Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 1 day 17 hours ago

Equiatomic intermetallic compounds YTX (T = Ni, Ir; X = Si, Ge, Sn, Pb): a systematic study by 89Y solid state NMR and 119Sn Mossbauer spectroscopy

13 April, 2014 - 20:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00161C, PaperChristoph Hoting, Hellmut Eckert, Frank Haarmann, Florian Winter, Rainer Pottgen
The equiatomic TiNiSi type tetrelides YTX (space group Pnma) with T = Ni, Ir and X = Si, Ge, Sn, Pb were synthesized from the elements by arc-melting or via high-frequency-melting of the elements in sealed niobium ampoules.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Novel metallo-therapeutics of the NSAID naproxen. Interaction with intracellular components that leads the cells to apoptosis

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6848-6863
DOI: 10.1039/C3DT53175A, PaperC. N. Banti, A. D. Giannoulis, N. Kourkoumelis, A. M. Owczarzak, M. Kubicki, S. K. Hadjikakou
Silver(I) complexes (1-2) of the anti-inflammatory drug naproxen were evaluated for their binding properties towards lipoxygenase and CT-DNA and the results are compared with their in vitro cytotoxicity. UVC light increases the effectiveness of complexes 1-2 on MCF-7 cells by 15.3% and 39.5% respectively.
The content of this RSS Feed (c) The Royal Society of Chemistry

Star shaped ferrocenyl truxenes: synthesis, structure and properties

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6891-6896
DOI: 10.1039/C4DT00210E, PaperRajneesh Misra, Rekha Sharma, Shaikh M. Mobin
This article reports the design and synthesis of star shaped, C3-symmetric ferrocenyl substituted truxenes by the Pd-catalyzed Sonogashira cross-coupling and cycloaddition reaction.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, antiradical activity and in vitro cytotoxicity of novel organotin complexes based on 2,6-di-tert-butyl-4-mercaptophenol

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6880-6890
DOI: 10.1039/C3DT53469C, PaperD. B. Shpakovsky, C. N. Banti, E. M. Mukhatova, Yu. A. Gracheva, V. P. Osipova, N. T. Berberova, D. V. Albov, T. A. Antonenko, L. A. Aslanov, E. R. Milaeva, S. K. Hadjikakou
The antiradical activity and in vitro cytotoxicity of novel organotin complexes with 2,6-di-tert-butylphenol pendant were established.
The content of this RSS Feed (c) The Royal Society of Chemistry

Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6842-6847
DOI: 10.1039/C4DT00242C, PaperLiping Guo, Xiancui Zhu, Shuangliu Zhou, Xiaolong Mu, Yun Wei, Shaowu Wang, Zhijun Feng, Guangchao Zhang, Baojia Deng
Monoalkyl rare-earth metal complexes could be highly active catalysts for 1,4-regioselective polymerization of isoprene in the presence of cocatalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry

Effect of the capping ligand on luminescent erbium(III) [small beta]-diketonate single-ion magnets

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6752-6761
DOI: 10.1039/C4DT00168K, PaperM. Ramos Silva, P. Martin-Ramos, J. T. Coutinho, L. C. J. Pereira, J. Martin-Gil
Three Erbium complexes with 2,4-hexanedione and different N,N-donor ancillary ligands have been synthesized and characterized. The impact of the diimide ligand on SIM behaviour has been assessed.
The content of this RSS Feed (c) The Royal Society of Chemistry

An organic-inorganic hybrid semiconductor material based on Lindqvist polyoxomolybdate and a tetra-nuclear copper complex containing two different ligands

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6744-6751
DOI: 10.1039/C3DT53345J, PaperZhi-Kun Qu, Kai Yu, Zhi-Feng Zhao, Zhan-hua Su, Jing-Quan Sha, Chun-Mei Wang, Bai-Bin Zhou
A tetranuclear copper complex was first introduced into {Mo6O19} systems to weave an unique 3D network with a 412[middle dot]63-nbo topology, which displays good semiconductive and magnetic activity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structure and valence-trapping vs. detrapping for new trinuclear iron pentafluoro benzoate complexes: possible recognition of organic molecules by 57Fe Mossbauer spectroscopy

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6711-6719
DOI: 10.1039/C3DT53623H, PaperSatoru Onaka, Yoichi Sakai, Tomoji Ozeki, Tadahiro Nakamoto, Yusuke Kobayashi, Masashi Takahashi, Ryo Ogiso, Tsutomu Takayama, Michito Shiotsuka
CH2Cl2 molecules trapped in the intermolecular nano-channels of the [Fe3O(C6F5CO2)6(py)3] crystal.
The content of this RSS Feed (c) The Royal Society of Chemistry

p-n junction CuO/BiVO4 heterogeneous nanostructures: synthesis and highly efficient visible-light photocatalytic performance

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6735-6743
DOI: 10.1039/C3DT53613K, PaperWenzhong Wang, Jun Wang, Zhizhen Wang, Xuanzhen Wei, Li Liu, Qingshan Ren, Wenliang Gao, Yujie Liang, Honglong Shi
p-n junction CuO/BiVO4 heterogeneous nanostructures with high visible-light-driven photocatalytic activity were prepared by coupling a polyol process with a hydrothermal technique.
The content of this RSS Feed (c) The Royal Society of Chemistry

Facial triad modelling using ferrous pyridinyl prolinate complexes: synthesis and catalytic applications

