Dalton Transactions

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Three novel polyoxoanion-supported compounds: confinement of polyoxoanions in Ni-containing rigid concave surfaces with enhanced NLO properties

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18347-18353
DOI: 10.1039/C5DT02710A, PaperYayu Dong, Xiao Xu, Guangpeng Zhou, Hao Miao, GongHao Hu, Yan Xu
Three new polyoxometalates confined in metal-containing rigid concave surfaces were developed. All of them gave a strong third-order NLO response.
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A new ONO3- trianionic pincer ligand with intermediate flexibility and its tungsten alkylidene and alkylidyne complexes

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18475-18486
DOI: 10.1039/C5DT02911B, PaperSudarsan VenkatRamani, Ion Ghiviriga, Khalil A. Abboud, Adam S. Veige
This report details the synthesis and characterization of the semi-flexible [ONCH2O]H3 (1) ligand and its W(VI)-alkylidene and alkylidyne complexes.
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Naphthylaminoborane: from structural switches to frustrated Lewis pair reactivity

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18340-18346
DOI: 10.1039/C5DT02659H, PaperDaniel Pla, Omar Sadek, Sarah Cadet, Beatrice Mestre-Voegtle, Emmanuel Gras
Boron-nitrogen peri-substituted naphthyl scaffolds: small variations but different behaviours.
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Synthesis and behavior of novel sulfonated water-soluble N-heterocyclic carbene ([small eta]4-diene) platinum(0) complexes

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18360-18369
DOI: 10.1039/C5DT02622A, PaperAndrea M. Ruiz-Varilla, Edwin A. Baquero, Gustavo F. Silbestri, Camino Gonzalez-Arellano, Ernesto de Jesus, Juan C. Flores
Novel water-soluble (NHC)Pt(0)(1,6-diene) complexes are presented, along with details of their preparation, stability, and use as catalysts for the hydrosilylation of acetylenes in water.
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Redox induced colour changes between red-violet and blue in hetero-metal complexes of the type [CoII(4[prime or minute]-ferrocenyl-2,2[prime or minute];6[prime or minute]2[prime or minute][prime or minute]-terpyridine)2]X2 (X = counter anion)

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18354-18359
DOI: 10.1039/C5DT02592C, PaperKohei Takami, Ryo Ohtani, Masaaki Nakamura, Takayuki Kurogi, Manabu Sugimoto, Leonard F. Lindoy, Shinya Hayami
Cobalt complexes incorporating ferrocene-terpyridine ligands show a reversible color change in response to redox reactions involving the cobalt centers.
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Structural diversity of late transition metal complexes with flexible tetra-NHC ligands

25 October, 2015 - 15:54

Dalton Trans., 2015, 44,18329-18339
DOI: 10.1039/C5DT02386F, PaperDaniel T. Weiss, Philipp J. Altmann, Stefan Haslinger, Christian Jandl, Alexander Pothig, Mirza Cokoja, Fritz E. Kuhn
Silver complexes with flexible tetra-NHC ligands were used as transmetalation agent to access a series of d-block metal complexes.
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Compositional dependence of anomalous thermal expansion in perovskite-like ABX3 formates

21 October, 2015 - 14:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03263F, PaperInes E. Collings, Joshua A. Hill, Andrew B. Cairns, Richard I. Cooper, Amber L. Thompson, Julia E. Parker, Chiu C. Tang, Andrew L. Goodwin
Thermal expansion in ABX3 formates is correlated to the size and molecular anisotropy of the A- and B-site cations.
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