Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 12 hours 51 min ago

Structural, Raman spectroscopic and microwave dielectric studies on Ni1-x(Zn1/2Zr1/2)xW1-xNbxO4 ceramic compounds with Wolframite structure

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02364A, PaperDasaradha Rama Rao Seethiraju, Rama Krishna Murthy Vemuri
Ni1-x(Zn1/2Zr1/2)xW1-xNbxO4 (x = 0.0 - 1.0) compositions were synthesized via conventional solid state reaction method. Structural and lattice vibrational characteristics of these compositions were studies with help of powder X-ray...
The content of this RSS Feed (c) The Royal Society of Chemistry

A highly selective fluorescent 'turn-on' chemosensor for Zn2+ based on a benzothiazole conjugate: their applicability in live cell imaging and use of the resultant complex as a secondary sensor of CN-

10 December, 2014 - 08:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT03247K, PaperNilesh Khairnar, Kundan Tayade, Suban K. Sahoo, Banashree Bondhopadhyay, Anupam Basu, Jasminder Singh, Narinder Singh, Vikas Gite, Anil Kuwar
A benzothiazole derivative linked "off-on" multi-responsive and selective chemosensor 3 has been synthesized.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, Characterization and Magnetism of Metal-Organic Compounds: Role of Positions of the Coordinating Groups of a Meso-flexible Ligand in Placing Anisotropy to Exhibit Spin-Canting Behaviour

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03468F, PaperSamar K Das, Paulami Manna, Bharat Kumar Tripuramallu, Suresh Bommakanti
Abstract. In continuation with our recent investigation on flexible ligands, three new metal-organic coordination framework containing compounds, formulated as {Co(L1)(px3ampy)}n[middle dot]npx3ampy (1), {Co(L2)(px3ampy)0.5}n (2) and {Co2(L3) (px3ampy)2(H2O)}n[round bullet, filled] 3nH2O (3) have been...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis of few-layer MoS2 nanosheet-loaded Ag3PO4 for enhanced photocatalytic activity

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03242J, PaperYanhua Song, Yucheng Lei, Hui Xu, Cheng Wang, Jia Yan, Haozhu Zhao, Yuanguo Xu, Jiexiang Xia, Sheng Yin, Huaming Li
A novel few-layer MoS2/Ag3PO4 composites were fabricated. The results indicated that Ag3PO4 nanoparticles were directly formed on the few-layer MoS2. The physical and chemical property of few-layer MoS2/Ag3PO4 composite photocatalysts...
The content of this RSS Feed (c) The Royal Society of Chemistry

Sol-gel syntheses, luminescence, and energy transfer properties of [small alpha]-GdB5O9:Ce3+/Tb3+ phosphors

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03303E, PaperXiaorui Sun, Gao Wenliang, Tao Yang, Rihong Cong
Sol-gel method was applied to prepare homogenous and high crystalline phosphors with the formulas [small alpha]-GdB5O9:xTb3+ (0 [less-than-or-equal] x [less-than-or-equal] 1), [small alpha]-Gd1-xCexB5O9 (0 [less-than-or-equal] x [less-than-or-equal] 0.40), [small alpha]-GdB5O9:xCe3+, 0.30Tb3+ (0 [less-than-or-equal]...
The content of this RSS Feed (c) The Royal Society of Chemistry

Breakdown of the geometry restriction of crystallographic site on the valence state of Eu in CaGdAlO4: realization of white emission from Eu singly-doped phosphors

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03095H, CommunicationYang Zhang, Xiaoming Liu, xuejiao li, Kai Li, Hongzhou Lian, Mengmeng Shang, Jun Lin
We demonstrate a strategy to manipulate the valence state of Eu in CaGdAlO4 based on breakdown of the geometry restriction on the activators, which would shed light on the exploration...
The content of this RSS Feed (c) The Royal Society of Chemistry

Assembling anionic Sb(V)/(III) containing polyoxostibonates stabilized by triphenyltellurium cations

