Dalton Transactions

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Fixed Distance Photoinduced Electron Transfer between Fe and Zn Porphyrins Encapsulated within the Zn HKUST-1 Metal Organic Framework

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02685C, CommunicationRandy W. Larsen, Lukasz Wojtas
An attractive strategy for the development of photocatalytic metal organic framework (MOF) materials is to co-encapsulate a photoactive electron donor with a catalytic electron acceptor within the MOF. Here we...
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Highly Stable and Sensitive LnMOF Ratiometric Thermometers Constructed with Mixed Ligands

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03421J, Paperwei yongqin, Rongjian Sa, Qiaohong Li, Wu Kechen
The mixed-lanthanide metal-organic frameworks (M'LnMOFs) applied for accurate, non-invasive and self-reference temperature measurements have been only recently recognized. It is a great challenge for chemists to fulfil thermostable structure, intense...
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Coordination Geometry of Lead Carboxylates - Spectroscopic and Crystallographic Evidence

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03075C, PaperJaclyn Catalano, Anna Murphy, Yao Yao, Glenn Yap, Nicholas Zumbulyadis, Silvia Centeno, Cecil Dybowski
Despite their versatility, only a few single-crystal X-ray structures of lead carboxylates exist, due to difficulties with solubility. In particular, the structures of long-chain metal carboxylates have not been reported....
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DOX-Cu9S5@mSiO2-PG composite fibers for orthotopic synergistic chemotherapy/photothermal tumor therapy

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03113J, PaperYinyin Chen, Zhiyao Hou, Bei Liu, shanshan huang, Chunxia Li, Jun Lin
A composite antitumor drug carrier platform, in which antitumor drug doxorubicin (DOX) loaded core-shell structured Cu9S5@mSiO2 nanoparticles were incorporated into poly([varepsilon]-caprolactone) (PCL) and Gelatin to form nanofibrous fabrics via electrospinning...
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L-lysine-assisted fabrication of PdxPt1-x/Ni(OH)2 (0 [less-than-or-equal] x [less-than-or-equal] 1) hybrids with composition-dependent catalytic properties

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03141E, PaperJiangman Zhen, Dapeng Liu, Xiao Wang, Junqi Li, Fan Wang, Yinghui Wang, Hongjie Zhang
A fast and facile self-assembly method has been developed to deposit 3-5 nm sized PdxPt1-x (0 [less-than-or-equal] x [less-than-or-equal] 1) nanoparticles (NPs) on Ni(OH)2 nanosheets. The biomolecule L-lysine has been...
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Sputtering-deposition of Ru nanoparticles onto Al2O3 modified with imidazolium ionic liquids: Synthesis, characterisation and catalysis

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03039G, PaperLucas Foppa, Leandro Luza, Aitor Gual, Daniel E Weibel, Dario Eberhardt, Sergio Ribeiro Teixera, Jairton Dupont
Well-distributed Ru nanoparticles (Ru-NPs) were produced over Al2O3 supports modified with covalently anchored imidazolium ionic liquids (ILs) containing different anions and cation lateral alkyl chain lengths by simple sputtering from...
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Antisite-disorder, magnetic and thermoelectric properties of Mo-rich Sr2Fe1-yMo1+yO6 (0 [less-than-or-equal] y [less-than-or-equal] 0.2) double perovskites

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03307H, PaperSrinivasa R. Popuri, Debbie Redpath, Gavin Chan, Ronald I. Smith, Oscar Cespedes, Jan-Willem G. Bos
A-site deficiency does not survive in Sr2-xFeMoO6 and instead Mo-rich Sr2Fe1-yMo1+yO6 perovskites, characterised by the gradual disordering of Fe and Mo, form.
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Exploring the effect of axial ligand substitution (X = Br, NCS, CN) on the photodecomposition and electrochemical activity of [MnX(N-C)(CO)3] complexes

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03079F, PaperJay Agarwal, Charles J. Stanton III, Travis W. Shaw, Jonathon E. Vandezande, George F. Majetich, Andrew B. Bocarsly, Henry F. Schaefer III
Four new Mn(I)-NHC compounds are tested for light stability and catalytic efficiency for reducing CO2 to CO.
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Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03508A, PaperSalah S. Massoud, Mark Spell, Catherine C. Ledet, Thomas Junk, Radovan Herchel, Roland C. Fischer, Zdenek Travnicek, Franz A. Mautner
Five new dinuclear bridged-phenoxido dichlorido-metal(II) complexes [M2([small mu ]-LClO)(X)2Cl2]PF6/ClO4 complexes, where M(II) = Co, Ni, Cu (1-4) and Zn (5); X = CH3OH, H2O or 0 were synthesized and structurally characterized. Complexes 1-4 revealed weak to moderate antiferromagnetic coupling.
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Blue phosphorescent N-heterocyclic carbene chelated Pt(II) complexes with an [small alpha]-duryl-[small beta]-diketonato ancillary ligand

