Dalton Transactions

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RSC - Dalton Trans. latest articles
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Geometric, electronic and magnetic structures of S = 19/2 and S = 20/2 thiophene-2-carboxylate functionalized Mn12 single molecule magnets

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,167-175
DOI: 10.1039/C4DT02703E, PaperJorge H. Rodriguez, Christopher J. Ziegler
Hydrogen bonding of water molecules to Mn4O4 inner cubane of S = 19/2 Mn12 SMM gives rise to geometric and magnetic asymmetries. Two Mn ions hydrogen bonded to water molecules depart from their Mn4+(S = 3/2) states and acquire an incipient Mn3+(S = 4/2) character. The magnetic moment vectors of the cubane Mn ions are inequivalent.
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Redox-active multinuclear Pd(II) complexes with bis- and tris-mesoionic carbenes

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,46-49
DOI: 10.1039/C4DT03239J, CommunicationRamananda Maity, Margarethe van der Meer, Biprajit Sarkar
Synthesis of a ligand platform to generate di- and tri-mesoionic carbenes is reported together with their multinuclear Pd(II) complexes.
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Stable anode performance of vanadium oxide hydrate semi-microspheres and their graphene based composite microspheres in sodium-ion batteries

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,146-150
DOI: 10.1039/C4DT02988G, PaperHailong Fei, Zhiwei Li, Wenjing Feng, Xin Liu
A novel graphene based VO2 hydrate anode material delivers a high capacity for sodium-ion batteries.
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Structural, optical and sensing properties of novel Eu(III) complexes with furan- and pyridine-based ligands

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,182-192
DOI: 10.1039/C4DT02326A, PaperFabio Piccinelli, Marco Bettinelli, Andrea Melchior, Cristian Grazioli, Marilena Tolazzi
Effect of the ligand's donor ability on the luminescence sensing of nitrate anions.
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Synthesis, structure and catalytic application of lead(II) complexes in cyanosilylation reactions

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,268-280
DOI: 10.1039/C4DT02316A, PaperAnirban Karmakar, Susanta Hazra, M. Fatima C. Guedes da Silva, Armando J. L. Pombeiro
3-Aminopyrazine-2-carboxylic acid is utilized to synthesize six new Pb(II) complexes with various dimensionalities, which act as heterogeneous catalysts for cyanosilylation of aldehydes with trimethylsilyl cyanide.
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Oxidative halogenation of cisplatin and carboplatin: synthesis, spectroscopy, and crystal and molecular structures of Pt(IV) prodrugs

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,119-129
DOI: 10.1039/C4DT02627F, PaperTimothy C. Johnstone, Sarah M. Alexander, Justin J. Wilson, Stephen J. Lippard
The oxidative halogenation of cisplatin and carboplatin has been explored spectroscopically, crystallographically, and computationally.
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Enhanced visible light photocatalytic activity of ZnO doped with down-conversion NaSrBO3:Tb3+ phosphors

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,97-103
DOI: 10.1039/C4DT01252F, CommunicationXinjuan Liu, