Dalton Transactions

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RSC - Dalton Trans. latest articles
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Employing a new 12-connected topological open-framework copper borovanadate as an effective heterogeneous catalyst for oxidation of benzyl-alkanes

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18731-18736
DOI: 10.1039/C5DT03425F, CommunicationYuquan Feng, Chenghua Ding, Huitao Fan, Zhiguo Zhong, Dongfang Qiu, Hengzhen Shi
The compound not only features the first 3-D copper(II) borovanadate which possesses the largest ratio of TM2+ and borovanadate anion, but also displays highly catalytic activities for the oxidation of benzyl-alkanes.
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Assembly and stabilization of {E(cyclo-P3)2} (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units

31 October, 2015 - 17:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03383G, PaperAlexandra Velian, Brandi M. Cossairt, Christopher C. Cummins
The reaction chemistry of complexes (THF)0-2E[P3Nb(ODipp)3]2 (E = Sn, Pb; Dipp = 2,6-iPr2C6H3) featuring the metallophosphide ligand {E(cyclo-P3)2} is investigated.
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Electropolymerizable peripherally tetra-{2-[3-(diethylamino)phenoxy]ethoxy} substituted as well as axially (4-phenylpiperazin-1-yl)propanoxy-disubstituted silicon phthalocyanines and their electrochemistry

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18993-18999
DOI: 10.1039/C5DT03421C, PaperZekeriya Biyiklioglu, Hakan Alp
A novel type of peripherally tetra-substituted as well as axially disubstituted silicon(IV) phthalocyanine containing electropolymerizable ligands was designed and synthesized for the first time.
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Imido-hydrido complexes of Mo(IV): catalysis and mechanistic aspects of hydroboration reactions

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18945-18956
DOI: 10.1039/C5DT02945G, PaperAndrey Y. Khalimon, Philip M. Farha, Georgii I. Nikonov
Stoichiometric reaction of complexes (ArN)Mo(H)(Cl)(PMe3)3 (1) and (ArN)Mo(H)2(PMe3)3 (3) with nitriles and HBCat suggest that catalytic hydroboration reactions proceed via a series of agostic borylamido and borylamino complexes.
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Water stable triazolyl phosphonate MOFs: steep water uptake and facile regeneration

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18727-18730
DOI: 10.1039/C5DT02651B, CommunicationS. Begum, S. Horike, S. Kitagawa, H. Krautscheid
Triazole and phosphonate donors connect Co2+ ions to a water stable 3D framework with hydrophilic nanopores featuring water uptake at low relative pressure.
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A urea-assisted template method to synthesize mesoporous N-doped CeO2 for CO2 capture

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18718-18722
DOI: 10.1039/C5DT03562G, CommunicationYangang Wang, Chaochuang Yin, Hengfei Qin, Yunzhu Wang, Yaguang Li, Xi Li, Yuanhui Zuo, Shifei Kang, Lifeng Cui
Novel mesoporous nitrogen doped CeO2 has been prepared via a simple urea-assisted template method. The synthesized N-doped mesoporous CeO2 exhibits significantly enhanced CO2 adsorption capacity compared to undoped mesoporous CeO2.
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Composite of K-doped (NH4)2V3O8/graphene as an anode material for sodium-ion batteries

31 October, 2015 - 17:17

Dalton Trans., 2015, 44,18864-18869
DOI: 10.1039/C5DT03239C, PaperXin Liu, Zhiwei Li, Hailong Fei, Mingdeng Wei
The K-doped (NH4)2V3O8/graphene electrode exhibited stable cycling and a good rate performance.
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Understanding gate adsorption behaviour of CO2 on elastic layer-structured metal-organic framework-11

29 October, 2015 - 16:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03476K, PaperShotaro Hiraide, Hideki Tanaka, Minoru T. Miyahara
We demonstrate that CO2 gate adsorption behaviour of elastic layer-structured metal-organic framework-11 can be described by a thermodynamic model by free energy analysis with the aid of an adsorption experiment and a molecular simulation.
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Structure and properties of Al-MIL-53-ADP, a breathing MOF based on the aliphatic linker molecule adipic acid

29 October, 2015 - 16:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03510D, PaperHelge Reinsch, Renjith S. Pillai, Renee Siegel, Jurgen Senker, Alexandra Lieb, Guillaume Maurin, Norbert Stock
A new breathing Al-MIL-53 framework incorporating adipic acid as linker molecules is reported and characterised in detail.
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The guest-dependent thermal response of the flexible MOF Zn2(BDC)2(DABCO)

29 October, 2015 - 16:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT03710G, PaperYonghwi Kim, Ritesh Haldar, Hyunuk Kim, Jaehyoung Koo, Kimoon Kim
The flexible MOF, Zn2(BDC)2(DABCO) presents unusual guest-dependent structural responses upon temperature changes.
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Phase development during high-energy ball-milling of zinc oxide and iron - the impact of grain size on the source and the degree of contamination

