Dalton Transactions

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Spectroscopic, structural and computational analysis of [Re(CO)3(dippM)Br]n+ (dippM = 1,1ʹ-bis(diiso-propylphosphino)metallocene, M = Fe, n = 0 or 1; M = Co, n = 1)

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04721H, PaperAliza G. Furneaux, nicholas piro, Raul Hernandez Sanchez, Kathryn M Gramigna, Natalie Fey, Michael J Robinson, William S. Kassel, Chip Nataro
While the redox active backbone of bis(phosphino)ferrocene ligands is often cited as an important feature of these ligands in catalytic studies, the structural parameters of oxidized bis(phosphino)ferrocene ligands have not...
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Sacrificial conversion of layered rare-earth hydroxide (LRH) nanosheets into (Y1-xEux)PO4 nanophosphors and investigation of photoluminescence

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT01983D, PaperZhihao Wang, Ji-Guang Li, Qi Zhu, Xiaodong Li, Xudong Sun
Ultra-thin nanosheets (2-6 nm) of the (Y1-xEux)2(OH)5NO3[round bullet, filled]nH2O layered rare-earth hydroxide (LRH), directly crystallized without exfoliation, were employed for the first time as a sacrificial precursor to synthesize (Y1-xEux)PO4 orthophosphate red...
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Thermal Degradation Mechanism of Triangular Ag@SiO2 Nanoparticles

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00169F, PaperMahesh K Gangishetty, Robert William James Scott, Timothy L. Kelly
Triangular silver nanoparticles are promising materials for light harvesting applications because of their strong plasmon bands; these absorption bands are highly tunable, and can be varied over the entire visible...
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Highly efficient CuxO/TiO2 catalysts: controllable dispersion and isolation of metal active species

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00055J, CommunicationLijuan Shen, Congbo Xu, Xinxin Qi, Yanning Cao, Jing Tang, Yuanhui Zheng, Lilong Jiang
Porous CuxO/TiO2 architectures with enhanced dispersion of active phase are synthesized by a facile MOF-tempalted method. Such unique composite would furnish excellent catalytic activity for CO oxidation under relatively mild...
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Correction: Microwave gallium-68 radiochemistry for kinetically stable bis(thiosemicarbazone) complexes: structural investigations and cellular uptake under hypoxia

9 February, 2016 - 19:17
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT90021F, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Israt S. Alam, Rory L. Arrowsmith, Fernando Cortezon-Tamarit, Frazer Twyman, Gabriele Kociok-Kohn, Stanley W. Botchway, Jonathan R. Dilworth, Laurence Carroll, Eric O. Aboagye, Sofia I. Pascu
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Zebra reaction or the recipe for the synthesis of heterodimeric zinc complexes

9 February, 2016 - 19:17

Dalton Trans., 2016, 45,2829-2838
DOI: 10.1039/C5DT03883A, PaperD. Jedrzkiewicz, J. Ejfler, L. John, S. Szafert
A series of asymmetric heterodimeric zinc complexes have been synthesized in a direct reaction between conformationally flexible chiral/achiral homodimers.
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Synthesis and characterization of ML and ML2 metal complexes with amino acid substituted bis(2-picolyl)amine ligands

9 February, 2016 - 19:17

Dalton Trans., 2016, 45,2845-2858
DOI: 10.1039/C5DT03387J, PaperDani Skalamera, Ernest Sanders, Robert Vianello, Aleksandra Marsavelski, Andrej Pevec, Iztok Turel, Srecko I. Kirin
The stoichiometry and stereochemistry of bis(2-picolyl)amine (bpa) or bis(2-quinaldyl)amine (bqa) metal complexes were studied by spectroscopy, crystallography and DFT calculations.
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Bismuth(III)dichalcogenones as Highly Active Catalysts in Multiple C-C Bond Formation Reactions

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04738B, PaperSrinivas Katam, Sathyanarayana Arruri, Naga Babu Chatla, Prabusankar Ganesan
Thirteen new bismuth(III) dichalcogenones derivatives of triflates and halides were synthesized and structurally characterized. The mono, di, tetra and hepta nuclear complexes were isolated with different bismuth(III) coordination environments. These...
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Boron induced structure modifications in Pd-Cu-B system: new Ti2Ni-type derivative borides Pd3Cu3B and Pd5Cu5B2

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT05058H, PaperOksana Sologub, Leonid Salamakha, Gaku Eguchi, Berthold Stoeger, Peter Rogl, Ernst Bauer
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Correction: Silver(I) complexes as precursors to produce silver nanowires: structure characterization, antimicrobial activity and cell viability

9 February, 2016 - 19:17
Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT90019D, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Nadia E. A. El-Gamel
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Structural analysis of monometallic ruthenium-arene complexes using ion mobility mass spectrometry, collision-induced dissociation, and density functional theory

