Dalton Transactions

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Emergence of electrophilic alumination as the counterpart of established nucleophilic lithiation: an academic sojourn in organometallics with William Kaska as fellow traveler

6 April, 2015 - 15:54

Dalton Trans., 2015, 44,6671-6679
DOI: 10.1039/C4DT01036A, EditorialJohn J. Eisch
Fundamental reactions of C-Al bonds in Ziegler's nobel research, alumination, carboalumination and hydroalumination, involve attack by tricoordinate aluminum electrophiles.
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The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03360D, PaperBrian F. G. Johnson
The Ligand Polyhedral Model (LPM) is applied to the carbonyl scrambling observed on the NMR timescale for the two cluster carbonyls [Rh4(CO)12] and [Rh6(CO)16].
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Two phosphaalkene radical cations with inverse spin density distributions

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00656B, CommunicationXiaobo Pan, Xingyong Wang, Zaichao Zhang, Xinping Wang
Two phosphaalkene radical cations have been made by using a weakly coordinating anion, and they exhibit inverse spin density distributions.
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Nanoscale metallogel via self-assembly of self-assembled trinuclear coordination rings: multi-stimuli-responsive soft materials

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03715D, PaperSudhakar Ganta, Dillip Kumar Chand
A multi-stimuli-responsive metallogel is obtained by the self-assembly of an already self-assembled trinuclear palladium(II) based coordination ring of the rare M3L6 composition.
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Titanocene(III) complexes with 2-phosphinoaryloxide ligands for the catalytic dehydrogenation of dimethylamine borane

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00275C, PaperMarcus Klahn, Dirk Hollmann, Anke Spannenberg, Angelika Bruckner, Torsten Beweries
A study of the dehydrogenation of dimethylamine borane using different titanocene(III) complexes with 2-phosphinoaryloxide ligands is presented.
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Synthesis and characterization of copper(II) complexes with multidentate ligands as catalysts for the direct hydroxylation of benzene to phenol

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00575B, PaperLi Wu, Wei Zhong, Beibei Xu, Zhenhong Wei, Xiaoming Liu
Like iron(III) complexes, copper(II) complexes catalyse the direct hydroxylation of benzene to phenol with H2O2 as the oxidant and their catalytic efficiency correlates with the reduction potentials of the copper(II) complexes.
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Synthesis and characterization of bis (acetylacetonato [small kappa]-O, O[prime or minute]) [zinc(II)/copper(II)] hybrid organic-inorganic complexes as solid metal organic precursors

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00808E, PaperReza Rooydell, Ruey-Chi Wang, Sanjaya Brahma, Farzaneh Ebrahimzadeh, Chuan-Pu Liu
We have synthesized novel metal organic hybrid mixed compounds of bis (acetylacetonato [small kappa]-O, O[prime or minute]) [zinc(II)/copper(II)].
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Heteroleptic naphthalo-phthalocyaninates of lutetium: synthesis and spectral and conductivity properties

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00635J, PaperTatiana V. Dubinina, Anton D. Kosov, Elizaveta F. Petrusevich, Sergey S. Maklakov, Nataliya E. Borisova, Larisa G. Tomilova, Nikolay S. Zefirov
A series of novel near-IR absorbing heteroleptic complexes were obtained with high yields. The correlation between the nature of the substituents and spectral properties of the target complexes was determined.
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Theoretical prediction of Am(III)/Eu(III) selectivity to aid the design of actinide-lanthanide separation agents

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03275F, PaperVyacheslav S. Bryantsev, Benjamin P. Hay
A computational protocol capable of predicting the correct order of Am(III)/Eu(III) selectivity provides a theoretical basis for the design of more selective separation agents.
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Hierarchical LiZnVO4@C nanostructures with enhanced cycling stability for lithium-ion batteries

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00673B, PaperLingxing Zeng, Xiaoxia Huang, Cheng Zheng, Qingrong Qian, Qinghua Chen, Mingdeng Wei
Hierarchical LiZnVO4@C nanostructures composed of thin nanobelt aggregates were synthesized for the first time and they exhibited a high performance for LIBs.
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A one-dimensional coordination polymer based on Cu3-oximato metallacrowns bridged by benzene-1,4-dicarboxylato ligands: structure and magnetic properties

