Dalton Transactions

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Chiral phenoxy-imino-amido aluminum complexes for the asymmetric cyanation of aldehydes.

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53292E, PaperJeremy Ternel, Francine Agbossou-Niedercorn, Regis Gauvin
The reactivity of triethylaluminum towards salicylaldimine sulfonamides was probed, affording well-defined complexes through consecutive protonolysis of two Al-C bonds by the proligand. These complexes when combined with an achiral anilinic...
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New type of Complex Alkali and Alkaline Earth Metal Borates with Isolated (B12O24)12- Anionic Group

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53115E, PaperHongping Wu, Hongwei Yu, Shi-Lie Pan, Anqing Jiao, Jian Han, Kui Wu, Shujuan Han, Hongyi Li
The compounds with the isolated anionic groups often exhibit special linear and nonliear optical properties and possess potential applications as birefringence, second harmonic generation and Stimulated Raman Scattering crystals. In...
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Quenching of fluorescence as an indicator of donor-strength in meso arylethynyl BODIPYs

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53056F, PaperRajneesh Misra, Bhausaheb Dhokale, Thaksen Jadhav, Mobin M Shaikh
A series of meso arylethynyl BODIPYs (2a-2h) were designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction. The effects of donor on the photophysical properties of the BODIPYs were explored....
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A spectroscopic study on the formation of Cm(III) acetate complexes at elevated temperatures

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52989D, PaperDaniel Robert Frohlich, Andrej Skerencak, Petra J. Panak
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Colourimetric and fluorescent detection of oxalate in water by a new macrocycle-based dinuclear nickel complex: A remarkable red shift of fluorescence band

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53467G, CommunicationMd Mhahabubur Rhaman, Frank R Fronczek, Douglas Powell, Md. Alamgir Hossain
A new macrocycle-based dinuclear nickel chemosensor selectively binds oxalate anions both in solution and solid state; displaying a remarkable red shift of the fluorescent band with visible colour change in...
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[IrCl{N(CHCHPtBu2)2}]-: A versatile source for the IrI(PNP) pincer platform

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53304B, PaperMarkus Kinauer, Markus G Scheibel, Josh Abbenseth, Frank W. Heinemann, Peter Stollberg, Christian Wurtele, Sven Schneider
Reduction of iridium(II) complex [IrCl{N(CHCHPtBu2)2}] is reduced by KC8 to give anionic iridium(I) pincer complex [IrCl{N(CHCHPtBu2)2}]- which was isolated and fully characterized upon stabilization of the counter caction with crown...
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Novel Germanetellones: XYGe=Te (X, Y=H, F, Cl, Br, I and CN) - Structures and Energetics. Comparison with the First Synthetic Successes

2 January, 2014 - 19:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52294F, PaperNaziah Bibi Jaufeerally, Hassan Hadi Abdallah, PROF. PONNADURAI RAMASAMI, Henry Schaefer
No stable germanetellone was described until Tbt(Dis)Ge=Te and Tbt(Tip)Ge=Te (Tbt=2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, Dis=bis(trimethylsilyl)methyl and Tip=2,4,6-triisopropylphenyl) were reported in 1997. Following these initial experiments, there has arisen considerable interest in Ge=Te systems. An...
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Production of reactive oxygen and nitrogen species by light irradiation of a nitrosyl phthalocyanine ruthenium complex as a strategy for cancer treatment

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52217B, PaperRoberto Santana da Silva, Tassiele Andrea Heinrich, Antonio Tedesco, Jon Fukuto
Production of reactive oxygen species have been used in clinical therapy for cancer treatment in a technique known as Photodynamic Therapy (PDT. The success of this therapy depends on oxygen...
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Role of different platinum precursors on formation and reaction mechanism of FePt nanoparticles and their electrocatalytic performance towards methanol oxidation

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53147C, PaperNiroj K Sahu, Anand Prakash, Dhirendra Bahadur
We report the formation mechanism of FePt nanoparticles (NPs) by high temperature polyol method using equimolar ratio of Fe and Pt-precursor with different Pt-precursors. Pt(acac)2, PtCl2, PtCl4 and H2PtCl6.H2O were...
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Evaluation of nickel ferrite nanoparticles coated with oleylamine by NMR relaxation measurements and magnetic hyperthermia

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52860J, PaperCatherine Dendrinou-Samara, Melita Menelaou, Katerina Georgoula, Konstantinos Simeonidis
Νickel ferrite nanoparticles were synthesized via a facile solvothermal approach. Oleylamine (OAm) was used in all synthetic procedures as a stabilizing agent and solvent. By varying the polarity of the...
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Novel nickel metal-organic framework with fluorite-like structure: Gas adsorption properties and catalytic activity in Knoevenagel condensation

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52698D, PaperMiroslav Almasi, Vladimir Zelenak, Maksym Opanasenko, Jiri Cejka
New non-interpenetrating 3D metal-organic framework {[Ni4([small mu ]6-MTB)2([small mu ]2-H2O)4(H2O)4] ∙10DMF∙11H2O}n (DMF = N,N´-dimethylformamide) built from nickel(II) ions as connectors and methanetetrabenzoate ligands (MTB4-) as linkers has been synthesized and characterized. The single crystal...
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Layered zeolitic materials: An approach to design versatile functional solids.

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53181C, PerspectiveAvelino Corma, Urbano Manuel Diaz
Along this perspective article, the most relevant layered zeolites have been analyzed from the point of view of the synthesis methodologies, materials characterization and catalytic implications, considering the unique physico-chemical...
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Computational insights in carbon-carbon homocoupling reactions mediated by organolanthanide(III) complexes

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52937A, PaperChristos E. Kefalidis, Lionel Perrin, Laurent Maron
Homocoupling of terminal alkynes into trienediyl complexes by alkyl samarocenes is known experimentally. By means of computational techniques, we investigated the mechanism of this reaction in detail. The overall reaction...
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Binding multidentate ligands to Ni2+: kinetic identification of preferential binding sites

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53359J, PaperDilek Nartrop, William Clegg, Ross Harrington, R A Henderson, Corinne Wills
The kinetics of the reactions between [Ni(MeOH)6]2+ (hereafter Ni2+) and a variety of neutral Schiff base multidentate ligands have been measured in methanol at 25.0 [degree]C using stopped-flow spectrophotometry. The...
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Dendritic CdS assembles for removal of organic dye molecules

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53256A, PaperXiang Wu, Zhou Yu, Fengyu Qu
In this paper, novel CdS 3D assemblies are prepared via a facile and effective hydrothermal route using dimethyl sulfoxide as the growth template. Morphologies, microstructures and photocatalytic properties of the...
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Guidance of growth mode and structural character in organic-inorganic hybrid materials - a comparative study

31 December, 2013 - 18:54
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52391H, PaperKarina Barnholt Klepper, Ola Nilsen, Simon Francis, Helmer Fjellvag
A main goal in the construction of thin films is control over the film growth in all aspects. Accurate control of the building blocks and their reaction sites is a...
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