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00080K, PaperIzabella Czerwinska, Johann Far, Christopher Kune, Carlos Larriba-Andaluz, Lionel Delaude, Edwin de Pauw
Ion mobility mass spectrometry (IM-MS) and collision-induced dissociation (CID) techniques were used to investigate the influence of the phosphine ligand on the physicochemical properties of [RuCl2(p-cymene)(PCy3)] (1), [RuCl2(p-cymene)(PPh3)] (2), and...
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Defect engineering of UiO-66 for CO2 and H2O uptake - a combined experimental and simulation study

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00189K, Communicationweibin liang, Campbell J Coghlan, Florence Ragon, Marta Rubio-Martinez, Deanna Michelle D'Alessandro, Ravichandar Babarao
Defect concentrations and their compensating groups have been systematically tuned within UiO-66 frameworks by using modified microwave-assisted solvothermal methods. Both of these factors have a pronounced effect on CO2 and...
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Taking Bismuthinite to Bismuth Sulfide Nanorods in Two Easy Steps

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00157B, CommunicationDimuthu Senevirathna, Victoria L Blair, Melissa Vivienne Werrett, Philip Craig Andrews
The transformation of mineral bismuthinite, to Bi2S3 nanoparticles, via a simple two-step process is described. The reaction of bismuthinite with two aryldithoic acids gave the complexes; [Bi(S2C(C6H4)-4-CH3)3] and [Bi(S2C(C6H4)-4-OCH3)3]. Mild...
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Bio-inspired stabilization of sulfenyl iodide RS-I in a Zr(IV)-based metal-organic framework

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C6DT00016A, PaperKa-Kit Yee, Yan-Lung Wong, Zhengtao Xu
A Zr(IV)-based metal-organic framework (MOF) appended with free-standing thiol (-SH) groups was found to react readily with I2 molecules to form sulfenyl iodide (S-I) units. In contrast to its solution...
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Neutral, heteroleptic copper(I)-4H-imidazolate complexes: synthesis and characterization of their structural, spectral and redox properties

9 February, 2016 - 19:17
Dalton Trans., 2016, Accepted Manuscript
DOI: 10.1039/C5DT04435A, PaperMartin Schulz, Fabian Droge, Felix Herrmann, Julian Schindler, Helmar Gorls, Martin Presselt
Facile synthetic access to four novel, neutral, heteroleptic copper(I)-complexes, incorporating 4H-imidazolates as well as the bisphosphane ligands XantPhos and DPEPhos is reported. The complexes were characterized in the solid state...
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U(V) in metal uranates: a combined experimental and theoretical study of MgUO4, CrUO4, and FeUO4

9 February, 2016 - 19:17

Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00066E, PaperXiaofeng Guo, Eitan Tiferet, Liang Qi, Jonathan M. Solomon, Antonio Lanzirotti, Matthew Newville, Mark H. Engelhard, Ravi K. Kukkadapu, Di Wu, Eugene S. Ilton, Mark Asta, Stephen R. Sutton, Hongwu Xu, Alexandra Navrotsky
Although pentavalent uranium can exist in aqueous solution, its presence in the solid state is uncommon.
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A ruthenium water oxidation catalyst based on a carboxamide ligand

9 February, 2016 - 19:17

Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00327C, CommunicationWangchuk Rabten, Torbjorn Akermark, Markus D. Karkas, Hong Chen, Junliang Sun, Pher G. Andersson, Bjorn Akermark
Herein is presented a single-site Ru complex bearing a carboxamide-based ligand that efficiently manages to carry out the four-electron oxidation of H2O.
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Reduction of a diamidocarbene-supported borenium cation: isolation of a neutral boryl-substituted radical and a carbene-stabilized aminoborylene

9 February, 2016 - 19:17

Dalton Trans., 2016, Advance Article
DOI: 10.1039/C6DT00300A, PaperAnthony D. Ledet, Todd W. Hudnall
We have synthesized the first diamidocarbene (DAC)-supported borenium salt which was found to readily undergo two sequential 1-electron reductions to give a boryl-substituted DAC-centred radical and a DAC-supported aminoborylene.
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Luminescent organoboron ladder compounds via directed electrophilic aromatic C-H borylation

9 February, 2016 - 19:17

Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT05077D, PaperMayyadah Yusuf, Kanglei Liu, Fang Guo, Roger A. Lalancette, Frieder Jakle
Regioselective electrophilic borylation of a pyridyl-flanked fluorene provides highly luminescent, air-stable boron-bridged ladder species.
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Role(s) of TMA in polymerization

9 February, 2016 - 19:17

Dalton Trans., 2016, Advance Article
DOI: 10.1039/C5DT04895H, PaperC. Ehm, R. Cipullo, P. H. M. Budzelaar, V. Busico
A new TMA-metallocene binding mode is presented and its role in entropy compensation in insertion chemistry discussed.
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