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00533G, PaperLilia Croitor, Eduard B. Coropceanu, Oleg Petuhov, Karl W. Kramer, Svetlana G. Baca, Shi-Xia Liu, Silvio Decurtins, Marina S. Fonari
A one-dimensional linear coordination polymer {[Cu3([small mu ]3-OH)(2-pyao)3(bdc)][middle dot]6(H2O)}n (1) composed of trinuclear metallacrown cores has been obtained.
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A highly sensitive room temperature H2S gas sensor based on SnO2 multi-tube arrays bio-templated from insect bristles

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00354G, PaperJunlong Tian, Feng Pan, Ruiyang Xue, Wang Zhang, Xiaotian Fang, Qinglei Liu, Yuhua Wang, Zhijian Zhang, Di Zhang
A tin oxide multi-tube array with a parallel effect was fabricated, which exhibited high sensitivity to H2S gas at room temperature.
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Utilisation of water soluble iridium catalysts for signal amplification by reversible exchange

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00311C, PaperM. Fekete, C. Gibard, G. J. Dear, G. G. R. Green, A. J. J. Hooper, A. D. Roberts, F. Cisnetti, S. B. Duckett
The catalytic hyperpolarisation of pyridine, 3-hydroxypyridine and oxazol by the Signal Amplification By Reversible Exchange (SABRE) process is achieved by a series of water soluble iridium phosphine and N-heterocyclic carbene dihydride complexes.
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An unusual three-dimensional Dy-Cd2 framework exhibiting single-ion magnet behavior

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00721F, CommunicationXue-Jing Zhang, Ke Liu, Yan-min Bing, Na Xu, Wei Shi, Peng Cheng
A framework approach was successfully performed to give a three-dimensional heterometallic compound exhibiting single-ion magnet (SIM) behavior.
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Synthesis and characterization of mixed-valence manganese fluorophosphate and analogues with clathrate-like structures: MnIII6F12(PO3(OH))8[Na8(Kx(H3O)4-x(H2O)2)MIV(OH)6] (MIV = Mn, Ti, Ge)

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00646E, PaperWei-Jian Ren, Jing-Quan Wang, Ya-Xi Huang, Zhi-Mei Sun, Yuanming Pan, Jin-Xiao Mi
A water-deficient hydrothermal method has been applied to synthesize the first-ever, mixed- and high-valence manganese (Mn3+/Mn4+) fluorophosphate with a clathrate-like structure.
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Correction: Chemistry of group 9 dimetallaborane analogues of octaborane(12)

6 April, 2015 - 15:54
Dalton Trans., 2015, 44,7068-7068
DOI: 10.1039/C5DT90059J, CorrectionSubrat Kumar Barik, Dipak Kumar Roy, Sundargopal Ghosh
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New iron tetrazolate frameworks: synthesis, temperature effect, thermal behaviour, Mossbauer and magnetic studies

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00281H, PaperVanessa Pimenta, Quang Hoang Hanh Le, Lucy Clark, Jerome Lhoste, Annie Hemon-Ribaud, Marc Leblanc, Jean-Marc Greneche, Gilles Dujardin, Philip Lightfoot, Vincent Maisonneuve
Two mixed Fe2+/Fe3+ hybrid fluorides: single crystal structures, Mossbauer spectrometry and magnetic properties.
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Study of the one-photon and two-photon properties of two water-soluble terpyridines and their zinc complexes

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00449G, PaperPengfei Shi, Qin Jiang, Xuesong Zhao, Qiong Zhang, Yupeng Tian
The terpyridine and its Zn(II) complex process large conjugation system and suitable electron donors, so that they display strong two-photon excited fluorescence.
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Correction: Unexpected optical activity of cerium in Y2O3:Ce3+, Yb3+, Er3+ up and down-conversion system

6 April, 2015 - 15:54
Dalton Trans., 2015, 44,7066-7067
DOI: 10.1039/C5DT90054A, CorrectionRiccardo Marin, Michele Back, Nicolo Mazzucco, Francesco Enrichi, Romana Frattini, Alvise Benedetti, Pietro Riello
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Quantitative aspects of the identification of Fe(II) moieties in ZSM-5 zeolites with various pore hierarchies

6 April, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00424A, PaperKinga Gora-Marek, Kamila Brylewska, Karolina A. Tarach, Minkee Choi
This work was attempted in order to provide a new and well-established approach for the quantification of Fe2+ sites in zeolites.
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