Dalton Transactions

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Synthesis, Structure, and Properties of Dialumane Supported by Pyrazolate Ligands

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03533J, CommunicationChristopher Snyder, Peter Zavalij, Kit H Bowen, Hansgeorg Schnoeckel, Bryan W Eichhorn
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Bi2Te(IO3)O5Cl: A Novel Polar Iodate Oxychloride Exhibiting A Second-Order Nonlinear Optical Response

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03532A, PaperLei Geng, Chang Yu Meng, Hong Yan Lu, Zhong-Zhen Luo, Chensheng Lin, Wen-Dan Cheng
The novel iodate oxychloride, Bi2Te(IO3)O5Cl, has been hydrothermally synthesized and structurally characterized. The compound crystallizes in the polar monoclinic space group Cc with a = 22.037(8) A, b = 5.256(2)...
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A Stable Zinc-4-carboxypyrazole Framework with High Uptake and Selectivity of Light Hydrocarbons

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03594A, PaperHong-Ru Fu, Fei Wang, Jian Zhang
A special organic ligand, 4-carboxypyrazole (4-cpz), is chosen to synthesize a highly stable metal-organic framework (MOF) for selective sorption of light hydrocarbons. The new MOF, H3O+[Zn3(OH)(4-cpz)3][round bullet, filled]2(DEF)[round bullet, filled]H2O (FIR-51, DEF = N,N-diethylformamide),...
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La2O3-encapsulated-SnO2 nanocrystallite-based photoanodes for enhanced DSSCs performance

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03564J, Papershoyeb F shaikh, Rajaram S Mane, Oh-shim Joo
A facile electrospray synthesis method and potential dye sensitized solar cells (DSSCs) application of SnO2 photoanodes (~10 [small mu ]m thick) have been investigated. Nanocrystallites with irregular dimensions have similar crystallite sizes...
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BaCu2Se2 based compounds as promising thermoelectric materials

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03556A, PaperJing Li, Li-Dong Zhao, Jiehe Sui, David Berardan, Wei Cai, Nita Dragoe
In the past few years, many studies have been devoted to the thermoelectric properties of copper selenides and sulfides, and several families of materials have been developed with promising performances....
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Bifunctional Zn(II) Complexes for Recognition of Non-Canonical Thymines in DNA Bulges and G-Quadruplexes

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03004D, PaperKevin E Siters, Stephanie A Sander, Jason Devlin, Janet Morrow
Six Zn(II) complexes of 1,4,7,10-tetraazacyclododecane (cyclen) derivatives were studied for binding to DNA sequences containing non-canonical thymines, including a hairpin with a single thymine bulge (T-bulge) and a G-quadruplex (H-telo)...
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Linear trinuclear cobalt(II) single molecule magnet

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03545C, PaperYuan-Zhu Zhang, Andrew J Brown, Yin-Shan Meng, Hao-Ling Sun, Song Gao
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Preparation, characterization, and properties of PMMA-doped polymer film materials: study the effect of terbium ion on luminescent and lifetime enhancement

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03348E, PaperHuijie Zhang, Ruiqing Fan, Xinming Wang, Ping Wang, Yulei Wang, Yulin Yang
Photophysical properties formed by poly(methylmethacrylate) (PMMA) and doped with Tb-based imidazole derivative coordination polymer {[Tb3(L)([small mu ]3-OH)7][round bullet, filled]H2O}n (1) (L = N,N[prime or minute]-bis(acetoxy)biimidazole) were synthesized and studied. The L[prime or minute] (L[prime or minute] = N,N[prime or minute]-bis(ethylacetate)biimidazole) ligand was...
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Structure, Magnetism and EPR Spectra of a ([small micro]-Thiophenolato) ([small micro]-Pyrazolato-N,N[prime or minute]) Double Bridged Dicopper(II) Complex

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03322A, PaperNarjes Khadir, Davar M. Boghaei, Abdeljalil Assoud, Otaciro Rangel Nascimento, Amanda Nicotina, Luis Ghivelder, Rafael Calvo
A new binuclear copper(II) complex, namely [Cu2L(pz)(DMSO)], where L = 2,6-bis[(2-phenoxy)iminomethyl]-4-methylthiophenolate(3-) and pz = pyrazolate ligand, has been synthesized by a one-pot synthesis involving copper(II) acetate monohydrate, the S-protected ligand...
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Europium doped LaF3 nanocrystals with organic 9-oxidophenalenone capping ligands that display visible light excitable steady-state blue and time delayed red emission

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03249G, PaperMir Irfanullah, Arindam Chowdhury, Dharmendar Kumar Sharma, Ramya Chulliyil
A visible light excitable and colour tunable ~5% Eu3+-doped LaF3 nanocrystals (NCs) containing 9-oxidophenalenone ligands bound to the surface as visible light sensitizers for Eu3+ dopants, have been synthesized...
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Cis-{MoO2}2+ assisted Mannich-type addition of acetylacetonate methine to azomethine of tridentate Schiff bases: racemic complexes with the chiral transformed ligands