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03085K, PaperSoo-Byung Ko, Hee-Jun Park, Shaolong Gong, Xiang Wang, Zheng-Hong Lu, Suning Wang
Blue phosphorescent Pt(II) complexes that display bright blue emission in the solid state have been obtained employing NHC-based C[logical and]C*-chelate ligands and an [small alpha]-duryl-[small beta]-diketonato ancillary ligand that provides steric blocking to minimize intermolecular interactions.
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Anion complexation, transport and structural studies of a series of bis-methylurea compounds

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02893G, PaperMartina Olivari, Riccardo Montis, Louise E. Karagiannidis, Peter N. Horton, Lucy K. Mapp, Simon J. Coles, Mark E. Light, Philip A. Gale, Claudia Caltagirone
A new family of bis-methylureas have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied.
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Manganese-calcium clusters supported by calixarenes

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02952F, PaperRebecca O. Fuller, George A. Koutsantonis, Ivan Lozic, Mark I. Ogden, Brian W. Skelton
An investigation inspired by the structure of the oxygen-evolving complex of photosystem II has resulted in the isolation and structural characterization of the first examples of Mn/Ca clusters supported by a calixarene ligand.
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Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03467H, CommunicationJeremy Michael Rawson, Melanie Pilkington, John J Hayward, Bryce Jackson Leontowicz, Muhammad Usman Anwar, Ewan Clark
Cu2+-promoted aerial oxidation of a series of benzothiadiazines (1) under ambient conditions affords the first structurally characterised examples of thiadiazine S-oxides (2) The isolation of the homoleptic CuII 3-(2ʹ-pyridyl)benzothiadiazide-S-oxide complex...
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Helix-Coil Transition Induced by Metal Ion Interaction with a Grafted Iron-Binding Site of the CyaY Protein Family

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02796E, PaperDiego Sebastian Vazquez, William Armando Agudelo, Angel Yone, Nora Vizioli, Martin Aran, Luis Gonzalez Flecha, Mariano Camilo Gonzalez Lebrero, Javier Santos
Iron-protein interactions are involved in electron transfer reactions. Alterations of these processes are present in a number of human pathologies; among then, in Friedreich's ataxia, in which a deficiency in...
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CPMV induced synthesis of Hollow-porous SiO2 Nanocapsules with excellent performance in Drug delivery

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02549K, PaperKoushi Kumar, Pradip Paik
An idiosyncratic hollow mesoporous-SiO2 nanocapsule has been synthesized at room temperature using unmodified Cowpea mosaic Virus (CPMV) as a template, and without using any catalyst or surfactant during synthesis. The...
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Catalytic Behaviour in the Ring-Opening Polymerisation of Organoaluminiums Supported by Bulky Heteroscorpionate Ligands

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03475A, PaperAntonio Otero, Jose Castro Osma, Carlos Alonso-Moreno, agustin lara, juan fernandez, LUIS FERNANDO SANCHEZ-BARBA MERLO, Ana Maria Rodriguez
A series of alkyl organoaluminium complexes based on bulky heteroscorpionate ligands were designed as catalysts for the ring-opening polymerisation of cyclic esters. Thus, treatment of AlX3 (X = Me, Et)...
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Ionothermal Synthesis and Crystal Structures of Novel Aluminum Phosphates with in Situ Generated Templates

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03233K, PaperShanshan Man, wang zeng long, Boya Zhao, Lei Liu, Jinxiang Dong
Protic ionic liquids (PILs) are subgroup of ionic liquids and easily formed by proton transfer from a Bronsted acid to a Bronsted base. Two new crystalline aluminumphosphates, [C5H16N2][Al(PO4)(HPO4)] (AlPO-PIL1) and...
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Cationic, luminescent cyclometalated iridium(III) complexes based on substituted 2-phenylthiazole ligands

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03054K, PaperEmily C. Stokes, Emily E. Langdon-Jones, Lara M. Groves, James A. Platts, Peter N. Horton, Ian A. Fallis, Simon J. Coles, Simon J. A. Pope
Ten cationic heteroleptic iridium(III) complexes involving substituted phenylthiazole ligands reveal phosphorescence emission in solution.
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Synthesis, Structure, and Properties of Dialumane Supported by Pyrazolate Ligands

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03533J, CommunicationChristopher Snyder, Peter Zavalij, Kit H Bowen, Hansgeorg Schnoeckel, Bryan W Eichhorn
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Bi2Te(IO3)O5Cl: A Novel Polar Iodate Oxychloride Exhibiting A Second-Order Nonlinear Optical Response

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03532A, PaperLei Geng, Chang Yu Meng, Hong Yan Lu, Zhong-Zhen Luo, Chensheng Lin, Wen-Dan Cheng
The novel iodate oxychloride, Bi2Te(IO3)O5Cl, has been hydrothermally synthesized and structurally characterized. The compound crystallizes in the polar monoclinic space group Cc with a = 22.037(8) A, b = 5.256(2)...
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