MS, has comparable HDAC and anticancer activity to scriptaid and allows visualisation of rapid cellular uptake and cytoplasmic localisation.
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Rapid and simple preparation of remarkably stable binary nanoparticle planet-satellite assemblies

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7812-7815
DOI: 10.1039/C5CC01543J, CommunicationStefan Borsley, Sarah Flook, Euan R. Kay
Homogeneous samples of binary nanoparticle planet-satellite superstructures are produced from simple building blocks in a rapid and readily scalable procedure that is tolerant to variations in building block size and shape.
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Integrated, highly crystalline and water stable coordination framework films on various substrates and water-assisted protonic conductivity

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7947-7949
DOI: 10.1039/C5CC02392K, CommunicationChen Xiao, Zhengyu Chu, Xiao-Ming Ren, Tian-Yu Chen, Wanqin Jin
The integrated, highly crystalline and water stable Prussian blue analogue films were successfully fabricated on the porous [small alpha]-Al2O3, the conducting ITO and the flexible non-woven fabric substrates, respectively, using the self-assembly approach.
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Solvent-dependent strong asymmetric amplification in the catalytic enantioselective Henry reaction using the trans-N,N[prime or minute]-bis-biphenyl-4-ylmethyl-cyclohexane-1,2-diamine-CuCl2 complex

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7907-7910
DOI: 10.1039/C5CC02302E, CommunicationKoichi Tanaka, Tomoharu Iwashita, Erika Yoshida, Tomomi Ishikawa, Shinya Otuka, Zofia Urbanczyk-Lipkowska, Hiroki Takahashi
An unprecedented strong positive nonlinear effect was observed in the asymmetric Henry reaction.
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Little do more: a highly effective Pt1/FeOx single-atom catalyst for the reduction of NO by H2

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7911-7914
DOI: 10.1039/C5CC00714C, CommunicationJian Lin, Botao Qiao, Ning Li, Lin Li, Xiucheng Sun, Jingyue Liu, Xiaodong Wang, Tao Zhang
A FeOx supported Pt single-atom catalyst (Pt-SAC) exhibited much higher NO conversion and selectivity to N2 than the supported Pt nanoparticle catalyst (Pt-Nano).
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Sequential double second-order nonlinear optical switch by an acido-triggered photochromic cyclometallated platinum(II) complex

25 April, 2015 - 12:17

Chem. Commun., 2015, 51,7805-7808
DOI: 10.1039/C5CC01893E, CommunicationJulien Boixel, Veronique Guerchais, Hubert Le Bozec, Agisilaos Chantzis, Denis Jacquemin, Alessia Colombo, Claudia Dragonetti, Daniele Marinotto, Dominique Roberto
The first example of a sequential double nonlinear optical switch, induced first by protonation and next upon irradiation with UV light.
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