Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 1 day 17 hours ago

Remarkable LnIII3FeIII2 clusters with magnetocaloric effect and slow magnetic relaxation

5 November, 2014 - 23:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02871F, CommunicationHan Li, Wei Shi, Zheng Niu, Jingmin Zhou, Gang Xiong, Lei-Lei Li, Peng Cheng
Two remarkable pentanuclear 3d-4f clusters Ln3Fe2 were synthesized and structurally characterized. Magnetic studies indicate that Gd3Fe2 possesses the significant magnetic entropy change (-[capital Delta]Sm) of 31.7 J kg-1 K-1 and slow...
The content of this RSS Feed (c) The Royal Society of Chemistry

Tetragonal Cu2Se nanoflakes: synthesis using selenated propylamine as Se source and activation of Suzuki and Sonogashira cross coupling reactions

5 November, 2014 - 23:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03320E, PaperAjai kumar Singh, Ved Vati Singh
The metastable tetragonal Cu2Se phase as nanoflakes has been synthesized for the first time by treating CuCl2 taken in a mixture (1:1) of 1-octadecene and oleylamine with H2N-(CH2)3-SePh dissolved in...
The content of this RSS Feed (c) The Royal Society of Chemistry

Lone Pair-[small pi] Interaction-induced Generation of Non-interpenetrated and Photochromic Cuboid 3-D Naphthalene Diimide Coordination Networks

5 November, 2014 - 23:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03124E, PaperJian-Jun Liu, Yu-Jian Hong, Ying-Fang Guan, Mei-Jin Lin, Chang-Cang Huang, Wenxin Dai
Interpenetration is an intrinsic behaviour for the porous coordination networks. To prevent the interpenetration, a common strategy is the imposition of geometric or steric restrictions by incorporating bulky moieties into...
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses, structures and properties of two new organic-inorganic hybrid materials based on [varepsilon]-Zn Keggin units {[varepsilon]-PMoV8MoVI4O40-x(OH)xZn4}

5 November, 2014 - 23:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02993C, PaperYan Xu, Hao Miao, Gong Hao Hu, Jiuyu Guo, Hongxiang Wang, Yu Zhang, Hua mei
Two novel organic-inorganic hybrids, Na[PMoV8MoVI4O38(OH)2Zn4][pyim]2∙1.5H2O [[varepsilon](pyim)2] (pyim = 2-(2-Pydidyl)-imidazole) and [PMoV8MoVI4O37(OH)3Zn4]2[pyim]6∙4H2O [[varepsilon]2(pyim)6], based on [varepsilon]-Zn Keggin units {[varepsilon]-PMoV8MoVI4O40-x(OH)xZn4} have been successfully synthesized under hydrothermal conditions by controlling pH values. Structural...
The content of this RSS Feed (c) The Royal Society of Chemistry

Reductive Dechlorination of BCl3 for Efficient Ammonia Borane Regeneration

5 November, 2014 - 23:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01592D, PaperXuebin Yu, Yingbin Tan, Lijun Zhang, Xiaowei Chen
This paper reports a complete AB regeneration process, in which Bu3SnH was utilized as a reductant for reductive dechlorination of BCl3, and Et2PhN was selected as "helper ligands" to generate...
The content of this RSS Feed (c) The Royal Society of Chemistry

Epitaxial growth of silver chloride crystals on bismuth oxychloride

5 November, 2014 - 23:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02666G, PaperBoris B. Bokhonov
AgCl crystals precipitating on the surface of bismuth oxychloride crystals show orientation ordering with the (001)BiOCl||(100)AgCl.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses, crystal structures, MMCT and magnetic properties of four one-dimensional cyanide-bridged complexes comprised of MII-CN-FeIII (M = Fe, Ru, Os)

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17453-17462
DOI: 10.1039/C4DT02272F, PaperYong Wang, Xiao Ma, Shengmin Hu, Yuehong Wen, Zhenzhen Xue, Xiaoquan Zhu, Xudong Zhang, Tianlu Sheng, Xintao Wu
Four 1D cyanide-bridged complexes [cis-MII(L)2(CN)2FeIII(salen)](PF6) (3-6) have been synthesized, of which 3 and 4 are Class II mixed-valence complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Electronic effects of substituents on the stability of the iridanaphthalene compound [Ir[upper bond 1 start]Cp*{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1 end]6H4)(Ph)}(PMe3)]PF6

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17366-17374
DOI: 10.1039/C4DT02744B, PaperM. Talavera, J. Bravo, J. Castro, S. Garcia-Fontan, J. M. Hermida-Ramon, S. Bolano
How do the substituents on the naphthalene skeleton affect the stability of the iridanaphthalene complex [Ir[upper bond 1 start]Cp*{[double bond, length as m-dash]C(OMe)CH[double bond, length as m-dash]C(o-C[upper bond 1 end]6H4)(Ph)}(PMe3)]PF6?
The content of this RSS Feed (c) The Royal Society of Chemistry

Porous SnO2-Fe2O3 nanocubes with improved electrochemical performance for lithium ion batteries

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17544-17550
DOI: 10.1039/C4DT02028F, PaperYuan Yan, Feihu Du, Xiaoping Shen, Zhenyuan Ji, Hu Zhou, Guoxing Zhu
Porous SnO2-Fe2O3 nanocubes were successfully fabricated by simply annealing the precursor of Sn3[Fe(CN)6]4 nanocubes, which exhibit excellent lithium storage performance.
The content of this RSS Feed (c) The Royal Society of Chemistry

