Dalton Transactions

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Crystal Structures and Luminescence Properties of Eu2+-activated new NaBa0.5Ca0.5PO4 and Na3Ba2Ca(PO4)3

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03024A, PaperMinsung Kim, Makoto Kobayashi, Hideki Kato, Hisanori Yamane, Yasushi Sato , Masato kakihana
NaBa1-xCaxPO4:Eu2+ were synthesized by polymerizable complex method. New phases were observed at x = 1/3 and 0.5, which were identified by single-crystal XRD analysis as Na3Ba2Ca(PO4)3and NaBa0.5Ca0.5PO4 with trigonal system....
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Highly Efficient Electrochemiluminescence from Iridium(III) Complexes with 2-Phenylquinoline Ligand

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02809K, PaperYuyang Zhou, Wanfei Li, Linpo Yu, Yang Liu, Xiaomei Wang, Ming Zhou
A series of cyclometalated iridium(III) complexes with 2-phenylquinoline ligand (1-4) were designed and synthesized, which were thoroughly investigated by the photophysics, electrochemistry, theoretical calculations and electrochemiluminescence (ECL). Through incorporating methyl...
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Polymer hybrid thin films based on rare earth ion-functionalized MOF: photoluminescence tuning and sensing as thermometer

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03213F, PaperX Shen, Bing Yan
A series of photofunctional polymer hybrid thin films based on rare earth ion functionalized metal organic frameworks (MOFs, 1 for zinc complexes bio-MOF-1 (Zn8(ad)4(BPDC)6O2Me2NH2) and 2 for rare earth complexes...
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High performing smart electrochromic device based on honeycomb nanostructured h-WO3 thin films: Hydrothermal assisted synthesis

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02953D, PaperVijay kondalkar, Sawanta S Mali, Rohini R. Kharade, Kishorkumar Vikas Khot, Pallavi Patil, Rahul M Mane, Sipra Choudhury, P S Patil, C K Hong, Jin Hyeok Kim, Popatrao N Bhosale
Herewith, we report the honeycomb nanostructured single crystalline hexagonal WO3 (h-WO3)thin films in order to improve the electrochromic performance. In the present investigation, honeycomb nanostructured WO3 with different unit size...
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Synthesis and Specific Fluoride Binding Properties of Expanded Dithiacalixphyrins

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03215B, PaperMagalampalli Ravikanth, Emandi Ganapathi, Tamal Chatterjee
Abstract Expanded dithiacalixphyrins with N2S2 core containing two sp3 and three sp2 meso-carbons have been prepared by condensation of one equivalent of butene-2,3-diyl-bisthiophene-2,5-diyl-bis(p-methoxyphenylmethanol) with one equivalent 5,5'-dialkyldipyrromethane under mild acid...
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Amorphous Co3O4 Modified CdS Nanorods with Enhanced Visible-light Photocatalytic H2-production Activity

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03197K, PaperJielin Yuan, Jiuqing Wen, Qiongzhi Gao, Shangchao Chen, Jiaming Li, Xin Li, Yueping Fang
In this work, amorphous Co3O4 modified CdS nanorods were synthesized by a two-step solvothermal/hydrothermal method, and characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), high-resolution transmission electron microscopy, UV-visible...
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The synthesis, characterisation and cytotoxicity of bisintercalating (2,2[prime or minute]:6[prime or minute],2[prime or minute][prime or minute]-terpyridine)platinum(II) complexes

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02773F, CommunicationBenjamin W. J. Harper, Janice R. Aldrich-Wright
Dinuclear (2,2[prime or minute]:6[prime or minute],2[prime or minute][prime or minute]-terpyridine)platinum(II) complexes were synthesised by tethering either thiol or pyridine based linkers. The cytotoxicity of the complexes was determined against human ovarian carcinoma cells (A2780) and its cisplatin-resistant sub-line A2780cis, as well as L1210 murine leukemia cells.
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Synthesis and coordination chemistry of 1,1,1-tris-(pyrid-2-yl)ethane

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02824D, PaperAmedeo Santoro, Carlo Sambiagio, Patrick C. McGowan, Malcolm A. Halcrow
The complexes [ML2]n+ (Mn+ = Fe2+, Co2+, Co3+, Cu2+ and Ag+), [PdCl2L] and [CuI(L)] are described. [AgL2]+ is an unusual square planar silver(I) centre (left). Exposure of [CuI(L)] to air affords mono- or dinuclear copper(II)/carbonato products. Two of the copper complexes form crystalline hydrates with complicated hydrogen bond networks (right).
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p-Type mesoscopic NiO as an active interfacial layer for carbon counter electrode based perovskite solar cells

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02904F, PaperZonghao Liu, Meng Zhang, Xiaobao Xu, Lingling Bu, Wenjun Zhang, Wenhui Li, Zhixin Zhao, Mingkui Wang, Yi-Bing Cheng, Hongshan He
Replacement of the ZrO2 insulator layer in the state-of-the-art TiO2/ZrO2/carbon structure by mesoscopic p-type NiO particles led to 39% increase of energy conversion efficiency of perovskite solar cells.
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Enhancement of thermoelectric properties by Na doping in Te-free p-type AgSbSe2

