Dalton Transactions

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A novel synthetic route to transition metal phosphide nanoparticles

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5503-5509
DOI: 10.1039/C4DT03886J, PaperZhiwei Yao, Meng Li, Xiang Wang, Xue Qiao, Jiang Zhu, Yu Zhao, Guanzhang Wang, Jingzhou Yin, Haiyan Wang
A novel synthetic route was developed to prepare nano-sized and well-dispersed phosphides of transition metals (Mo, Ni, and Co) from their corresponding oxide precursors.
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Reactivity of TCNE and TCNQ derivatives of quinonoid zwitterions with Cu(I)

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5441-5450
DOI: 10.1039/C4DT03956D, PaperThomas Kauf, Vitor Rosa, Christophe Fliedel, Roberto Pattacini, Naina Deibel, Teresa Aviles, Biprajit Sarkar, Pierre Braunstein
The reactions of TCNE- and TCNQ-functionalized zwitterionic benzoquinonemonoimines with a Cu(I)-BIAN complex have been investigated and found to follow a diversity of interesting patterns.
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Influence of N-heteroaromatic [small pi]-[small pi] stacking on supramolecular assembly and coordination geometry; effect of a single-atom change in the ligand

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5488-5502
DOI: 10.1039/C4DT03518F, PaperHamid Reza Khavasi, Bahareh Mir Mohammad Sadegh
A study on how the polarization of aromatic systems, through the introduction of a nitrogen heteroatom, affects the [small pi]-[small pi] interactions and crystal packing of mercury coordination compounds.
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Key multi(ferrocenyl) complexes in the interplay between electronic coupling and electrostatic interaction

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5234-5257
DOI: 10.1039/C4DT03581J, PerspectiveSaverio Santi, Annalisa Bisello, Roberta Cardena, Alessandro Donoli
In this review, the properties of the most significant examples of multi(ferrocenyl) cations containing a number of ferrocenyl units from two to six are discussed and the results are compared with the outcomes of some of our recent studies on conjugated ferrocenyl complexes.
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Lanthanide derivatives comprising arylhydrazones of [small beta]-diketones: cooperative E/Z isomerization and catalytic activity in nitroaldol reaction

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5602-5610
DOI: 10.1039/C4DT03788J, PaperKamran T. Mahmudov, M. Fatima C. Guedes da Silva, Manas Sutradhar, Maximilian N. Kopylovich, Fatali E. Huseynov, Nazim T. Shamilov, Anna A. Voronina, Tatyana M. Buslaeva, Armando J. L. Pombeiro
RAHB and ionic interaction assisted E/Z[rightward arrow]E isomerization of arylhydrazone of [small beta]-diketone is reported.
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Spectroscopic, computational and electrochemical studies on the formation of the copper complex of 1-amino-4-hydroxy-9,10-anthraquinone and effect of it on superoxide formation by NADH dehydrogenase

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5428-5440
DOI: 10.1039/C4DT03635B, PaperSanjay Roy, Palash Mondal, Partha Sarathi Sengupta, Debasis Dhak, Ramesh Chandra Santra, Saurabh Das, Partha Sarathi Guin
A copper-anthraquinone complex significantly reduces O2[radical dot]- by NADH dehydrogenase compared to the free ligand.
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Organometallic chemistry of ethynyl boronic acid MIDA ester, HC[triple bond, length as m-dash]CB(O2CCH2)2NMe

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5713-5726
DOI: 10.1039/C4DT03695F, PaperAnthony F. Hill, Craig D. Stewart, Jas S. Ward
The reactions of HC[triple bond, length as m-dash]CBMIDA (BMIDA = B(O2CCH2)2NMe) with a range of ruthenium complexes examples of [sigma]-alkynyl, [sigma]-alkenyl and vinylidene complexes bearing 4-coordinate boron substituents.
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Synthesis and characterization of substituted Schiff-base ligands and their d10 metal complexes: structure-induced luminescence tuning behaviors and applications in co-sensitized solar cells

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5306-5322
DOI: 10.1039/C4DT03602F, PaperYu-Wei Dong, Rui-Qing Fan, Ping Wang, Li-Guo Wei, Xin-Ming Wang, Hui-Jie Zhang, Song Gao, Yu-Lin Yang, Yu-Lei Wang
The structure-induced luminescence tuning behaviors of Schiff-base ligand based d10 metal complexes and their applications in co-sensitized solar cells.
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A new inorganic-organic hybrid material Al-SBA-15-TPI/H6P2W18O62 catalyzed one-pot, three-component synthesis of 2H-indazolo[2,1-b]phthalazine-triones

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5888-5897
DOI: 10.1039/C4DT03504F, PaperR. Tayebee, M. M. Amini, S. Pouyamanesh, A. Aliakbari
Al-SBA-15-TPI/H6P2W18O62 is introduced as an effective catalyst for the one-pot synthesis of indazolo-phthalazine-triones. The catalyst could be easily separated without noticeable reduction in activity.
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Lithiated sulfoxides: [small alpha]-sulfinyl functionalized carbanions

11 March, 2015 - 09:17

Dalton Trans., 2015, 44,5323-5330
DOI: 10.1039/C4DT02238F, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gerd Ludwig, Tobias Ruffer, Andre Hoppe, Till Walther, Heinrich Lang, Stefan G. Ebbinghaus, Dirk Steinborn
Lithiated sulfoxides of the type [Li2{CRR[prime or minute]S(O)Ar}2(TMEDA)2], their molecular structures, and diastereoselective C-C bond formation reactions with benzaldehyde and benzophenone are presented.
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