Dalton Transactions

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RSC - Dalton Trans. latest articles
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Encapsulation of [X2(H2O)4]2- (X = F/Cl) clusters by pyridyl terminated tripodal amide receptor in aqueous medium: single crystal X-ray structural evidence

8 January, 2014 - 20:54

Dalton Trans., 2014, 43,2061-2068
DOI: 10.1039/C3DT52694A, PaperSourav Chakraborty, Ranjan Dutta, M. Arunachalam, Pradyut Ghosh
[F2(H2O)4]2- and [Cl2(H2O)4]2- zipped molecular capsule formation by a tripodal amide receptor in acetone-water (1 : 1) binary solvent mixture is described.
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Effect of ligand modification on the reactivity of phosphinoamide-bridged heterobimetallic Zr/Co complexes

8 January, 2014 - 20:54

Dalton Trans., 2014, 43,1984-1989
DOI: 10.1039/C3DT52133H, PaperWen Zhou, Noam I. Saper, Jeremy P. Krogman, Bruce M. Foxman, Christine M. Thomas
Variation of the N-aryl substituent in tris(phosphinoamide)-linked Zr/Co complexes is found to have a profound effect on both the stoichiometric and catalytic reactivity of these complexes.
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Synthesis, crystal structure and lithium ion conduction of Li3BP2O8

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2294-2300
DOI: 10.1039/C3DT52917G, PaperToru Hasegawa, Hisanori Yamane
Projective views of the crystal structure of Li3BP2O8 along the a axis and the b axis (y = 0.41-0.59).
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Organoselenium(II) halides containing the pincer 2,6-(Me2NCH2)2C6H3 ligand - an experimental and theoretical investigation

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2221-2233
DOI: 10.1039/C3DT52886C, PaperAlexandra Pop, Anca Silvestru, Emilio Jose Juarez-Perez, Massimiliano Arca, Vito Lippolis, Cristian Silvestru
DFT calculations on [RSe]+X- [R = 2,6-(Me2NCH2)2C6H3; X = Cl (2), Br (3), I (4)] show the X- halide to determine an unbalancing of the N-Se-N system towards a charge-transfer N[rightward arrow]Se-N system going from 4 to 2.
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Characterization of one-electron oxidized copper(II)-salophen-type complexes; effects of electronic and geometrical structures on reactivities

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2283-2293
DOI: 10.1039/C3DT52338A, PaperKazutaka Asami, Akiko Takashina, Misato Kobayashi, Satoshi Iwatsuki, Tatsuo Yajima, Amelie Kochem, Maurice van Gastel, Fumito Tani, Takamitsu Kohzuma, Fabrice Thomas, Yuichi Shimazaki
One-electron oxidized Cu(II)-salophen complexes showed different electronic structures by position of the methoxy substitutions, leading to different oxidation pathways.
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Structural modulation of silver complexes and their distinctive catalytic properties

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2252-2258
DOI: 10.1039/C3DT52655K, PaperYue Zhao, Kai Chen, Jian Fan, Taka-aki Okamura, Yi Lu, Li Luo, Wei-Yin Sun
The effect of a crystal nucleation inductor on the structures of silver(I) 4,4[prime or minute]-di(2-oxazolinyl)biphenyl complexes and the catalytic performance of the complexes were investigated.
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Porous coordination polymers based on functionalized Schiff base linkers: enhanced CO2 uptake by pore surface modification

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2272-2282
DOI: 10.1039/C3DT52266K, PaperBiswajit Bhattacharya, Ritesh Haldar, Rajdip Dey, Tapas Kumar Maji, Debajyoti Ghoshal
Three porous coordination polymers have been synthesized with dicarboxylates and Schiff base linkers. Enhanced CO2 uptake is observed with the pore surface modification by changing the pillar backbone to a -CMe[double bond, length as m-dash]N- group from -CH[double bond, length as m-dash]N-.
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Halogen effects on photoluminescence and catalytic properties: a series of spatially arranged trimetallic zinc(II) complexes

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53137F, PaperOk-Sang Jung, Haeri Lee, Tae Hwan Noh
Self-assembly of ZnX2 (X = Cl, Br, and I) with N,N',N"-tris(2-pyridinylethyl)-1,3,5-benzenetricarboxamide (L) as a tridentate N-donor ligand yields discrete C3-symmetric trimetallic zinc(II) complexes, [Zn3X6L(MeOH)3]. These form, via [small pi]∙∙∙[small pi] interactions and...
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Investigation of a dichlorodioxomolybdenum(VI)-pyrazolylpyridine complex and a hybrid derivative as catalysts in olefin epoxidation

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52981A, PaperTatiana R Amarante, Patricia Neves, Filipe Alexandre Almeida Paz, Anabela A. Valente, Martyn Pillinger, Isabel S. Goncalves
Treatment of the solvent adduct [MoO2Cl2(THF)2] with the ligand 2-(1-pentyl-3-pyrazolyl)pyridine (1, abbreviated as pent-pp) gave the dioxomolybdenum(VI) complex [MoO2Cl2(pent-pp)] (2), which was characterised by elemental analysis, 1H NMR, FT-IR spectroscopy...
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Unprecedented bistability domain and interplay between spin crossover and polymorphism in a mononuclear iron(II) complex

