Dalton Transactions

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Highly efficient degradation of dye pollutants by Ce-doped MoO3 catalyst at room temperature

11 August, 2014 - 02:17

Dalton Trans., 2014, 43,12860-12870
DOI: 10.1039/C4DT01012D, PaperYujian Jin, Na Li, Haiqiu Liu, Xia Hua, Qiuying Zhang, Mindong Chen, Fei Teng
A novel energy-saving degradation reaction for dye pollutants over Ce-doped MoO3 catalyst.
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1,2,3-Triazolylidene ruthenium(II)([small eta]6-arene) complexes: synthesis, metallation and reactivity

11 August, 2014 - 02:17

Dalton Trans., 2014, 43,12842-12850
DOI: 10.1039/C4DT01174K, PaperBidraha Bagh, Adam M. McKinty, Alan J. Lough, Douglas W. Stephan
Three bis(1,2,3-triazolylidene) silver(I) complexes were reacted with [RuCl2(p-cymene)]2 and the ruthenium complexes [RCH2N2(NMe)C2Ph]RuCl2(p-cymene) (R = C6H2Me34a1, C6H2iPr34b1, Ph 4c1) were isolated as major products with the minor C(sp2)-H activated products [RCH2N2(NMe)C2C6H4]RuCl(p-cymene) (R = C6H2Me34a2, C6H2iPr34b2, Ph 4c2) and [(C6H4)CH2N2(NMe)C2Ph]RuCl(p-cymene) (4c3).
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Activation of the C-N bond of N-heterocyclic carbenes by inorganic elements

11 August, 2014 - 02:17

Dalton Trans., 2014, 43,12820-12823
DOI: 10.1039/C4DT00946K, FrontierKalon J. Iversen, David J. D. Wilson, Jason L. Dutton
This frontier article summarizes the recent activity around a new mode of reactivity for N-heterocyclic carbenes: insertion of inorganic elements into the C-N bond of the carbene ring.
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Encapsulation and Stabilization of Polyoxometalates in Self-Assembled Supramolecular Hydrogels

7 August, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01372G, CommunicationVamangi M Pandya, Ulrich Kortz, Sachin Arun Joshi
We have encapsulated the polyoxoanions [P2W18O62]6- and [P2W15V3O62]9- in a self-assembled carboxy-methyl-chitosan (CMC) hydrogel, exhibiting a regular super-structure in water at physiological pH. We performed stability studies as a function...
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