Dalton Transactions

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Bifunctional 64Cu-labelled macrobicyclic cage amine isothiocyanates for immuno-positron emission tomography

3 November, 2014 - 23:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02983F, PaperBrett M. Paterson, Gojko Buncic, Lachlan E. McInnes, Peter Roselt, Carleen Cullinane, David S. Binns, Charmaine M. Jeffery, Roger I. Price, Rodney J. Hicks, Paul S. Donnelly
Sarcophagine ligands with isothiocyanate functional groups were conjugated to trastuzumab, radiolabelled with 64Cu and used to image HER2-positive tumours using PET.
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Controlled translocation of palladium(II) within a 22 ring atom macrocyclic ligand

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17006-17016
DOI: 10.1039/C4DT00765D, PaperMichael G. Burgess, M. Naveed Zafar, Stephen T. Horner, George R. Clark, L. James Wright
Palladium can be directed to coordinate to the "tail" region of the macrocycle H4L to give 3b. Translocation of the palladium from the tail coordination pocket to the head coordination pocket occurs on treatment with amines such as n-BuNH2 to give 4.
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Synchrotron applications to f-element research in the nuclear fuel cycle

3 November, 2014 - 23:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02716G, PaperMelissa Anne Denecke
Synchrotron-based techniques are increasingly used to characterize radioactive materials and elucidate determinant processes relevant to the nuclear fuel cycle. Many recent advances are driven by the need to characterize such...
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Tuning the Coordination Properties of Phenothiazine by Regioselective Introduction of Diphenylphosphanyl Groups

3 November, 2014 - 23:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02665A, PaperLuminita Silaghi-Dumitrescu, Iudit Hajnal Filip, Emese Gal, Iulia Lupan, Maria Perde Schrepler, Peter Lonnecke, Mihai Surducan, Luiza Gaina, Eva Hey-Hawkins
The palladium and platinum complexes of the newly synthesized 1-(diphenylphosphino)-10-methyl-10H-phenothiazine (1) and the previously reported 3-(diphenylphosphino)-10-alkyl-10H-phenothiazine [alkyl=Me (2), Et (3)] and 4-(diphenylphosphino)-10-ethyl-10H-phenothiazine (4) were prepared. Density functional calculations were carried...
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Influence of lithium concentration on the structure and Li+ transport properties of cubic phase lithium garnets

3 November, 2014 - 23:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02861A, PaperMurugan Ramaswamy, Ramakumar S, janani N
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Stable anode performance of vanadium oxide hydrate semi-microspheres and their graphene based composite microspheres in sodium-ion batteries

3 November, 2014 - 23:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02988G, PaperHailong Fei, Zhiwei Li, Wenjing Feng, Xin Liu
A novel graphene based VO2 hydrate anode material delivers a high capacity for sodium-ion batteries.
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Meridional vs. facial coordination geometries of a dipodal ligand framework featuring a secondary coordination sphere

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,16992-16995
DOI: 10.1039/C4DT02327G, CommunicationEllen M. Matson, Zachary Gordon, Benjamin Lin, Mark J. Nilges, Alison R. Fout
Ligation of bipyridine invokes a conformational change in iron and copper complexes.
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A perception of ferro- and antiferromagnetic interactions in a two dimensional Ni(II) heterochiral coordination polymer showing unusual CO2 uptake behavior

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,16996-16999
DOI: 10.1039/C4DT02496F, CommunicationHimanshu Sekhar Jena, Soumyabrata Goswami, Suresh Sanda, Srinivasulu Parshamoni, Soumava Biswas, Sanjit Konar
A robust 2D heterochiral Ni(II) coordination polymer is reported which shows ferro-, antiferromagnetic interactions and unusual CO2 uptake behavior.
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Correction: Reversible CO exchange at platinum(0). An example of similar complex properties produced by ligands with very different stereoelectronic characteristics

3 November, 2014 - 23:17
Dalton Trans., 2014, 43,17209-17209
DOI: 10.1039/C4DT90172J, CorrectionSebastian J. K. Forrest, Paul G. Pringle, Hazel A. Sparkes, Duncan F. Wass
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Phosphine complexes of lone pair bearing Lewis acceptors

3 November, 2014 - 23:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02789B, PerspectiveSaurabh S. Chitnis, Neil Burford
The unique structural outcomes and reactivity modes for phosphine complexes featuring lone-pair bearing acceptors are considered.
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A conformationally stressed novel ball-type perylenediimide appended zinc(II)phthalocyanine hybrid: spectroelectrochemical, electrocolorimetric and photovoltaic properties

3 November, 2014 - 23:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01761G, PaperFatih Pekdemir, Sertan Kurnal[i without dot], Abdurrahman Sengul, Ahmet Alt[i without dot]ndal, Ali R[i without dot]za Ozkaya, Bekir Salih, Ozer Bekaroglu
The ZnPc-perylenediimide hybrid displayed a well-defined electrochromic behaviour and the best photovoltaic conversion efficiency observed with a Pc-based organic solar cell.
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Tetrametallic lanthanide(III) phosphonate cages: synthetic, structural and magnetic studies