10 December, 2014 - 08:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03319A, PaperNagarjuna Kumar Srungavruksham, Viswanathan Baskar
Mixed valent polyoxostibonates ligated by tetraorganoditelluroxane and stabilized by weak interactions from triaryltellurium cations are presented. Successive reactions like reduction, dearylation and disproportionation have been observed en route to the formation of these novel POMs.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A porous metal-organic framework containing multiple active Cu2+ sites for highly efficient cross dehydrogenative coupling reaction

10 December, 2014 - 08:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03371J, CommunicationShu-Lan Zhu, Sha Ou, Min Zhao, Hong Shen, Chuan-De Wu
A novel 3D porous metal-organic framework was constructed from imidazol carboxylate linkers and copper(II) nodes, which in situ generates multiple active CuII sites in the nanosized channel walls for highly...
The content of this RSS Feed (c) The Royal Society of Chemistry

Structural Diversities and Related Properties of Four Coordination Polymers Synthesized From Original Ligand of 3,3',5,5'-Azobenzenetetracarboxylic Acid

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03076A, Paperxiutang zhang, Liming Fan, Weiliu Fan, Bin Li, Xinzheng Liu, Xian Zhao
Four new coordination polymers, namely [Co(H2oabtc)(bibp)]n (1), {[Mn1.5(oabtc)(H2O)2][round bullet, filled](H2bmib)0.5[round bullet, filled]H2O}n (2), {[Cd1.5(o2abtc)][round bullet, filled](H2bmib)0.5[round bullet, filled]2H2O}n (3), and {[Cd(nip)(bibp)][round bullet, filled]H2O}n (4), were constructed under solvothermal conditions in the presence of two bis(imidazole) bridging linkers (bimb = 1,4-bis(2-methylimidazol-1-ylmethyl)benzene,...
The content of this RSS Feed (c) The Royal Society of Chemistry

Exploring the Effect of Axial Ligand Substitution (X = Br, NCS, CN) on the Photodecomposition and Electrochemical Activity of MnX(N-C)(CO)3 Complexes

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03079F, PaperJay Agarwal, Charles J. Stanton, Travis W. Shaw, Jonathon E. Vandezande, George F. Majetich, Andrew B. Bocarsly, Henry F. Schaefer
The synthesis, electrochemical activity, and relative photodecomposition rate is reported for four new Mn(I) N-heterocyclic carbene complexes: MnX(N-ethyl-N'-2-pyridylimidazol-2-ylidine)(CO)3 (X = Br, NCS, CN) and MnCN(N-ethyl-N'-2-pyridylbenzimidazol-2-ylidine)(CO)3. All compounds display an electrocatalytic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Transition Metal Complexes Assisted Csp3F Bond Formation

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03410D, PerspectiveZhiqiang Weng, Xiaoxi Lin
Fluoroorganic compounds have attracted significant attention in various fields, such as pharmaceutical, agricultural chemistry, and material science, as a result of their unique physical, chemical, and physiological properties. Consequently, extensive...
The content of this RSS Feed (c) The Royal Society of Chemistry

Confocal and fluorescence lifetime imaging sheds light on the fate of a pyrene-tagged carbon monoxide-releasing Fischer carbene chromium complex

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03312D, PaperRory L. Arrowsmith, Stanley W Botchway, Ian J S Fairlamb, Jason Lynam, James WB Moir, Sofia I Pascu, Jonathan S Ward, Wei-Qiang Zhang, Anthony J Atkin
The synthesis and full spectroscopic characterisation of a new pyrene-containing chromium-based Fischer carbene complex is described. The complex has a broad absorbance spectrum between 300 and 400 nm and, on...
The content of this RSS Feed (c) The Royal Society of Chemistry

Solution Studies on DNA Interactions of Substitution-inert Platinum Complexes mediated via The Phosphate Clamp

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03237C, PaperYun Qu, Ralph G Kipping, Nick P Farrell
The phosphate clamp is a distinct mode of ligand-DNA binding where the molecular is manifest through ("non-covalent") hydrogen-bonding from am(m)ines of polynuclear platinum complexes to the phosphate oxygens on the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Magnetic and Structural Properties of Dinuclear Singly Bridged-Phenoxido Metal(II) Complexes