Speciation and the structure of lead(II) in hyper-alkaline aqueous solution

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17539-17543
DOI: 10.1039/C4DT02757D, PaperEva G. Bajnoczi, Istvan Palinko, Tamas Kortvelyesi, Szabolcs Balint, Imre Bako, Pal Sipos, Ingmar Persson
In hyper-alkaline aqueous solutions, lead(II) is present exclusively as [Pb(OH)3]-. Other species, like [Pb(OH)4]2-, [PbOOH]- or [PbO2]2- are not detectable.
The content of this RSS Feed (c) The Royal Society of Chemistry

Supported Rh-phosphine complex catalysts for continuous gas-phase decarbonylation of aldehydes

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17230-17235
DOI: 10.1039/C4DT01629G, CommunicationPhillip Malcho, Eduardo J. Garcia-Suarez, Uffe Vie Mentzel, Christian Engelbrekt, Anders Riisager
Heterogeneous silica supported rhodium-phosphine complex catalysts are employed for the first time in the catalytic decarbonylation of aldehydes in the continuous gas-phase.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ag incorporated Mn3O4/AC nanocomposite based supercapacitor devices with high energy density and power density

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17528-17538
DOI: 10.1039/C4DT02287D, PaperS. Nagamuthu, S. Vijayakumar, G. Muralidharan
Silver incorporated Mn3O4/amorphous carbon (AC) nanocomposites are synthesized by a green chemistry method.
The content of this RSS Feed (c) The Royal Society of Chemistry

Shape controlled synthesis of hierarchical nickel sulfide by the hydrothermal method

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17445-17452
DOI: 10.1039/C4DT02059F, PaperR. Karthikeyan, M. Navaneethan, J. Archana, D. Thangaraju, M. Arivanandhan, Y. Hayakawa
Hierarchical structures of nickel sulfide have been grown by the hydrothermal method.
The content of this RSS Feed (c) The Royal Society of Chemistry

Mixed amido-/imido-/guanidinato niobium complexes: synthesis and the effect of ligands on insertion reactions

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17434-17444
DOI: 10.1039/C4DT01975J, PaperDavid Elorriaga, Fernando Carrillo-Hermosilla, Antonio Antinolo, Isabel Lopez-Solera, Rafael Fernandez-Galan, Elena Villasenor
Mixed amido-/imido niobium complexes supported by guanidinato ligands were synthesized and their behaviour on some insertion reactions was studied.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, cytotoxic and hydrolytic studies of titanium complexes anchored by a tripodal diamine bis(phenolate) ligand

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17422-17433
DOI: 10.1039/C4DT00975D, PaperSonia Barroso, Ana M. Coelho, Santiago Gomez-Ruiz, Maria Jose Calhorda, Zeljko Zizak, Goran N. Kaluderovic, Ana M. Martins
The reactivity, cytotoxic studies and hydrolytic behaviour of diamine bis(phenolate) titanium complexes are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Simple and extremely efficient blue emitters based on mononuclear Cu(I)-halide complexes with delayed fluorescence

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17317-17323
DOI: 10.1039/C4DT02709D, PaperHiroki Ohara, Atsushi Kobayashi, Masako Kato
Mononuclear Cu(I)-halide complexes with a ternary ligand system exhibit blue light emission based on delayed fluorescence with extremely high quantum yields, approaching 100% in the solid states.
The content of this RSS Feed (c) The Royal Society of Chemistry

Interactions of gold-based drugs with proteins: the structure and stability of the adduct formed in the reaction between lysozyme and the cytotoxic gold(III) compound Auoxo3

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17483-17488
DOI: 10.1039/C4DT02332C, PaperIrene Russo Krauss, Luigi Messori, Maria Agostina Cinellu, Daniela Marasco, Rosalba Sirignano, Antonello Merlino
Auoxo3 breaks down and produces reactive gold(I) species able to bind lysozyme and form stable derivative.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, characterization and biocompatibility of chitosan functionalized superparamagnetic nanoparticles for heat activated curing of cancer cells

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17343-17351
DOI: 10.1039/C4DT02293A, PaperN. D. Thorat, S. V. Otari, R. M. Patil, R. A. Bohara, H. M. Yadav, V. B. Koli, A. K. Chaurasia, R. S. Ningthoujam
The LSMO-chitosan core cell formation improves cell viability, colloidal stability and hyperthermia properties and is suitable in a cancer cell acidic environment.
The content of this RSS Feed (c) The Royal Society of Chemistry

Probing the magnetic and magnetothermal properties of M(II)-Ln(III) complexes (where M(II) = Ni or Zn; Ln(III) = La or Pr or Gd)

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17375-17384
DOI: 10.1039/C4DT02360A, PaperNaushad Ahmed, Chinmoy Das, Shefali Vaidya, Anant Kumar Srivastava, Stuart K. Langley, Keith S. Murray, Maheswaran Shanmugam
We report the crystal structures of Ni(II)-Ln(III) (where Ln = Gd or Pr) complexes and their suitably substituted diamagnetic analogues. Magnetic characterization revealed the nature of the magnetic exchange interactions and the magnetothermal properties.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structure and properties of 2D lanthanide coordination polymers based on N-heterocyclic arylpolycarboxylate ligands

5 November, 2014 - 23:54

Dalton Trans., 2014, 43,17385-17394
DOI: 10.1039/C4DT02517B, PaperLi-Xin You, Shu-Ju Wang, Gang Xiong, Fu Ding, Katrien W. Meert, Dirk Poelman, Philippe F. Smet, Bao-Yi Ren, Yan-Wen Tian, Ya-Guang Sun
Eight 2D LCPs based on the N-heterocyclic arylpolycarboxylate ligands were prepared, and the luminescence and magnetic properties were studied.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.