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17101-17107
DOI: 10.1039/C4DT02630F, PaperKarzan H. Zangana, Eufemio Moreno Pineda, Richard E. P. Winpenny
Reaction of lanthanide nitrates with phosphonic acids in the presence of pivalic acid and pyridine lead to a trigonal pyramid of lanthanides with phosphonates capping three of the triangular faces.
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Fischer carbene complexes remain favourite targets, and vehicles for new discoveries

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,16959-16973
DOI: 10.1039/C4DT01943A, PerspectiveH. G. Raubenheimer
Fifty years after their introduction, Fischer-type carbene complexes still enthral synthetic and theoretical chemists interested in their preparation and characterization.
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Five types of odd-even effect and crystal structure changes brought about by [small omega]-phenylalkyl group in [Ni(dmit)2] complex salts

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17067-17074
DOI: 10.1039/C4DT02320J, PaperMasahiro Saeki, Kotaro Dai, Shuhei Ichimura, Yoshinori Tamaki, Kazuaki Tomono, Kazuo Miyamura
A series of [Ni(dmit)2] salts of [small omega]-phenylalkyl-trimethylammonium (CnPh: n is the alkylene chain length; n = 2-5) have been prepared and characterized by X-ray crystallographic structural analysis.
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Solvent effect-driven assembly of W/Cu/S cluster-based coordination polymers from the cluster precursor [Et4N][Tp*WS3(CuBr)3] and CuCN: isolation, structures and enhanced NLO responses

3 November, 2014 - 23:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02725F, PaperQuan Liu, Zhi-Gang Ren, Li Deng, Wen-Hua Zhang, Xin Zhao, Zhen-Rong Sun, Jian-Ping Lang
Solvent modulation of a W/Cu/S cluster and CuCN reaction system provides coordination polymers with enhanced nonlinear optical performances.
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The first investigation of the synthetic mechanism and lithium intercalation chemistry of Li9Fe3(P2O7)3(PO4)2/C as cathode material for lithium ion batteries

3 November, 2014 - 23:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02498B, PaperHe Gao, Sen Zhang, Chao Deng
Li9Fe3(P2O7)3(PO4)2 with mixed-polyanion groups is introduced as a novel cathode material for Li-ion batteries.
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Layered uranium(VI) hydroxides: structural and thermodynamic properties of dehydrated schoepite [small alpha]-UO2(OH)2

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17191-17199
DOI: 10.1039/C4DT02455A, PaperPhilippe F. Weck, Eunja Kim
The structure of dehydrated schoepite, [small alpha]-UO2(OH)2, was investigated using computational approaches going beyond standard density functional theory and including van der Waals dispersion corrections. Some entropy estimates from calorimetric measurements overestimate by up to 23% the values computed in this study.
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Ruthenium and osmium complexes of hemilabile chiral monophosphinite ligands derived from 1D-pinitol or 1D-chiro-inositol as catalysts for asymmetric hydrogenation reactions

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17163-17171
DOI: 10.1039/C4DT02558J, PaperAngela T. Slade, Cornelis Lensink, Andrew Falshaw, George R. Clark, L. James Wright
Chiral monophosphinite ligands derived from 1D-pinitol or 1D-chiro-inositol coordinate to ruthenium as bidentate hemilabile ligands to produce ketone hydrogenation catalysts that give high conversions but low %ee values.
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Mixed-metal chalcogenide tetrahedral clusters with an exo-polyhedral metal fragment

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17184-17190
DOI: 10.1039/C4DT02329C, PaperK. Yuvaraj, Dipak Kumar Roy, V. P. Anju, Bijnaneswar Mondal, Babu Varghese, Sundargopal Ghosh
Mixed-metal chalcogenide tetrahedral clusters, [Cp*Ru(CO)2([small mu ]-H){Os3(CO)9}S] and [Cp*Ru(CO)2([small mu ]-H){Ru3(CO)9}S], have been isolated from arachno-[(Cp*RuCO)2B2H6] and [(Cp*Mo)2B5H9] respectively, in which the [Cp*Ru(CO)2] fragment is attached in an exo-polyhedral manner.
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Microporous Ni11(HPO3)8(OH)6 nanocrystals for high-performance flexible asymmetric all solid-state supercapacitors

3 November, 2014 - 23:17

Dalton Trans., 2014, 43,17000-17005
DOI: 10.1039/C4DT02831G, CommunicationYanping Gao, Junhong Zhao, Zhen Run, Guangqin Zhang, Huan Pang
Microporous Ni11(HPO3)8(OH)6 nanocrystals were successfully applied to create a flexible solid-state asymmetric supercapacitor, which achieved a maximum energy density of 0.45 mW h cm-3 with high stability for 10 000 cycles.
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