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03508A, PaperSalah S. Massoud, Mark Spell, Catherine C. Ledet, Thomas Junk, Radovan Herchel, Roland Fischer, Zdenek Travnicek, Franz Andreas Mautner
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
The content of this RSS Feed (c) The Royal Society of Chemistry

Application of three-coordinate copper(I) complexes with halide ligands in organic light-emitting diodes that exhibit delayed fluorescence

8 December, 2014 - 07:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02853H, PaperMasahisa Osawa, Mikio Hoshino, Masashi Hashimoto, Isao Kawata, Satoshi Igawa, Masataka Yashima
Conventional bottom-emitting devices with three-layered structures containing sublimable three-coordinate copper(I) complexes produce bright green luminescence with maximum external quantum efficiencies (EQE) of 18.6-22.5%.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Blue Phosphorescent N-Heterocyclic Carbene Chelated Pt(II) Complexes with an [small alpha]-Duryl-[small beta]-Diketonato Ancillary Ligand

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03085K, PaperSoo-Byung Ko, Hee-Jun Park, Shao-Long Gong, Xiang Wang, Zhenghong Lu, Suning Wang
C^C* chelated Pt(II) compounds that contain an N-heterocyclic carbene (NHC) donor have recently attracted great interest as blue or white phosphorescent emitters for organic light-emitting devices (OLEDs). To overcome the...
The content of this RSS Feed (c) The Royal Society of Chemistry

[Mn2Ga4Sn4S20]8- T3 Supertetrahedral Nanocluster Directed by a Series of Transition Metal Complexes

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02864C, PaperCheng-Yang Yue, Xiao-Wu Lei, Li-Juan Feng, Chen Wang, Ya-Ping Gong, Xin-Ying Liu
With different transition metal (TM) complexes as structure directing agents or building units, three new multinary chalcognidometalates based on T3 supertetrahedral nanocluster of [Mn2Ga4Sn4S20]8- have been solvothermally synthesized and structurally...
The content of this RSS Feed (c) The Royal Society of Chemistry

A Study on the Inhibition of DiHydroFolateReductase (DHFR) from Escherichia coli by Gold(I) Phosphane Compounds. X-ray Crystal Structures of (4,5-dichloro-1H-imidazolate-1-yl)-triphenylphosphane-gold(I) and (4,5-dicyano-1H-imidazolate-1-yl)-triphenylphosp

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01542H, PaperRossana Galassi, Camille Simon Oumarou, Alfredo Burini, Daniela Micozzi, Stefania Pucciarelli, Silvia Vincenzetti, Alessandro Dolmella
An unprecedented study on the inhibitory activity of a class of phosphane gold(I) complexes on E. coli DiHydroFolate Reductase (DHFR) is reported. The gold(I) complexes considered in this work consist...
The content of this RSS Feed (c) The Royal Society of Chemistry

Flexibility windows in faujasite with explicit water and methanol extra-framework content

8 December, 2014 - 07:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03150D, PaperStephen A. Wells, Ka Ming Leung, Peter P. Edwards, Asel Sartbaeva
Geometric simulations reveal limits on flexibility in a zeolite framework (faujasite) with extra-framework methanol and water contents explicitly present.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Nickel(II) complexes with flexible piperazinyl moiety : studies on DNA and protein binding and catecholase like properties

8 December, 2014 - 07:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02675F, PaperSuman Mukhopadhyay, Mriganka Das, Rajendar Nasani, Manideepa Saha, Mobin M Shaikh
Four new mononuclear Ni(II) complexes [Ni(L1)]ClO4 (1a), [Ni(L2)]ClO4 (1b), [Ni(SCN)3(CH3OH)(aminoethylpiperazineH)] (2a), and [Ni(DMSO)4(aminoethylpiperazineH)](ClO4)3 (2b) have been synthesized from two Schiff base ligands [L1 = 1-phenyl-3-((2-(piperidin-4-yl)ethyl)imino)but-1-en-1-ol and L2 = 4-((2-(piperazin-1-yl)ethyl)imino)pent-2-en-2-ol] by...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.