Dalton Transactions

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Investigation of composition dependent structural and optical properties of the Zn1-xCdxS, coaxial Zn0.99-xCdxCu0.01S/ZnS, Zn0.99-xCdxMn0.01S nanorods generated by a one-step hydrothermal process

29 June, 2014 - 15:17

Dalton Trans., 2014, 43,11019-11026
DOI: 10.1039/C4DT00667D, PaperDonglai Han, Jian Cao, Shuo Yang, Jinghai Yang, Bingji Wang, Lin Fan, Qianyu Liu, Tingting Wang, Haifeng Niu
Doping Cu2+ and Mn2+ ions into Zn1-xCdxS NRs makes the samples exhibit a strong emission at 509.6 and 583 nm.
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Structure-direction in the crystallization of ITW zeolites using 2-ethyl-1,3,4-trimethylimidazolium

29 June, 2014 - 15:17

Dalton Trans., 2014, 43,10760-10766
DOI: 10.1039/C4DT00828F, PaperAlex Rojas, Miguel A. Camblor
2-Ethyl-1,3,4-trimethylimidazolium, the fifth and largest imidazolium cation able to produce the pure silica zeolite ITW, affords together with fluoride a significant flexibility enhancement of the SiO2 framework.
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Nanocasted synthesis of ordered mesoporous cerium iron mixed oxide and its excellent performances for As(V) and Cr(VI) removal from aqueous solutions

29 June, 2014 - 15:17

Dalton Trans., 2014, 43,10767-10777
DOI: 10.1039/C4DT01101E, PaperBo Chen, Zhiliang Zhu, Jun Hong, Zhipan Wen, Jie Ma, Yanling Qiu, Junhong Chen
Ordered mesoporous cerium iron mixed oxide shows excellent adsorption performance for As(V) and Cr(VI) in aqueous solutions.
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Isoquinoline-derivatized tris(2-pyridylmethyl)amines as fluorescent zinc sensors with strict Zn2+/Cd2+ selectivity

27 June, 2014 - 14:54

Dalton Trans., 2014, 43,10751-10759
DOI: 10.1039/C4DT01054J, PaperYuji Mikata, Keiko Kawata, Saaya Takeuchi, Kaori Nakanishi, Hideo Konno, Saori Itami, Keiko Yasuda, Satoshi Tamotsu, Shawn C. Burdette
The new fluorescent probe 7-MeO-1-isoBQPA exhibits a highly Zn-specific response, which is applicable in fluorescence microscopic analysis of living cells.
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Si-H bond activation at {(NHC)2Ni0} leading to hydrido silyl and bis(silyl) complexes: a versatile tool for catalytic Si-H/D exchange, acceptorless dehydrogenative coupling of hydrosilanes, and hydrogenation of disilanes to hydrosilanes

27 June, 2014 - 14:54

Dalton Trans., 2014, 43,10816-10827
DOI: 10.1039/C4DT01250J, PaperDavid Schmidt, Thomas Zell, Thomas Schaub, Udo Radius
The unique reactivity of the nickel(0) complex [Ni2(iPr2Im)4(COD)] towards hydrosilanes in stoichiometric and catalytic reactions is reported.
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Oxygen insertion reactions of mixed N-heterocyclic carbene-oxazolinylborato zinc alkyl complexes

25 June, 2014 - 14:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01011F, PaperSongchen Xu, William C. Everett, Arkady Ellern, Theresa L. Windus, Aaron D. Sadow
An oxazolinyl-carbene borate zinc ethyl compound reacts with O2 at room temperature to provide a monometallic zinc ethylperoxide.
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Synthesis and molecular structure of an abnormal carbene-gallium chloride complex

25 June, 2014 - 14:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00933A, CommunicationMingwei Chen, Yuzhong Wang, Robert J. Gilliard, Jr., Pingrong Wei, Nichole A. Schwartz, Gregory H. Robinson
The C4-lithiated N-heterocyclic carbene : BEt3 complex was synthesized by low-temperature lithiation of the N-heterocyclic carbene : BEt3 adduct, which may react with GaCl3 in THF to form the first abnormal N-heterocyclic carbene : GaCl3 complex.
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Layered inorganic solids

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10274-10275
DOI: 10.1039/C4DT90078B, EditorialJiri Cejka, Russell E. Morris, Petr Nachtigall, Wieslaw J. Roth
Welcome to this themed issue of Dalton Transactions entitled "Layered Inorganic Solids".
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Storylines in intercalation chemistry

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10276-10291
DOI: 10.1039/C4DT00203B, PerspectiveA. Lerf
Intercalation chemistry taking into account the interstratification and disorder phenomena is a valuable preparative tool for the design of artificial layered artificial nanostructures.
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Porous nitrogen-doped carbon microspheres as anode materials for lithium ion batteries