13 April, 2014 - 20:17

Dalton Trans., 2014, 43,6769-6785
DOI: 10.1039/C3DT53266F, PaperMarcel A. H. Moelands, Daniel J. Schamhart, Emma Folkertsma, Martin Lutz, Anthony L. Spek, Robertus J. M. Klein Gebbink
Iron complexes based on the simple PyPro ligand show a large conformational flexibility in modelling the 2-His-1-carboxylate facial triad.
The content of this RSS Feed (c) The Royal Society of Chemistry

Exploring anagostic interactions in 5,15-porphodimethene metal complexes

13 April, 2014 - 20:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT53307G, CommunicationM. G. Derry Holaday, Gourav Tarafdar, Arun Kumar, M. L. P. Reddy, A. Srinivasan
By using 5,15-porphodimethene metal complexes, the weak noncovalent anagostic interaction is explored using variable temperature NMR studies and is further confirmed by single crystal X-ray analysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

The energy transfer phenomena and colour tunability in Y2O2S:Eu3+/Dy3+ micro-fibers for white emission in solid state lighting applications

9 April, 2014 - 19:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00349G, PaperS. Som, P. Mitra, Vijay Kumar, Vinod Kumar, J. J. Terblans, H. C. Swart, S. K. Sharma
This paper reports on the structural, optical and photometric characterization of an Eu3+/Dy3+ doped yttrium oxysulfide phosphor (Y2O2S:Eu3+/Dy3+) for near white emission in solid state lighting.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ni2+ chemistry in pathogens -a possible target for eradication

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00421C, PerspectiveMagdalena Rowinska-Zyrek, Jolanta Zakrzewska-Czerwinska, Anna Zawilak-Pawlik, Henryk Kozlowski
The survival of all urease and/or hydrogenase containing pathogens depends on the proper homeostasis of nickel. In the scope of this perspectives paper, details of Ni2+ metabolism of Helicobacter pylori,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses and properties of 2-D and 3-D heterometallic Pb-Ag iodometallates decorated by ethylene polyamines at Pb(II) center

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00358F, PaperYali Shen, Jialin Lu, Chunying Tang, Fang Wang, Dingxian Jia, Yong Zhang
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
The content of this RSS Feed (c) The Royal Society of Chemistry

Immobilization of BiOX (X=Cl, Br) on activated carbon fibers as recycled photocatalysts

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00483C, CommunicationZaiyong Jiang, Baibiao Huang, Zaizhu Lou, Zeyan Wang, Xiaodong Meng, Yuanyuan Liu, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai
BiOX have been grown on the surface of activated carbon fibers (ACF) as recycled photocatalysts. The analysis results illustrate that the electrostatic adsorption plays an important role in the formation...
The content of this RSS Feed (c) The Royal Society of Chemistry

Three Mn(II) Coordination Polymers with a Bispyridyl-based Quinolinate Ligand: the Anion-Controlled Tunable Structural and Magnetic Properties

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00877D, PaperGuozan Yuan, Weilong Shan, Bin Liu, Lulu Rong, Liyan Zhang, Xianwen Wei
Three new Mn(II) coordination polymers, namely [Mn3L6[round bullet, filled]2H2O] (1), [MnL2] (2), and [MnL2[round bullet, filled]2H2O] (3), were prepared by hydrothermal reactions of Mn(II) salts with a bispyridyl-based quinolinate ligand. All complexes were characterized...
The content of this RSS Feed (c) The Royal Society of Chemistry

Ca3Be6B5O16F: the First Alkaline-Earth Beryllium Borate with Fluorine Anions

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00775A, PaperWenjiao Yao, Tao Xu, Xingxing Jiang, Hongwei Huang, Xiaoyang Wang, Zheshuai Lin, Chuangtian Chen
The first alkaline-earth beryllium borate with fluorine anions, Ca3Be6B5O16F, was synthesized by spontaneous crystallization flux method using LiF-B2O3 as flux. The structural framework of Ca3Be6B5O16F is composed of the inter-connected...
The content of this RSS Feed (c) The Royal Society of Chemistry

Improved magnetic and ferroelectric properties of Sc and Ti codoped multiferroic nano BiFeO3 prepared via sonochemical synthesis

9 April, 2014 - 19:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C3DT52779D, PaperDimple P. Dutta, B. P. Mandal, M. D. Mukadam, S. M. Yusuf, A. K. Tyagi
Sonochemically synthesized BiFe0.925Sc0.05Ti0.025O3 exhibits much better multiferroic properties compared to its undoped counterpart.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Formation of cyanate in low-valent uranium chemistry: A synergistic experimental/theoretical study

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00618F, PaperChristos E. Kefalidis, Alistair Frey, Mark Roe, Geoff Frederick Geoffrey Cloke, Laurent Maron
Computational studies on the reductive activation of a mixture of CO and NO by the U(III) complex [U([small eta]-C8H6{SiiPr3-1,4}2)([small eta]-Cp*)], which affords a mixture of [U([small eta]-C8H6{SiiPr3-1,4}2)([small eta]-Cp*)]2([small mu ]-OCN)2 1 and [U([small eta]-C8H6{SiiPr3-1,4}2)([small eta]-Cp*)]2([small mu ]-O) 2, show that...
The content of this RSS Feed (c) The Royal Society of Chemistry

Structural Characterization and Biological Evaluation of a Clioquinol-Ruthenium Complex with Copper-Independent Antileukaemic Activity

9 April, 2014 - 19:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT00463A, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Martina Gobec, Jakob Kljun, Izidor Sosic, Irena Mlinaric Rascan, Matija Ursic, Stanislav Gobec, Iztok Turel
In this study, we present the synthesis, biological characterization, and first crystal structure, of an organometallic-clioquinol complex. Combining ruthenium with the established apoptotic agent and 8-hydroxyquinoline derivative, clioquinol, resulted in...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.