Dalton Transactions

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Facile fabrication of heterostructured g-C3N4/Bi2MoO6 microspheres with highly efficient activity under visible light irradiation

5 January, 2015 - 17:17

Dalton Trans., 2015, 44,1601-1611
DOI: 10.1039/C4DT02127D, PaperTao Yan, Qing Yan, Xiaodong Wang, Hongye Liu, Mengmeng Li, Shixiang Lu, Wenguo Xu, Meng Sun
A facile and template-free solvothermal method was developed for the synthesis of microspheric g-C3N4/Bi2MoO6 photocatalysts.
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Gas-Phase Reaction of CeVO5+ Cluster Ions with C2H4: Reactivity of Cluster Bonded Peroxides

3 January, 2015 - 16:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03398A, PaperJia-Bi Ma, Jing-Heng Meng, Sheng-Gui He
Cerium-vanadium oxide cluster cations CeVO5+ were generated by laser ablation, mass-selected by a quadrupole mass filter, thermalized through collisions with helium atoms, and then reacted with ethene molecules in a...
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Core Substituted Naphthalene Diimide - Metallo Bisterpyridine Supramolecular Polymers: Synthesis, Photophysics and Morphology

3 January, 2015 - 16:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02719A, PaperHamideh Shokouhi Mehr, Natalie C Romano, Rashid Altimimi, Jody M Modarelli, David A. Modarelli
A series of metallo Ru(II), Fe(II), Co(II) bisterpyridine polymers were prepared with naphthalene diimide (NDI) groups inserted between two 4ʹ-phenyl-2,2:6ʹ,2ʹʹ-terpyridine (phtpy) groups. Core-substituted NDIs typically have long-lived excited states with...
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Thermoelectric properties and chlorine doping effect of In4Pb0.01Sn0.03Se2.9Clx polycrystalline compounds

3 January, 2015 - 16:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03432E, PaperJin Hee Kim, Min Jae Kim, Suekyung Oh, Jong-Soo Rhyee, Su-Dong Park, Docheon Ahn
We investigated thermoelectric properties of the Cl-doped polycrystalline compounds of In4Pb0.01Sn0.03Se2.9Clx (x = 0.02, 0.04, and 0.06). The x-ray diffraction measurement shows gradual change of lattice volume for x [less-than-or-equal]...
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Controlling the redox properties of a pyrroloquinolinequinone (PQQ) derivative in a ruthenium(II) coordination sphere

3 January, 2015 - 16:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03358B, PaperHiroumi Mitome, Tomoya Ishizuka, Yoshihito Shiota, Kazunari Yoshizawa, Takahiko Kojima
Ruthenium(II) complexes of PQQTME, a trimethyl ester derivative of redox-active PQQ (pyrroloquinolinequinone), were prepared using a tridentate ligand, 2,2':6',2''-terpyridine (terpy) as an auxiliary ligand. Characterization of the complexes was made...
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Synthesis Methods to Prepare Single- and Multi-core Iron Oxide Nanoparticles for Biomedical Applications

3 January, 2015 - 16:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03013C, PerspectiveLucia Gutierrez, Rocio Costo, Cordula Gruettner, Fritz Westphal, Nicole Gehrke, David Heinke, Andrea Fornara, Quentin Andrew Pankhurst, Christer Johansson, Sabino Veintemillas-Verdaguer, M. Puerto Morales
We review current synthetic routes to magnetic iron oxide nanoparticles for biomedical applications. We classify the different approaches used depending on their ability to generate magnetic particles that are either...
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Four linear CuII3 subunit-based coordination polymers with various inter-subunit connections, spin ground-states and intra-/inter-subunit magnetic couplings

1 January, 2015 - 14:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03741C, PaperEn-Cui Yang, Zhong-Yi Liu, Si-Hang Chen, Yan-Hong Su, Yan-Yan Zhang, Xiao-Jun Zhao
Four new 4-amino-1,2,4-triazole (atr)-based coordination polymers, {[Cu2(atr)(H2O)([small mu ]-OH)2(pa)][round bullet, filled]H2O}n (1), {[Cu3(atr)2(H2O)2([small mu ]-OH)2(npa)2][round bullet, filled]2H2O}n (2), {[Cu3(atr)5(dca)([small mu ]-OH)(ClO4)2](ClO4)2}n (3) and {[Cu3(atr)2(H2O)([small mu ]3-OH)([small mu ]-OH)2(spa)]∙1.5H2O}n (4) (pa2- = phthalate, npa2- = 3-nitrophthalate, dca- = dicyanamide and spa3- = 4-sulfophthalate), were successfully...
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Pyrazine-imide complexes: reversible redox and MOF building blocks

1 January, 2015 - 14:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03407D, PaperSally Brooker, Matthew G Cowan, Reece G Miller
The synthesis of the symmetric pyrazine imide ligand, N-(2-pyrazylcarbonyl)-2-pyrazinecarboxamide, (Hdpzca) and five new first row transition metal complexes of it are reported: [MII(dpzca)2], MII = Fe, Cu, Zn; {[CuII(dpzca)(H2O)n]1 or...
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Overcoming crystallographically imposed geometrical restrictions on the valence state of Eu in CaGdAlO4: realization of white light emission from singly-doped Eu phosphors

1 January, 2015 - 14:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03095H, CommunicationYang Zhang, Xiaoming Liu, Xuejiao Li, Kai Li, Hongzhou Lian, Mengmeng Shang, Jun Lin
The crystallographically imposed geometrical restrictions on the valence state of Eu in CaGdAlO4 has been overcome by the replacement of Al3+-Gd3+ with Si4+-Ca2+.
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