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03059A, PaperSongting Cai, Zihang Liu, Jianyong Sun, Rui Li, Weidong Fei, Jiehe Sui
Na substituting Sb in the AgSbSe2 not only improves the power factor caused by the enhanced carrier concentration, but also decreases the thermal conductivity due to point defects, nanoscale stacking faults and Na-rich precipitate. Consequently, a high ZT value of 0.92 is achieved in the AgSb0.99Na0.01Se2 sample.
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Multifunctional carbon nanotubes/ruthenium purple thin films: preparation, characterization and study of application as sensors and electrochromic materials

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02784A, PaperSamantha Husmann, Aldo J. G. Zarbin
Ruthenium purple/carbon nanotube nanocomposites are synthesized by a heterogeneous solid/liquid reaction and are applied as H2O2 sensors and electrochromic materials.
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Photocatalytic oxidation of organic compounds in a hybrid system composed of a molecular catalyst and visible light-absorbing semiconductor

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02945C, CommunicationXu Zhou, Fei Li, Xiaona Li, Hua Li, Yong Wang, Licheng Sun
Photocatalytic oxidation of organic compounds was carried out in water using a molecular catalyst and semiconductor photosensitizer.
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Competitive formation of DNA linkage isomers by a trinuclear platinum complex and the influence of pre-association

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02942A, PaperJoseph J. Moniodis, Donald S. Thomas, Murray S. Davies, Susan J. Berners-Price, Nicholas P. Farrell
The trinuclear platinum drug BB3464 pre-associates in the minor groove at two different sites on a 14-mer duplex and this dictates the nature of the adducts formed in both 5[prime or minute]-5[prime or minute] and 3[prime or minute]-3[prime or minute] directions.
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A very simple and high-yield method to synthesize nanolayered Mn oxide

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02468K, PaperMohammad Mahdi Najafpour, Emad Amini
Nanolayered Mn oxides have been prepared by a very simple, low-cost and high-yield method using soap, KOH, MnCl2 and H2O2.
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Synthesis and properties of greenish-blue-emitting iridium dendrimers with N-phenylcarbazole-based polyether dendrons by a post-dendronization route

26 November, 2014 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02815E, PaperYang Wang, Shumeng Wang, Shiyang Shao, Junqiao Ding, Lixiang Wang, Xiabin Jing, Fosong Wang
Solution processible greenish-blue-emitting Ir dendrimers with N-phenylcarbazole based polyether dendrons are developed via a convenient post-dendronization route.
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[small pi]-Excess aromatic [sigma]2P ligands: Synthesis and structure of an unprecedented [small mu ]2-P-1,3-benzazaphosphole bridged tetranuclear copper(I) acetate complex

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03072A, PaperMohammed Ghalib, Laszlo Konczol, Laszlo Nyulaszi, Gottfried Julius Palm, Carola Schulzke, Joachim Werner Heinicke
The -P=CH-NR-heterocycle 1-neopentyl-1,3-benzazaphosphole (npBAP) reacts in THF with copper(I) acetate via labile soluble complexes (npBAP)xCuOAc preferably to the insoluble tetranuclear (npBAP)2(CuOac)4 complex 1. The crystal structure analysis of 1[round bullet, filled]2CH2Cl2, grown...
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Immobilized Pd on magnetic nanoparticles bearing proline as highly efficient and retrievable Suzuki-Miyaura catalyst in aqueous media.

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02899F, CommunicationEmilie Nehlig, Bintou Waggeh, Nadine Millot, Yoann lalatonne, Laurence Motte, Erwann Guenin
A magnetically retrievable nanocatalyst was evaluated for microwave assisted Suzuki-Miyaura reaction in aqueous media. Excellent yields and conversions were obtained with low Pd loadings (down to 0.01 mol% Pd). Stability...
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A Novel Open-Framework Copper Borophosphate Containing 1-D Borophosphate Anion with 10-MR Windows and 12-MR Channels

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02840F, CommunicationYu-Quan Feng, Min Li, Huitao Fan, Qunzeng Huang, Dongfang Qiu, Hengzhen Shi
A novel open-framework copper borophosphate, Na5KCu3[B9P6O33(OH)3]∙H2O (1), has been synthesized by means of boric acid flux method. Its structure can be viewed as a 3-D open framework constructed by the...
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Na0.3WO3 Nanowires: A Multifunctional Agent for in vivo Dual-Model Imaging and Photothermal Therapy of Cancer Cells

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02927E, PaperJunqing Hu, Yuxin Zhang, Bo Li, Yunjiu Cao, Jinbao Qin, Zhiyou Peng, xiaojuan huang, Zhiyin Xiao, Rujia Zou
The combination of imaging diagnosis and photothermal ablation (PTA) therapy has become a potential treatment for cancer. In particular, tungsten bronzes have a number of unique properties such as broad...
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Electronic structure of [small beta]-RbSm(MoO4)2 and chemical bonding in molybdates

26 November, 2014 - 04:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03203A, PaperVictor V. Atuchin, A.S. Aleksandrovsky, O.D. Chimitova, Chengpeng Diao, T.A. Gavrilova, V. G. Kesler, M. S. Molokeev, A.S. Krylov, B.G. Bazarov, J.G. Bazarova, Zheshuai Lin
Microcrystals of orthorhombic rubidium samarium molybdate, [small beta]-RbSm(MoO4)2, have been fabricated by solid state synthesis at T = 450 [degree]C, 70 h, and T = 600 [degree]C, 150 h. The crystal...
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