Dalton Transactions

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Unprecedented iminobenzosemiquinone and iminobenzoquinone coordinated mononuclear Cu(II) complex formation under air

15 May, 2015 - 01:17

Dalton Trans., 2015, 44,9375-9381
DOI: 10.1039/C4DT03263B, PaperManas Kumar Mondal, Abul Kalam Biswas, Bishwajit Ganguly, Chandan Mukherjee
Ligand H4LS(AP/AP) comprised of two orthogonally placed non-innocent unit that were bridged by a common -ortho S atom. It reacted with CuCl2[middle dot]2H2O and provided a mononuclear diamagnetic Cu(II) complex where two non-innocent units were in two different oxidation states.
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