Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 12 hours 51 min ago

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02585G, PaperClement Camp, Oliver Cooper, Julie Andrez, Jacques PECAUT, M Mazzanti
Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid...
The content of this RSS Feed (c) The Royal Society of Chemistry

Abnormal luminescent property of Mn2+ in [small alpha]-LiZnBO3:Mn2+

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02626H, PaperHongrun Wang, Li Wu, Huan Yi, Biao Wang, Liwei Wu, Yuelong Gu, Yi Zhang
Mn2+-activated red phosphor [small alpha]-LiZnBO3:Mn2+ was synthesized by solid state reaction. ESR spectra prove that the doped ions are Mn2+. The doped Mn2+ ion is inclined to occupy Zn2+ site which...
The content of this RSS Feed (c) The Royal Society of Chemistry

Small Molecular Amine Mediated Synthesis of Hydrophilic CdS Nanorods and their Photoelectrochemical Water Splitting Performance

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02671C, PaperChunlin Bao, Guo Xing Zhu, Jing Yang, Miaomiao Liu, Rongxian Zhang, Xiao Ping Shen
Photoelectrochemical (PEC) water splitting is a promising route for solar energy harvesting and storage, but it has been highly limited by the performance of the semiconductor photoelectrodes. Herein, we report...
The content of this RSS Feed (c) The Royal Society of Chemistry

Multi-step mechanism and integrity of titanate nanoribbons

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02573C, PaperVanessa Bellat, Remi CHASSAGNON, Olivier HEINTZ, Lucien SAVIOT, David VANDROUX, Nadine Millot
A one-step hydrothermal treatment of TiO2 powders in strongly basic conditions has been used to synthesize titanate nanoribbons. The nanoparticles were thoroughly characterized using several methods including transmission electron microscopy...
The content of this RSS Feed (c) The Royal Society of Chemistry

Two types of lanthanide selenidostannates(IV) first prepared under same solvothermal conditions

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03099K, PaperJian Zhou, Hong Xiao, Hong-Ping Xiao, Tao Yang, Hua-Hong Zou, Xing Liu, Rongqing Zhao, Qiuling Tang
Two types of lanthanide selenidostannates(IV) [Ln2(tepa)2([small mu ]-OH)2Sn2Se6] {Ln = Y(Ia), Pr (Ib), Dy (Ic), Er (Id), Tm(Ie); tepa = tetraethylenepentamine} and [Ln2(tepa)2([small mu ]2-OH)2Cl2]2[Sn4Se10][round bullet, filled]4H2O {Ln = Y (IIa), Dy (IIb), Er (IIc), Tm(IId)}...
The content of this RSS Feed (c) The Royal Society of Chemistry

Series of open-framework aluminoborates containing B5O10 clusters

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02632B, PaperGuo-Yu Yang, Li Wei, Guo-Ming Wang, Huan He, Bai-Feng Yang
Three new open-framework aluminoborates (ABOs), Rb2AlB5O10[round bullet, filled]4H2O (1), [C5N2H16]AlB5O10 (2, C5N2H16 = N-ethyl-1,3-diaminopropane) and [H2dap][(CH3)2NH]AlB5O10 (3, dap = 1,2-diaminopropane) have been made under solvothermal conditions and characterized by elemental analysis, IR,...
The content of this RSS Feed (c) The Royal Society of Chemistry

In situ tetrazole templated chair-like decanuclear azido-cobalt(II) SMM containing both tetra- and octa-hedral Co(II) ions

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03211J, CommunicationYuan-Zhu Zhang, Song Gao, Osamu Sato
An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18].4MeOH.2H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both...
The content of this RSS Feed (c) The Royal Society of Chemistry

The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02773F, CommunicationBenjamin William John Harper, Janice Rae Aldrich-Wright
Dinuclear (2,2':6',2''-terpyridine)platinum(II) (PtTerpy) complexes were synthesised by tethering either thiol or pyridine based linkers. All intermediates and resulting complexes were characterised using a combination of 1H and 195Pt NMR, two-dimensional...
The content of this RSS Feed (c) The Royal Society of Chemistry

The First Tritopic Bridging Ligand 1,3,5-tris(4-carboxyphenyl)-benzene (H3BTB) Functionalized Porous Polyoxometalate-Based Metal-Organic Framework (POMOF): From Design, Sythesis to Electrocatalytic Properties

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02486A, PaperBao-Xia Dong, Lu Chen, Shi-yang Zhang, Jun Ge, Liang Song, Hui Tian, Yun-Lei Teng, Wen-long Liu
Replacing the metal ions (or metal clusters) in the routine MOFs with size-matched polyoxoanions to construct POM-based MOF materials (POMOF) combining well-defined crystalline structures, high surface areas, regular and tunable...
The content of this RSS Feed (c) The Royal Society of Chemistry

Copper(II) Coordination Polymers: Tunable Structures and Different Activation Effect of Hydrogen Peroxide for the Degradation of Methyl Orange under Visible Light Irradiation

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02440K, PaperHongwei Hou, Lu Liu, Dongqing Wu, Bei Zhao, Xiao Han, Jie Wu, yaoting Fan
By tuning synthesis conditions, based on a conformation-sensitive ligand 1,4-bis(1,2,4-triazole-1-methylene)-2,3,5,6-tetramethyl benzene (btmx) and Cu(NO3)2[round bullet, filled]3H2O/CuCl2[round bullet, filled]2H2O, we obtained three Cu(II) coordination polymers with diverse structures, namely, {[Cu(btmx)2(H2O)][round bullet, filled]2NO3}n (1), {[Cu(btmx)2(Cl)2][round bullet, filled]5H2O}n (2) and {[Cu(btmx)(Cl)2]n...
The content of this RSS Feed (c) The Royal Society of Chemistry

