Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 1 day 22 hours ago

Metal-organic frameworks based on the [1,1[prime or minute]:3[prime or minute],1[prime or minute][prime or minute]-terphenyl]-3,3[prime or minute][prime or minute],5,5[prime or minute][prime or minute]-tetracarboxylic acid ligand: syntheses, structures an

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15475-15481
DOI: 10.1039/C4DT02342K, PaperXiaofeng Lv, Lu Liu, Chao Huang, Li'an Guo, Jie Wu, Hongwei Hou, Yaoting Fan
Five coordination polymers containing transition metals (Mn, Co, Ni) and the organic ligand [1,1[prime or minute]:3[prime or minute],1[prime or minute][prime or minute]-terphenyl]-3,3[prime or minute][prime or minute],5,5[prime or minute][prime or minute]-tetracarboxylic acid (H4TPTA) were synthesized and characterized. Moreover, the magnetism of complexes 3-5 is also discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Non-covalent interactions in coinage metal complexes of 1,2,4-triazole-based N-heterocyclic carbenes

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15465-15474
DOI: 10.1039/C4DT01994F, PaperJan Turek, Illia Panov, Petr Svec, Zdenka Ruzickova, Ales Ruzicka
Non-covalent interactions were revealed in the complete series of coinage metal complexes of the type (NHC)MX (M = Cu, Ag, Au; X = Cl, Br, I) bearing 1,2,4-triazole based NHCs.
The content of this RSS Feed (c) The Royal Society of Chemistry

Hydrogen and halogen bonding in a concerted act of anion recognition: F- induced atmospheric CO2 uptake by an iodophenyl functionalized simple urea receptor

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15628-15637
DOI: 10.1039/C4DT00940A, PaperR. Chutia, G. Das
Halogen bonding plays a key role in the fixation of atmospheric CO2 because air-stable crystals of HCO3- dimer by a simple urea based para-iodo substituted acyclic receptor in the presence of n-TBA salt of F- in MeCN solution.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dihaloborenium cations stabilized by a four-membered N-heterocyclic carbene: electron deficiency compensation by asymmetric structural changes

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15313-15316
DOI: 10.1039/C4DT01210K, CommunicationMadelyn Qin Yi Tay, Balasubramanian Murugesapandian, Yunpeng Lu, Rakesh Ganguly, Kinjo Rei, Dragoslav Vidovic
Coordination of the four membered carbene ligand to electron deficient dihaloborenium moieties has resulted in asymmetric structural changes for the ligand's CN2P cyclic fragment.
The content of this RSS Feed (c) The Royal Society of Chemistry

Significantly enhanced dehydrogenation properties of calcium borohydride combined with urea

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15291-15294
DOI: 10.1039/C4DT01355G, CommunicationHailiang Chu, Shujun Qiu, Lin Liu, Yongjin Zou, Cuili Xiang, Huanzhi Zhang, Fen Xu, Lixian Sun, Huaiying Zhou, Guotao Wu
The Ca(BH4)2-4CO(NH2)2 system can release 8 equiv. or 5.2 wt% H2 at 250 [degree]C through a reaction between [BH4] and [NH2].
The content of this RSS Feed (c) The Royal Society of Chemistry

New insight into modulated up-conversion luminescent silica nanotubes as efficient adsorbents for colored effluents

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15457-15464
DOI: 10.1039/C4DT01552E, PaperXuejiao Li, Zhiyao Hou, Yang Zhang, Guo Zhang, Jianshe Lian, Jun Lin
Multicolor up-conversion luminescent SNTs were synthesized via electrospinning technique, and their behavior for the removal of colorful dyes was investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and physical properties of layered BaxCoO2

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15414-15418
DOI: 10.1039/C4DT01674B, PaperJinfeng Liu, Xiangyang Huang, Danfeng Yang, Guisheng Xu, Lidong Chen
A layered cobaltite BaxCoO2 (x = 0.19, 0.28, 0.30, 0.33) was synthesized by an ion exchange technique from the layered NaxCoO2 precursors.
The content of this RSS Feed (c) The Royal Society of Chemistry

Layered V-B-O polyoxometalate nets linked by diethylenetriamine complexes with dangling amine groups

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15283-15286
DOI: 10.1039/C4DT01533A, CommunicationHong Chen, Yunfeng Zhang, Zheng-Bao Yu, Junliang Sun
Dangling amine groups were found in the diethylenetriamine (DETA) metal complexes, which worked as linkers in the construction of two-dimensional V-B-O polyoxometalate.
The content of this RSS Feed (c) The Royal Society of Chemistry

Avoiding problem reactions at the ferrocenyl-alkyne motif: a convenient synthesis of model, redox-active complexes for molecular electronics

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15287-15290
DOI: 10.1039/C4DT02359E, CommunicationMichael S. Inkpen, Andrew J. P. White, Tim Albrecht, Nicholas J. Long
A much improved route to 1,1[prime or minute]-bis(arylethynyl)ferrocenes comprising accessible thiolates on the aryl ring is reported. Unanticipated reactions between AcCl, TBAF-BBr3 and ferrocenyl-alkynes are also discussed, offering a rationale for previous synthetic difficulties.
The content of this RSS Feed (c) The Royal Society of Chemistry

Tuning of the dimensional linkage from the complex to the framework by thermal conversion in the system Fe/Cl/piperazine

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15398-15406
DOI: 10.1039/C4DT01987C, PaperF. Schonfeld, R. Wirthensohn, H.-C. Schmitt, P. Constantinidis, I. Fischer, K. Muller-Buschbaum
An attempt to control the three structural features linkage, structural dimensionality and coordination mode is presented for the combination of FeII and FeIII chlorides together with the ditopic ligand piperazine (pipz).
The content of this RSS Feed (c) The Royal Society of Chemistry

Loop shaped dicarboxylate-bridged dimolybdenum(II) bisphosphine compounds - a rational synthesis

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15367-15374
DOI: 10.1039/C4DT01560F, PaperDominik Hohne, Eberhardt Herdtweck, Alexander Pothig, Fritz E. Kuhn
Starting from a loop shaped mixed carboxylate/acetonitrile ligated tetrametallic structure three novel bisphosphine-substituted dimolybdenum(II) coordination compounds can be synthesized, maintaining the original structural motif.
The content of this RSS Feed (c) The Royal Society of Chemistry

Co-molten solvothermal method for synthesizing chalcopyrite CuFe1-xCrxS2 (x [less-than-or-equal] 0.4): high photocatalytic activity for the reduction of nitrate ions

8 October, 2014 - 16:54

Dalton Trans., 2014, 43,15385-15390
DOI: 10.1039/C4DT02008A, PaperJia Yang, Mufei Yue, Jing Ju, Rihong Cong, Wenliang Gao, Tao Yang
CuFe1-xCrxS2 prepared by a thiourea-oxalic acid co-molten solvothermal method show superior UV-light photocatalytic activities toward nitrate ions reduction.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.