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18870-18881
DOI: 10.1039/C5DT02498F, PaperG. Stefanic, S. Krehula, I. Stefanic
The impact of grain size on the source and the degree of contamination.
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Time-resolved laser fluorescence spectroscopy of UO2(CO3)34-

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18831-18838
DOI: 10.1039/C5DT02873F, PaperE. C. Jung, H.-R. Cho, M. H. Baik, H. Kim, W. Cha
We confirmed the luminescence characteristics of UO2(CO3)34- in the hindrance to the observation of the luminescence spectra. Previous studies are discussed.
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Structures and multiple properties of two polar metal-organic frameworks based on achiral N,O-coordinated ligands: toward multifunctional materials

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18882-18892
DOI: 10.1039/C5DT02374B, PaperGuang-Ning Liu, Ming-Jian Zhang, Wan-Qing Liu, Hui Sun, Xin-Yu Li, Ke Li, Cai-Ze Ren, Zhen-Wei Zhang, Cuncheng Li
Reported here are two polar MOFs with combined PL and SHG response or combined antiferromagnetism and photocatalysis properties.
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How a novel tyrosine-heme cross-link fine-tunes the structure and functions of heme proteins: a direct comparitive study of L29H/F43Y myoglobin

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18815-18822
DOI: 10.1039/C5DT03040D, PaperDao-Jing Yan, Hong Yuan, Wei Li, Yu Xiang, Bo He, Chang-Ming Nie, Ge-Bo Wen, Ying-Wu Lin, Xiangshi Tan
Two heme proteins differing only in a novel Tyr-heme cross-link were obtained by the same protein scaffold of L29H/F43Y myoglobin.
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Spin crossover in iron(II) complexes with ferrocene-bearing triazole-pyridine ligands

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18911-18918
DOI: 10.1039/C5DT03084F, PaperTania Romero-Morcillo, Francisco Javier Valverde-Munoz, Lucia Pineiro-Lopez, M. Carmen Munoz, Tomas Romero, Pedro Molina, Jose A. Real
Thermal- and light-induced spin crossover properties of two iron(II) complexes derived from a ferrocene-appended triazole-pyridine ligand are described.
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Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{[small mu ]-(XCH2)2CRR[prime or minute]}] hydrogenase models (X = S, Se)

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18780-18794
DOI: 10.1039/C5DT01387A, PaperRalf Trautwein, Laith R. Almazahreh, Helmar Gorls, Wolfgang Weigand
Investigations of the electrochemical properties of [Fe2(CO)6{[small mu ]-(XCH2)2CRR[prime or minute]}] (X = S, Se; R or R[prime or minute] = H or Me) showed that the complex with the bulkiest CMe2 moiety undergoes reduction with potential inversion.
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Spatial distribution of phases during gradual magnetostructural transitions in copper(II)-nitroxide based molecular magnets

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18823-18830
DOI: 10.1039/C5DT03441H, PaperMatvey V. Fedin, Sergey L. Veber, Elena G. Bagryanskaya, Galina V. Romanenko, Victor I. Ovcharenko
A thorough analysis of EPR and XRD data led to conclusions on the spatial distribution of phases in copper-nitroxide molecular magnets.
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Tuning the target composition of amine-grafted CPO-27-Mg for capture of CO2 under post-combustion and air filtering conditions: a combined experimental and computational study

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18970-18982
DOI: 10.1039/C5DT03137K, PaperM. C. Bernini, A. A. Garcia Blanco, J. Villarroel-Rocha, D. Fairen-Jimenez, K. Sapag, A. J. Ramirez-Pastor, G. E. Narda
A computational and experimental study is performed to determine the optimal composition that enhances the adsorption performance at low pressure.
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Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18810-18814
DOI: 10.1039/C5DT02337H, PaperYanlong Wang, Yuxiang Li, Zhuanling Bai, Chengliang Xiao, Zhiyong Liu, Wei Liu, Lanhua Chen, Weiwei He, Juan Diwu, Zhifang Chai, Thomas E. Albrecht-Schmitt, Shuao Wang
Microporous SCU-3 is synthesized with high SHG efficiency and Th4+ sequestration potential.
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Luminescence, magnetocaloric effect and single-molecule magnet behavior in lanthanide complexes based on a tridentate ligand derived from 8-hydroxyquinoline

29 October, 2015 - 16:54

Dalton Trans., 2015, 44,18893-18901
DOI: 10.1039/C5DT02894A, PaperHai-Yun Shen, Wen-Min Wang, Yan-Xia Bi, Hong-Ling Gao, Shuang Liu, Jian-Zhong Cui
New lanthanide complexes based on a tridentate ligand derived from 8-hydroxyquinoline were synthesized. Luminescence properties and single-molecule magnet behavior were investigated.
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