Dalton Transactions

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Nitrosyl and carbene iron complexes bearing a [small kappa]3-SNS thioamide pincer type ligand

18 December, 2014 - 10:17

Dalton Trans., 2015, 44,1017-1022
DOI: 10.1039/C4DT03128H, PaperTatsuya Suzuki, Jun Matsumoto, Yuji Kajita, Tomohiko Inomata, Tomohiro Ozawa, Hideki Masuda
The monochelate iron complex with [small kappa]3-SNS thioamide pincer ligand, [Fe(THF)2([small kappa]3-LDPM)], gave novel complexes, [Fe(NHC)([small kappa]3-LDPM)] and [Fe(NO)2([small kappa]3-LDPM)], by substitution reactions with N heterocyclic carbene and NO molecules, respectively.
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Assembly of three coordination polymers based on a sulfonic-carboxylic ligand showing high proton conductivity

18 December, 2014 - 10:17

Dalton Trans., 2015, 44,948-954
DOI: 10.1039/C4DT02870H, PaperShu-Na Zhao, Xue-Zhi Song, Min Zhu, Xing Meng, Lan-Lan Wu, Shu-Yan Song, Cheng Wang, Hong-Jie Zhang
Three MOFs with different structures all exhibit proton conduction behavior, especially for the Cu compound with a proton conductivity of 3.46 [times] 10-3 S cm-1 at 368 K and 95% RH.
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Main group catalysed reduction of unsaturated bonds

18 December, 2014 - 10:17

Dalton Trans., 2015, 44,840-866
DOI: 10.1039/C4DT02024C, PerspectiveK. Revunova, G. I. Nikonov
This Perspective article reviews the recent developments in reduction reactions catalysed by main-group element compounds.
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A relationship among structural, electronic order-disorder effects and optical properties in crystalline TiO2 nanomaterials

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03254C, PaperEuripedes Silva Junior, Felipe de Almeida La Porta, Maximo Siu Li, Juan Andres, Jose Arana Varela, Elson Longo
The focus of this paper is on the analysis of the structural and electronic order-disorder effects at long, medium and short-range of titanium dioxide (TiO2) nanoparticles synthesized by the sol-gel...
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Direct Synthesis of Size-Tunable PbS Nanocubes and Octahedra and the pH Effect on Crystal Shape Control

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03345K, CommunicationHsiang-Shen Chen, Szu-Chieh Wu, Michael Hsuan-Yi Huang
A one-pot synthesis for the growth of PbS nanocubes and octahedra has been developed by heating an aqueous mixture of cetyltrimethylammonium bromide (CTAB), thioacetamide (TAA), lead acetate, and nitric acid...
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Hybrid ZnO/ZnS nanoforests as the electrode materials for high performance supercapacitor application

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03270E, PaperSiwen Zhang, Bosi Yin, He Jiang, Fengyu Qu, Ahmad Umar, Xiang Wu
Heterostructured ZnO/ZnS nanoforests are prepared through a simple two-step thermal evaporation method at 650 oC and 1300 oC in a tube furnace under the flow of argon gas, respectively. A...
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Fixed Distance Photoinduced Electron Transfer between Fe and Zn Porphyrins Encapsulated within the Zn HKUST-1 Metal Organic Framework

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02685C, CommunicationRandy W. Larsen, Lukasz Wojtas
An attractive strategy for the development of photocatalytic metal organic framework (MOF) materials is to co-encapsulate a photoactive electron donor with a catalytic electron acceptor within the MOF. Here we...
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Highly Stable and Sensitive LnMOF Ratiometric Thermometers Constructed with Mixed Ligands

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03421J, Paperwei yongqin, Rongjian Sa, Qiaohong Li, Wu Kechen
The mixed-lanthanide metal-organic frameworks (M'LnMOFs) applied for accurate, non-invasive and self-reference temperature measurements have been only recently recognized. It is a great challenge for chemists to fulfil thermostable structure, intense...
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Coordination Geometry of Lead Carboxylates - Spectroscopic and Crystallographic Evidence

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03075C, PaperJaclyn Catalano, Anna Murphy, Yao Yao, Glenn Yap, Nicholas Zumbulyadis, Silvia Centeno, Cecil Dybowski
Despite their versatility, only a few single-crystal X-ray structures of lead carboxylates exist, due to difficulties with solubility. In particular, the structures of long-chain metal carboxylates have not been reported....
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DOX-Cu9S5@mSiO2-PG composite fibers for orthotopic synergistic chemotherapy/photothermal tumor therapy

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03113J, PaperYinyin Chen, Zhiyao Hou, Bei Liu, shanshan huang, Chunxia Li, Jun Lin
A composite antitumor drug carrier platform, in which antitumor drug doxorubicin (DOX) loaded core-shell structured Cu9S5@mSiO2 nanoparticles were incorporated into poly([varepsilon]-caprolactone) (PCL) and Gelatin to form nanofibrous fabrics via electrospinning...
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L-lysine-assisted fabrication of PdxPt1-x/Ni(OH)2 (0 [less-than-or-equal] x [less-than-or-equal] 1) hybrids with composition-dependent catalytic properties