Density functional theory investigation of the layered uranium oxides U3O8 and U2O5

12 November, 2014 - 01:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02493A, PaperNicholas A. Brincat, Stephen C. Parker, Marco Molinari, Geoffrey C. Allen, Mark T. Storr
New predictions of structural, electronic and mechanical properties of layered uranium oxides using DFT + U calculations.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dinuclear First-Row Transition Metal Complexes with a Naphthyridine-Based Dinucleating Ligand

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02727B, PaperTimothy C Davenport, T. Don Tilley
A series of dinuclear and tetranuclear first-row transition metal complexes were synthesized with the dinucleating ligand 2,7-bis(di(2-pyridyl)fluoromethyl)-1,8-naphthyridine (DPFN). The coordination pocket and rigidity of the DPFN ligand enforces pseudo-octahedral geometries...
The content of this RSS Feed (c) The Royal Society of Chemistry

BaMn9II(VO4)6(OH)2: a homospin ferrimagnet with a broken spinel-lattice of B-sites

12 November, 2014 - 01:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02930E, PaperWenbin Guo, Zhangzhen He, Yingying Tang, Suyun Zhang, Ming Yang, Wendan Cheng
A new homospin ferrimagnet BaMn9II(VO4)6(OH)2 exhibits a unique structural feature with a reverse triangular dipyramid Mn7 spin lattice, in which such a lattice can be considered as a broken spin lattice of B-sites in spinel compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Crystal Structure and Temperature-Dependent Luminescence of a Heterotetranuclear Sodium-Europium(III) [small beta]-diketonate Complex

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02301C, CommunicationSofia M. Bruno, Duarte Ananias, Filipe Alexandre Almeida Paz, Martyn Pillinger, Anabela A. Valente, Luis Antonio Dias Carlos, Isabel S. Goncalves
A heterotetranuclear Na2Eu2 complex with uncommon photoluminescence properties is reported. The complex exhibits good emission efficiency at ambient temperature, coupled with strong temperature dependence of the emission intensity and lifetime...
The content of this RSS Feed (c) The Royal Society of Chemistry

Heterojunction engineering of graphitic carbon nitride (g-C3N4) via Pt loading with improved daylight-induced photocatalytic reduction of carbon dioxide to methane

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02940B, PaperWee-Jun Ong, Lling-Lling Tan, Siang-Piao Chai, Siek Ting Yong
In this paper, noble-metal Pt nanoparticles of around 2.5 nm were deposited on graphitic carbon nitride (g-C3N4) synthesized by chemical reduction process in ethylene glycol. Compared with pure g-C3N4, the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Silver Coordination Polymers with Tri- and Hexacyanoethyl-functionalized Macrocyclic Ligands

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02604G, PaperZhen Ma, Huaduan Shi, Xiuqiang Deng, M. Fatima C. Guedes da Silva, Luisa Martins, Armando J. L. Pombeiro
Tri- and hexa-cyanoethyl functionalized 17- (L1) and 42-membered (L2) macrocyclic compounds were obtained by [1+1] (for L1) or [2+2] (for L2) cyclocondensation of the corresponding dialdehyde and diethylenetriamine, followed by...
The content of this RSS Feed (c) The Royal Society of Chemistry

Actinide selectivity of 1,10-phenanthroline-2,9-dicarboxamide and its derivatives: A theoretical prediction followed by experimental validation

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02402H, PaperDebashree Manna, S. Mula, A Bhattacharyya, S Chattopadhyay, T K Ghanty
The conventional concept of selective complexation of actinides with soft donor ligands (either S or N donor) has been modified here through exploiting the concept, "intra-ligand synergism", where hard donor...
The content of this RSS Feed (c) The Royal Society of Chemistry

Oxyanions in Perovskites: From Superconductors to Solid Oxide Fuel Cells

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03036B, PerspectiveCathryn Ann Hancock, Jose Porras, Philip J Keenan, Peter Slater
In this article we review work on oxyanion (carbonate, borate, nitrate, phosphate, sulphate, silicate) doping in perovskite materials beginning with early work on doping studies in superconducting cuprates, and extending...
The content of this RSS Feed (c) The Royal Society of Chemistry

Argentivorous Molecules Bearing Three Aromatic Side Arms: Synthesis of Triple-Armed Cyclens and Their Complexing Property towards Ag+

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02954B, PaperYoichi Habata, Juli Kizaki, Yasuhiro Hosoi, Mari Ikeda, Shunsuke Kuwahara
Triple-armed cyclens bearing three aromatic side-arms were prepared in three steps from (3R,5S)-3,5-dimethyl-1,4,7,10-tetraazacyclododecane-2,6-dione. Ag+-induced 1H NMR and UV-vis spectral changes suggest that the aromatic side-arms cover the Ag+ incorporated in...
The content of this RSS Feed (c) The Royal Society of Chemistry

Optimizing the high-field relaxivity by self-assembling of macrocyclic Gd(III) complexes

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02971B, PaperDale Lawson, Alessandro Barge, Enzo Terreno, David Parker, Silvio Aime, Mauro Botta
Using recognition moieties that bind to the inner co-ordination sphere of a monomeric DO3A-type di-aqua complex, dimeric poly(aminocarboxylate) gadolinium(III) compounds can be formed with greatly enhanced relaxivities, arising from optimized...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.