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53440E, PaperMark B Bushuev, Vasiliy A Daletsky, Denis P Pishchur, Yuri V Gatilov, Ilya V Korolkov, Elena B Nikolaenkova, Viktor P Krivopalov
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Pillar[5]arene-based diglycolamides for highly efficient separation of americium(III) and europium(III)

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53336K, CommunicationLei Wu, Yuyu Fang, Yiming Jia, Yuanyou Yang, Jiali Liao, Ning Liu, Xinshi Yang, Wen Feng, Jialin Ming, Lihua Yuan
Pillar[5]arenes, as a new intriguing class of calixarene analogues, were functionalized with ten diglycolamide (DGA) arms on both sides(rims) of the pillar framework and evaluated for their extraction behaviour towards...
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Removal of Uranium(VI) From Aqueous Solution Using Iminodiacetic Acid Derivatives Functionalized SBA-15 As Adsorbents

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT52610K, Paperyulong wang, lijuan Song, lu Zhu, bolong Guo, Su-Wen Chen, wangsuo Wu
Three different functional SBA-15 were prepared by post-grafting method using three iminodiacetic acid derivatives of ethylenediaminetriacetic acid (ED3A), diethylenetriaminetetraacetic acid (DT4A), and 1,2-cyclohexylenedinitrilotriacetic acid (CyD3A), which were used as adsorbents...
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Concentration quenching of praseodymium ions Pr3+ in BaGd2(MoO4)4 crystals

6 January, 2014 - 20:17
Dalton Trans., 2013, Accepted Manuscript
DOI: 10.1039/C3DT53225A, PaperYing Guan, Taiju TSUBOI, yanlin huang, Wei Huang
Concentration effect on the photoluminescence (PL) of praseodymium Pr3+ ion is studied at 298-12 K for barium gadolinium molybdate (BaGd2(MoO4)4, called BGM) crystals with a wide Pr3+ concentration range of...
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Transport properties of CuIn1-xAlxSe2/AZnO heterostructure for low cost thin film photovoltaics

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,1974-1983
DOI: 10.1039/C3DT52515E, PaperBanavoth Murali, S. B. Krupanidhi
Solution processed low cost CIASe/AZnO visible photodetection under AM 1.5 different sun illuminations.
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Syn-anti conformational switching in an ethane-bridged Co(II)bisporphyrin induced by external stimuli: effects of inter-macrocyclic interactions, axial ligation and chemical and electrochemical oxidations

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2301-2314
DOI: 10.1039/C3DT52784K, PaperSoumyajit Dey, Sankar Prasad Rath
The reversible syn-anti conformational switching has been observed either by various external ligands or stepwise oxidations (shown below).
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A new family of Ln-radical chains (Ln = Nd, Sm, Gd, Tb and Dy): synthesis, structure, and magnetic properties

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2234-2243
DOI: 10.1039/C3DT52959B, PaperPeng Hu, Xiufeng Wang, Yue Ma, Qinglun Wang, Licun Li, Daizheng Liao
The effect of the substituents of the nitronyl nitroxide radical on modulation of the magnetic behavior is studied for 1D Ln-radical complexes.
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Living ring-opening homo- and copolymerisation of [varepsilon]-caprolactone and L-lactide by cyclic [small beta]-ketiminato aluminium complexes

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2244-2251
DOI: 10.1039/C3DT52712C, PaperYan Liu, Wei-Shi Dong, Jing-Yu Liu, Yue-Sheng Li
A series of novel aluminium complexes containing cyclic [small beta]-ketiminato ligands have been prepared. The well-defined block copolymers of [varepsilon]-CL and L-LA were successfully prepared in the presence of 2-propanol.
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Magnetic composite BiOCl-SrFe12O19: a novel p-n type heterojunction with enhanced photocatalytic activity

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2211-2220
DOI: 10.1039/C3DT52219A, PaperTaiping Xie, Longjun Xu, Chenglun Liu, Jun Yang, Mei Wang
The structure and photocatalytic activity of the magnetic photocatalyst BiOCl-SrFe12O19 were characterized. The high photocatalytic activity was interpreted by introducing the magnetic field effect for the first time.
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Graphene oxide capturing surface-fluorinated TiO2 nanosheets for advanced photocatalysis and the reveal of synergism reinforce mechanism

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2202-2210
DOI: 10.1039/C3DT52542B, PaperKai Dai, Luhua Lu, Qi Liu, Guangping Zhu, Qinzhuang Liu, Zhongliang Liu
GO/F-TiO2 hybrid with high reusable photocatalytic activity was successfully synthesized by a facile hydrothermal and subsequent ultrasonic method.
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Mechanism of stabilization of dicalcium silicate solid solution with aluminium

6 January, 2014 - 20:17

Dalton Trans., 2014, 43,2176-2182
DOI: 10.1039/C3DT52194J, PaperAna Cuesta, Miguel A. G. Aranda, Jesus Sanz, Angeles G. de la Torre, Enrique R. Losilla
Stoichiometric dicalcium silicate, Ca2SiO4, displays a well-known polymorphism with temperature.
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