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03141E, PaperJiangman Zhen, Dapeng Liu, Xiao Wang, Junqi Li, Fan Wang, Yinghui Wang, Hongjie Zhang
A fast and facile self-assembly method has been developed to deposit 3-5 nm sized PdxPt1-x (0 [less-than-or-equal] x [less-than-or-equal] 1) nanoparticles (NPs) on Ni(OH)2 nanosheets. The biomolecule L-lysine has been...
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Sputtering-deposition of Ru nanoparticles onto Al2O3 modified with imidazolium ionic liquids: Synthesis, characterisation and catalysis

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03039G, PaperLucas Foppa, Leandro Luza, Aitor Gual, Daniel E Weibel, Dario Eberhardt, Sergio Ribeiro Teixera, Jairton Dupont
Well-distributed Ru nanoparticles (Ru-NPs) were produced over Al2O3 supports modified with covalently anchored imidazolium ionic liquids (ILs) containing different anions and cation lateral alkyl chain lengths by simple sputtering from...
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Antisite-disorder, magnetic and thermoelectric properties of Mo-rich Sr2Fe1-yMo1+yO6 (0 [less-than-or-equal] y [less-than-or-equal] 0.2) double perovskites

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03307H, PaperSrinivasa R. Popuri, Debbie Redpath, Gavin Chan, Ronald I. Smith, Oscar Cespedes, Jan-Willem G. Bos
A-site deficiency does not survive in Sr2-xFeMoO6 and instead Mo-rich Sr2Fe1-yMo1+yO6 perovskites, characterised by the gradual disordering of Fe and Mo, form.
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Blue phosphorescent N-heterocyclic carbene chelated Pt(II) complexes with an [small alpha]-duryl-[small beta]-diketonato ancillary ligand

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03085K, PaperSoo-Byung Ko, Hee-Jun Park, Shaolong Gong, Xiang Wang, Zheng-Hong Lu, Suning Wang
Blue phosphorescent Pt(II) complexes that display bright blue emission in the solid state have been obtained employing NHC-based C[logical and]C*-chelate ligands and an [small alpha]-duryl-[small beta]-diketonato ancillary ligand that provides steric blocking to minimize intermolecular interactions.
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Copper-promoted aerial oxidation of benzothiadiazines: Access to benzothiadiazine S-oxide heterocycles

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03467H, CommunicationJeremy Michael Rawson, Melanie Pilkington, John J Hayward, Bryce Jackson Leontowicz, Muhammad Usman Anwar, Ewan Clark
Cu2+-promoted aerial oxidation of a series of benzothiadiazines (1) under ambient conditions affords the first structurally characterised examples of thiadiazine S-oxides (2) The isolation of the homoleptic CuII 3-(2ʹ-pyridyl)benzothiadiazide-S-oxide complex...
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Helix-Coil Transition Induced by Metal Ion Interaction with a Grafted Iron-Binding Site of the CyaY Protein Family

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02796E, PaperDiego Sebastian Vazquez, William Armando Agudelo, Angel Yone, Nora Vizioli, Martin Aran, Luis Gonzalez Flecha, Mariano Camilo Gonzalez Lebrero, Javier Santos
Iron-protein interactions are involved in electron transfer reactions. Alterations of these processes are present in a number of human pathologies; among then, in Friedreich's ataxia, in which a deficiency in...
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CPMV induced synthesis of Hollow-porous SiO2 Nanocapsules with excellent performance in Drug delivery

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02549K, PaperKoushi Kumar, Pradip Paik
An idiosyncratic hollow mesoporous-SiO2 nanocapsule has been synthesized at room temperature using unmodified Cowpea mosaic Virus (CPMV) as a template, and without using any catalyst or surfactant during synthesis. The...
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Catalytic Behaviour in the Ring-Opening Polymerisation of Organoaluminiums Supported by Bulky Heteroscorpionate Ligands

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03475A, PaperAntonio Otero, Jose Castro Osma, Carlos Alonso-Moreno, agustin lara, juan fernandez, LUIS FERNANDO SANCHEZ-BARBA MERLO, Ana Maria Rodriguez
A series of alkyl organoaluminium complexes based on bulky heteroscorpionate ligands were designed as catalysts for the ring-opening polymerisation of cyclic esters. Thus, treatment of AlX3 (X = Me, Et)...
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Ionothermal Synthesis and Crystal Structures of Novel Aluminum Phosphates with in Situ Generated Templates

16 December, 2014 - 09:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03233K, PaperShanshan Man, wang zeng long, Boya Zhao, Lei Liu, Jinxiang Dong
Protic ionic liquids (PILs) are subgroup of ionic liquids and easily formed by proton transfer from a Bronsted acid to a Bronsted base. Two new crystalline aluminumphosphates, [C5H16N2][Al(PO4)(HPO4)] (AlPO-PIL1) and...
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Cationic, luminescent cyclometalated iridium(III) complexes based on substituted 2-phenylthiazole ligands

16 December, 2014 - 09:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03054K, PaperEmily C. Stokes, Emily E. Langdon-Jones, Lara M. Groves, James A. Platts, Peter N. Horton, Ian A. Fallis, Simon J. Coles, Simon J. A. Pope
Ten cationic heteroleptic iridium(III) complexes involving substituted phenylthiazole ligands reveal phosphorescence emission in solution.
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