Dalton Transactions

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Rapid synthesis, structure and photocatalysis of pure bismuth A-site perovskite of Bi(Mg3/8Fe2/8Ti3/8)O3

3 June, 2014 - 08:54

Dalton Trans., 2014, 43,9255-9259
DOI: 10.1039/C3DT53621A, PaperWenjuan Zhang, Jun Chen, Xiaoxin An, Qi Wang, Longlong Fan, Fangfang Wang, Jinxia Deng, Ranbo Yu, Xianran Xing
Pure bismuth A-site perovskite Bi(Mg3/8Fe2/8Ti3/8)O3 particles were prepared by a sample molten salt synthesis.
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Syntheses, structures and properties of 5-azotetrazolyl salicylic acid and its dilanthanide complexes

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9090-9097
DOI: 10.1039/C4DT00278D, PaperWen-Bin Chen, Zhi-Xin Li, Xin-Wei Yu, Meng Yang, Yan-Xuan Qiu, Wen Dong, Ya-Qiu Sun
Two hydrated 5-azotetrazolyl salicylic acids (H3ASA) and five H3ASA based dinuclear Ln3+ complexes have been synthesized and characterized by single crystal X-ray diffraction analysis.
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Labile coordination approach for the modulation of the electronic properties of ruthenium(II) and iridium(III) complexes within an "N-heterocyclic carbene (NHC)-pyridyl" dynamic platform

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9356-9362
DOI: 10.1039/C4DT00551A, PaperMoumita Mondal, T. K. Ranjeesh, Suraj K. Gupta, Joyanta Choudhury
The electronic properties of newly designed "(NHC)-pyridyl" iridium- and ruthenium-based complexes can be dynamically controlled via a remote modulator.
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Structural and functional models in molybdenum and tungsten bioinorganic chemistry: description of selected model complexes, present scenario and possible future scopes

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,8990-9003
DOI: 10.1039/C4DT00631C, PerspectiveAmit Majumdar
Current status, synthetic problems and future scopes for the bioinorganic modelling chemistry of mononuclear molybdenum and tungsten enzymes.
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Microwave-assisted synthesis of arene ruthenium(II) complexes [([small eta]6-RC6H5)Ru(m-MOPIP)Cl]Cl (R = -H and -CH3) as groove binder to c-myc G4 DNA

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9216-9225
DOI: 10.1039/C3DT53635A, PaperQiong Wu, Tianfeng Chen, Zhao Zhang, Siyan Liao, Xiaohui Wu, Jian Wu, Wenjie Mei, Yanhua Chen, Weili Wu, Lingli Zeng, Wenjie Zheng
Two arene Ru(II) complexes are prepared under microwave irradiation and display application potential as small molecule inhibitors of c-myc G4 DNA.
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Aluminum complexes with bidentate amido ligands: synthesis, structure and performance on ligand-initiated ring-opening polymerization of rac-lactide

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9098-9110
DOI: 10.1039/C4DT00353E, PaperJunpeng Liu, Haiyan Ma
A series of aluminum dimethyl complexes bearing bidentate amido ligands could initiate the ring-opening polymerization of rac-lactide with living features to afford narrowly distributed PLAs end-capped with the bidentate amido ligands.
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Red electroluminescence of ruthenium sensitizer functionalized by sulfonate anchoring groups

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9202-9215
DOI: 10.1039/C3DT52949E, PaperHashem Shahroosvand, Parisa Abbasi, Ezeddin Mohajerani, Mohammad Janghouri
We have synthesized five novel Ru(II) phenanthroline complexes with an additional aryl sulfonate ligating substituent at the 5-position, as both photosensitizers for oxide semiconductor solar cells (DSSCs) and light emitting diodes (LEDs).
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Biogenic synthesis of palladium nanoparticles using Pulicaria glutinosa extract and their catalytic activity towards the Suzuki coupling reaction

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9026-9031
DOI: 10.1039/C3DT53554A, PaperMujeeb Khan, Merajuddin Khan, Mufsir Kuniyil, Syed Farooq Adil, Abdulrahman Al-Warthan, Hamad Z. Alkhathlan, Wolfgang Tremel, Muhammad Nawaz Tahir, Mohammed Rafiq H. Siddiqui
Biosynthesized Pd NPs: wonderful catalyst towards the Suzuki coupling reaction under aerobic conditions.
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Reduction of an Fe(I) mesityl complex induced by [small pi]-acid ligands

1 June, 2014 - 08:17

Dalton Trans., 2014, 43,9032-9037
DOI: 10.1039/C4DT00170B, PaperYa-Fan Lin, Yumiko Nakajima, Fumiyuki Ozawa
The Fe(I) complex [Fe(Mes)(BPEP-Ph)] bearing a PNP-pincer type phosphaalkene ligand (BPEP-Ph) undergoes one-electron reduction via Mes group migration from Fe to P in the presence of [small pi]-acid ligands (CO, RNC).
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TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operation

30 May, 2014 - 07:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01053A, PaperRagnar Kiebach, Kion Norrman, Christodoulos Chatzichristodoulou, Ming Chen, Xiufu Sun, Sune D. Ebbesen, Mogens B. Mogensen, Peter Vang Hendriksen
TOF-SIMS was used to investigate the enrichment and redistribution of impurities in solid oxide cells during operation.
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An in situ spectroscopic study of the local structure of oxyfluoride melts: NMR insights into the speciation in molten LiF-LaF3-Li2O systems

30 May, 2014 - 07:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00926F, PaperAnne-Laure Rollet, Haruaki Matsuura, Catherine Bessada
An in situ high temperature NMR technique evidences the local structure of lithium lanthanum oxyfluoride melts.
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