Dalton Transactions

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RSC - Dalton Trans. latest articles
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Characterization of [Fe(BPMEN)ACC]SbF6 : a Structural and Functional Mimic of ACC-Oxidase

3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00347D, Communicationyoann roux, Wadih Ghattas, Frederic Avenier, Regis Guillot, A. Jalila Simaan, Jean-Pierre Mahy
A mononuclear Fe(II) complex bearing 1-aminocyclopropane-1-carboxylic acid (ACCH) was synthesized and characterized. X-ray crystallography demonstrated that ACC binds to the Fe(II) ion in a bidentate mode constituting the first structural...
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Partial oxidation of light alkanes by periodate and chloride salts

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00558B, CommunicationSteven E. Kalman, Dominik Munz, George C. Fortman, Nicholas C. Boaz, John T. Groves, T. Brent Gunnoe
The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported.
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Synthesis and (Spectro)Electrochemistry of Mixed-Valent Diferrocenyldihydrothiopyran Derivatives

3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00246J, PaperKonrad Kowalski, Rafal Karpowicz, Grzegorz Mloston, Dominique Miesel, Alexander Hildebrandt, Heinrich Lang, Rafal Czerwieniec, Bruno Therrien
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Ruthenium catalysts bearing a benzimidazolylidene ligand for the metathetical ring-closure of tetrasubstituted cycloolefins

3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00433K, PaperYannick Borguet, Guillermo Zaragoza, Albert Demonceau, Lionel Delaude
Deprotonation of 1,3-di(2-tolyl)benzimidazolium tetrafluoroborate with a strong base afforded 1,3-di(2-tolyl)benzimidazol-2-ylidene (BTol), which dimerized progressively into the corresponding dibenzotetraazafulvalene. The complexes [RhCl(COD)(BTol)] (COD is 1,5-cyclooctadiene) and cis-[RhCl(CO)2(BTol)] were synthesized to probe...
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Iridium-bipyridine periodic mesoporous organosilica catalyzed direct C-H borylation using a pinacolborane

3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00239G, PaperYoshifumi Maegawa, Shinji Inagaki
Heterogeneous catalysis for direct C-H borylation of arenes and heteroarenes in the combination of iridium (Ir) complex fixed on periodic mesoporous organosilica containing bipyridine ligands within the framework (Ir-BPy-PMO) and...
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Intramolecular N-coordination in ketiminoboranes

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00196J, CommunicationCatherine E. Bacon, Liz Mansour, John J. Hayward, Jeremy M. Rawson
Ketiminoboranes, R2C[double bond, length as m-dash]NB-R[prime or minute]2, pioneered by Wade et al., are formally isoelectronic with allenes but undergo intramolecular cyclisation when R = 2-pyridyl to form heterocyclic boranes with N-donor capability.
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Thermoelastic and structural properties of ionically conducting cerate perovskites: (II) SrCeO3 between 1273 K and 1723 K

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00041F, PaperKevin S. Knight, Richard Haynes, Nikolaos Bonanos, Feridoon Azough
Thermodynamic gruneisen parameter and bond valence parameters for strontium cerate perovskite.
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Chiral crystallization and optical properties of three metal complexes based on two non-centrosymmetric tripodal ligands

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00292C, PaperMing-Dao Zhang, Zhi-Qiang Shi, Min-Dong Chen, He-Gen Zheng
Three chiral coordination polymers 1-3 with novel architectures were constructed by asymmetric induction. Complex 3 can satisfy the fundamental requirement of second-order nonlinear optical material.
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Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00476D, CommunicationYasuhiro Arikawa, Takuo Nakamura, Shinji Ogushi, Kazushige Eguchi, Keisuke Umakoshi
Capture of CO2 from air gave a methylcarbonato ruthenium complex, which was reacted with methylating reagents to release dimethylcarbonate.
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Effect of the cation size on the framework structures of magnesium tungstate, A4Mg(WO4)3 (A = Na, K), R2Mg2(WO4)3 (R = Rb, Cs)

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00332F, PaperShujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang
A series of alkali metal magnesium tungstates, A4Mg(WO4)3 (A = Na, K), R2Mg2(WO4)3 (R = Rb, Cs), were synthesized from a high temperature solution, and their structures were determined by single-crystal X-ray diffraction.
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Synthesis of a cyclometalated 1,3,5-triphenylpyrazole palladium dimer and its activity towards cross coupling reactions

