Dalton Transactions

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Chiral phenoxy-imino-amido aluminum complexes for the asymmetric cyanation of aldehydes.

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53292E, PaperJeremy Ternel, Francine Agbossou-Niedercorn, Regis Gauvin
The reactivity of triethylaluminum towards salicylaldimine sulfonamides was probed, affording well-defined complexes through consecutive protonolysis of two Al-C bonds by the proligand. These complexes when combined with an achiral anilinic...
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New type of Complex Alkali and Alkaline Earth Metal Borates with Isolated (B12O24)12- Anionic Group

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53115E, PaperHongping Wu, Hongwei Yu, Shi-Lie Pan, Anqing Jiao, Jian Han, Kui Wu, Shujuan Han, Hongyi Li
The compounds with the isolated anionic groups often exhibit special linear and nonliear optical properties and possess potential applications as birefringence, second harmonic generation and Stimulated Raman Scattering crystals. In...
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Quenching of fluorescence as an indicator of donor-strength in meso arylethynyl BODIPYs

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53056F, PaperRajneesh Misra, Bhausaheb Dhokale, Thaksen Jadhav, Mobin M Shaikh
A series of meso arylethynyl BODIPYs (2a-2h) were designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction. The effects of donor on the photophysical properties of the BODIPYs were explored....
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A spectroscopic study on the formation of Cm(III) acetate complexes at elevated temperatures

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52989D, PaperDaniel Robert Frohlich, Andrej Skerencak, Petra J. Panak
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Colourimetric and fluorescent detection of oxalate in water by a new macrocycle-based dinuclear nickel complex: A remarkable red shift of fluorescence band

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53467G, CommunicationMd Mhahabubur Rhaman, Frank R Fronczek, Douglas Powell, Md. Alamgir Hossain
A new macrocycle-based dinuclear nickel chemosensor selectively binds oxalate anions both in solution and solid state; displaying a remarkable red shift of the fluorescent band with visible colour change in...
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[IrCl{N(CHCHPtBu2)2}]-: A versatile source for the IrI(PNP) pincer platform

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53304B, PaperMarkus Kinauer, Markus G Scheibel, Josh Abbenseth, Frank W. Heinemann, Peter Stollberg, Christian Wurtele, Sven Schneider
Reduction of iridium(II) complex [IrCl{N(CHCHPtBu2)2}] is reduced by KC8 to give anionic iridium(I) pincer complex [IrCl{N(CHCHPtBu2)2}]- which was isolated and fully characterized upon stabilization of the counter caction with crown...
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Novel Germanetellones: XYGe=Te (X, Y=H, F, Cl, Br, I and CN) - Structures and Energetics. Comparison with the First Synthetic Successes

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52294F, PaperNaziah Bibi Jaufeerally, Hassan Hadi Abdallah, PROF. PONNADURAI RAMASAMI, Henry Schaefer
No stable germanetellone was described until Tbt(Dis)Ge=Te and Tbt(Tip)Ge=Te (Tbt=2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Dis=bis(trimethylsilyl)methyl and Tip=2,4,6-triisopropylphenyl) were reported in 1997. Following these initial experiments, there has arisen considerable interest in Ge=Te systems. An...
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