Dalton Transactions

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Pyrolytic cavitation, selective adsorption and molecular recognition of a porous Eu(III) MOF

6 October, 2014 - 16:17

Dalton Trans., 2014, 43,15305-15307
DOI: 10.1039/C4DT01434K, CommunicationWei-Ming Liao, Hua-Tian Shi, Xu-Hua Shi, Ye-Gao Yin
A channel-equipped metal-organic framework, resulting from pyrolysis of [(CH3)2NH2]@[Eu2L3(HCOO)], showed the preferable absorption of CO2 and the Eu(III)-based emission quenched by aromatics.
The content of this RSS Feed (c) The Royal Society of Chemistry

L-Selenomethionine reduces platinum(IV) anticancer model compounds at strikingly faster rates than L-methionine

6 October, 2014 - 16:17

Dalton Trans., 2014, 43,15328-15336
DOI: 10.1039/C4DT01528B, PaperShuying Huo, Jingran Dong, Shigang Shen, Yanli Ren, Changying Song, Jianzhong Xu, Tiesheng Shi
Reduction of Pt(IV) anticancer model compounds trans-[PtX2(CN)4]2- (X = Cl, Br) with L-selenomethionine proceeds at reaction rates 3.7 [times] 103-5.7 [times] 104 times faster than that with L-methionine.
The content of this RSS Feed (c) The Royal Society of Chemistry

Positional isomeric tunable two Co(II) 6-connected 3-D frameworks with pentanuclear to binuclear units: structures, ion-exchange and magnetic properties

6 October, 2014 - 16:17

Dalton Trans., 2014, 43,15450-15456
DOI: 10.1039/C4DT01086H, PaperMin-Le Han, Ya-Ping Duan, Dong-Sheng Li, Hai-Bin Wang, Jun Zhao, Yao-Yu Wang
{[Co5([small mu ]3-OH)2(m-pda)3(bix)4][middle dot]2ClO4}n (1) has the pcu open cationic framework with pentanuclear units while {[Co2(p-pda)2(bix)2(H2O)][middle dot]H2O}n (2) is the first msw framework based on binuclear units.
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