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03908D, PaperRamesh Mamidala, Vanga Mukundam, Kunchala Dhanunjayarao, Krishnan Venkatasubbaiah
A phosphine free 1,3,5-triphenylpyrazole acetate-bridged palladacycle was prepared from simple commercially available starting materials.
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Pyridine versus acetonitrile coordination in rhodium-N-heterocyclic carbene square-planar complexes

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00182J, PaperLaura Palacios, Andrea Di Giuseppe, Ricardo Castarlenas, Fernando J. Lahoz, Jesus J. Perez-Torrente, Luis A. Oro
Experimental and theoretical studies on the factors that control the coordination chemistry of N-donor ligands in square-planar complexes of the type RhCl(NHC)L1L2 (NHC = N-heterocyclic carbene) are presented.
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Yb7Ni4InGe12: a quaternary compound having mixed valent Yb atoms grown from indium flux

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03783A, PaperUdumula Subbarao, Rajkumar Jana, Maria Chondroudi, Mahalingam Balasubramanian, Mercouri G. Kanatzidis, Sebastian C. Peter
Yb7Ni4InGe12 is a new compound crystallizing from indium metal flux. Magnetic susceptibility and XANES data suggest mixed valent Yb atoms.
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A simple and highly selective 2,2-diferrocenylpropane-based multi-channel ion pair receptor for Pb2+ and HSO4-

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03862B, PaperQian Wan, Ji-Bin Zhuo, Xiao-Xue Wang, Cai-Xia Lin, Yao-Feng Yuan
A 2,2-diferrocenylpropane-based multi-channel ion pair receptor 1 was designed and structurally characterized. It was a "naked-eye-detectable" chemosensor towards Pb2+ and HSO4- with excellent selectivity and sensitivity.
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Mono(boratabenzene) rare-earth metal dialkyl complexes: synthesis, structure and catalytic behaviors for styrene polymerization

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT04043K, PaperXiufang Wang, Xuebing Leng, Yaofeng Chen
Synthesis and structural characterization of mono(boratabenzene) rare-earth metal dialkyl complexes were achieved by using multi-substituted boratabenzene ligands, and the synthesized scandium complexes show high catalytic activities for syndiotactic styrene polymerization upon activation with cocatalysts.
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A new visible-light-excitable ICT-CHEF-mediated fluorescence 'turn-on' probe for the selective detection of Cd2+ in a mixed aqueous system with live-cell imaging

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02463J, PaperShyamaprosad Goswami, Krishnendu Aich, Sangita Das, Chitrangada Das Mukhopadhyay, Deblina Sarkar, Tapan Kumar Mondal
A new quinoline based sensor was developed and applied for the selective detection of Cd2+ both in vitro and in vivo.
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Multifunctional mononuclear bisthienylethene-cobalt(II) complexes: structures, slow magnetic relaxation and photochromic behavior

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT04035J, PaperDeng-Ke Cao, Ruo-Hong Wei, Xiao-Xiong Li, Yan-Wei Gu
Based on bisthienylethene ligands BrLH and PLH, multifunctional mononuclear complexes Co(BrL)2[middle dot]3CH3OH (1) and Co(PL)2[middle dot]2CH3OH (2) were synthesized, and they exhibited field-induced slow magnetic relaxation behavior and photochromic properties in CH2Cl2-CH3CN solution.
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Luminescent lanthanide MOFs based on conjugated 1,1[prime or minute]-ethynebenzene-3,3[prime or minute],5,5[prime or minute]-tetracarboxylate ligand: syntheses, structures and photoluminescent properties

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03794D, PaperLu Zhai, Wen-Wei Zhang, Xiao-Ming Ren, Jing-Lin Zuo
Nine isostructural lanthanide MOFs based on 1,1[prime or minute]-ethynebenzene-3,3[prime or minute],5,5[prime or minute]-tetracarboxylate ligand capable of emitting from the visible to near-infrared wavelengths have been synthesized and characterized in detail.
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Template free construction of a hollow Fe3O4 architecture embedded in an N-doped graphene matrix for lithium storage

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03795B, PaperGuohui Qin, Zewei Fang, Chengyang Wang
The rational design and fabrication of electrode materials is a significant, yet highly challenging task.
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Organometallic chemistry of ethynyl boronic acid MIDA ester, HC[triple bond, length as m-dash]CB(O2CCH2)2NMe

3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03695F, PaperAnthony F. Hill, Craig D. Stewart, Jas S. Ward
The reactions of HC[triple bond, length as m-dash]CBMIDA (BMIDA = B(O2CCH2)2NMe) with a range of ruthenium complexes examples of [sigma]-alkynyl, [sigma]-alkenyl and vinylidene complexes bearing 4-coordinate boron substituents.
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