25 June, 2014 - 14:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01223B, CommunicationTaiqiang Chen, Likun Pan, T. A. J. Loh, D. H. C. Chua, Yefeng Yao, Qun Chen, Dongsheng Li, Wei Qin, Zhuo Sun
Porous nitrogen-doped carbon microspheres, synthesized via a microwave-assisted method and thermal treatment, exhibit excellent electrochemical performance for lithium ion batteries.
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Ship-in-bottle synthesis of the mixed-layered compounds of clay silicate/zirconium phosphate

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10642-10650
DOI: 10.1039/C4DT01126K, PaperHiroshi Kawagoe, Naoya Imo-oka, Hiroyasu Shinohara, Shoji Yamanaka
An attempt was made to synthesize artificial mixed-layered compounds between montmorillonite silicate and [small alpha]-zirconium phosphate using a ship-in-bottle approach.
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The role of boric acid in the synthesis of Eni Carbon Silicates

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10617-10627
DOI: 10.1039/C4DT00919C, PaperStefano Zanardi, Giuseppe Bellussi, Wallace O'Neil Parker Jr., Erica Montanari, Michela Bellettato, Giuseppe Cruciani, Angela Carati, Stefania Guidetti, Caterina Rizzo, Roberto Millini
Boric acid accelerates the crystallization rate of Eni Carbon Silicates improving their crystallinity and phase purity, favoring also the formation of new structures.
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Topotactic condensation of layer silicates with ferrierite-type layers forming porous tectosilicates

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10396-10416
DOI: 10.1039/C4DT00262H, PaperB. Marler, Y. Wang, J. Song, H. Gies
Hydrous layered silicates containing ferrierite-type layers are a structurally versatile family of materials which can be converted into microporous silicates by topotactic condensation or interlayer expansion.
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A controlled spatial distribution of functional units in the two dimensional nanospace of layered silicates and titanates

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10340-10354
DOI: 10.1039/C4DT00147H, PerspectiveMakoto Ogawa, Kanji Saito, Minoru Sohmiya
The effects of the spatial distribution of functional units in the interlayer space of intercalation compounds are discussed.
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Peculiar behavior of MWW materials in aldol condensation of furfural and acetone

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10628-10641
DOI: 10.1039/C4DT00184B, PaperOleg Kikhtyanin, Pavla Chlubna, Tereza Jindrova, David Kubicka
MWW family of different structural types (MCM-22, MCM-49, MCM-56 and MCM-36) was used as catalysts for aldol condensation of furfural and acetone studied in a batch reactor at 100 [degree]C, autogenous pressure and a reaction time of 0-4 h.
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Reactivity and applications of layered silicates and layered double hydroxides

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10365-10387
DOI: 10.1039/C4DT00573B, PerspectiveThangaraj Selvam, Alexandra Inayat, Wilhelm Schwieger
The reactivity and applications of layered sodium silicates and layered double hydroxides (LDHs) are described in more detail.
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A force field for tricalcium aluminate to characterize surface properties, initial hydration, and organically modified interfaces in atomic resolution

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10602-10616
DOI: 10.1039/C4DT00438H, PaperRatan K. Mishra, Lucia Fernandez-Carrasco, Robert J. Flatt, Hendrik Heinz
A force field for tricalcium aluminate is presented, validated, and applied to generate insight into surface forces, the hydration reaction, and molecular adsorption that remains elusive from experiment.
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Ab initio structure determination of interlayer expanded zeolites by single crystal rotation electron diffraction

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10593-10601
DOI: 10.1039/C4DT00458B, PaperPeng Guo, Leifeng Liu, Yifeng Yun, Jie Su, Wei Wan, Hermann Gies, Haiyan Zhang, Feng-Shou Xiao, Xiaodong Zou
Rotation electron diffraction (RED) combines the beam tilt and goniometer tilt to obtain single crystal electron diffraction data, which has been used for ab initio structure determination of interlayer expanded zeolites.
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Surface modification of layered zirconium phosphates: a novel pathway to multifunctional materials

25 June, 2014 - 14:17

Dalton Trans., 2014, 43,10328-10339
DOI: 10.1039/C4DT00613E, PerspectiveBrian M. Mosby, Agustin Diaz, Abraham Clearfield
The combination of surface modification and intercalation chemistry of inorganic layered materials allows for the design of nanoparticles for specific applications.
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Layered double hydroxide (LDH) derived catalysts for simultaneous catalytic removal of soot and NOx

23 June, 2014 - 13:54

Dalton Trans., 2014, 43,10317-10327
DOI: 10.1039/C3DT52896K, PerspectiveRuoyan Yang, Yanshan Gao, Junya Wang, Qiang Wang
The latest progress in layered double hydroxides derived catalysts for the simultaneous catalytic removal of soot and NOx was reviewed.
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