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03187C, PaperSathish Kumar Kurapati, Samudranil Pal
Reactions of [MoO2(acac)2] (acac- = acetylacetonate) with the potentially N2O-donor 5,5-membered fused chelate rings forming Schiff bases 2-(2-pyridylaldimine)ethanol (HL1) and 4/5-R-2-(2-pyridylaldimine)phenols (HLn; n = 2-5 for R = H, 4-Cl,...
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Structural variations in metal complexes of a tertiary [small alpha]-hydroxyoxime

16 December, 2014 - 10:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03393K, PaperDaniel D'Alessio, Daniel M Lombardo, Jamila G. Vaughan, Brian W. Skelton, Keith R Barnard, Mark Ian Ogden
Despite the long term interest in hydroxyoximes as metal ion extractants, there is a lack of information on the possible coordination modes these ligands can assume, particularly in concert with...
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A theoretical study of the aromaticity in neutral and anionic borole compounds

16 December, 2014 - 10:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03445G, PaperJ. Oscar C. Jimenez-Halla, Eduard Matito, Miquel Sola, Holger Braunschweig, Christian Horl, Ivo Krummenacher, Johannes Wahler
A theoretical assessment of the degree of (anti)aromaticity in various borole compounds reveals distinct substituent effects.
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3D Co(II) coordination polymer with ferrimagnetic-like layers based on azide and tetrazolate bridges showing slow magnetic dynamics

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,511-514
DOI: 10.1039/C4DT03332A, CommunicationXiu-Mei Zhang, Peng Li, Wei Gao, Jie-Ping Liu, En-Qing Gao
A novel layer-pillared 3D coordination polymer composed of unprecedented Co(II) layers with azide and tetrazolate bridges exhibits the ferrimagnetic-like behaviors with spin-glass dynamic relaxation.
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Theoretical evidence of metal-induced structural distortions in a series of bipyrimidine-based ligands

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,506-510
DOI: 10.1039/C4DT03291H, CommunicationCamille Latouche, Huriye Akdas-Kilig, Jean-Pierre Malval, Jean-Luc Fillaut, Abdou Boucekkine, Vincenzo Barone
Herein, we report theoretical evidence of the geometric changes occurring upon complexation, for a series of octupolar bipyrimidine-based ligands incorporating the NPh2 terminal donor group.
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Immobilized Pd on magnetic nanoparticles bearing proline as a highly efficient and retrievable Suzuki-Miyaura catalyst in aqueous media

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,501-505
DOI: 10.1039/C4DT02899F, CommunicationE. Nehlig, B. Waggeh, N. Millot, Y. Lalatonne, L. Motte, E. Guenin
Immobilized Pd on magnetic nanoparticles bearing proline as a highly efficient and retrievable Suzuki-Miyaura catalyst in aqueous media.
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The stabilization of gallane and indane by a ring expanded carbene

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,498-500
DOI: 10.1039/C4DT03489A, CommunicationAnthony R. Leverett, Alasdair I. McKay, Marcus L. Cole
7Dipp Complexes of GaH3 and InH3 have been prepared. Despite high thermal stability in the solid state, both adducts decompose readily in solution at ambient temperature.
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A series of cobalt and nickel clusters based on thiol-containing ligands accompanied by in situ ligand formation

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,560-567
DOI: 10.1039/C4DT03109A, PaperSong-De Han, Xiao-Hong Miao, Sui-Jun Liu, Xian-He Bu
We report a series of cobalt and nickel clusters based on thiol-containing ligands, 2-mercaptobenzothiazole (HMBT) and 2-mercaptobenzimidazole (H2MBI), accompanied by in situ ligand transformation of HMBT. The magnetic properties of the cobalt clusters have been investigated.
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Metallomic and metalloproteomic strategies in elucidating the molecular mechanisms of metallodrugs

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,437-447
DOI: 10.1039/C4DT02814G, PerspectiveYuchuan Wang, Haibo Wang, Hongyan Li, Hongzhe Sun
Advances in the mechanistic studies of metallodrugs by metallomic and metalloproteomic approaches will improve our understanding of the mechanism of action and allow more metallodrugs to be developed.
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The solution chemistry and reactivity of lacunary Keggin silicotungstates monitored in real-time by a combination of mass spectrometry and electrochemistry

16 December, 2014 - 10:54

Dalton Trans., 2015, 44,553-559
DOI: 10.1039/C4DT02723J, PaperQiaodi Jia, Jie Cao, Yunpeng Duan, Changwen Hu
The relationship between the lacunary Keggin silicotungstate precursors and their vanadium-substituted products.
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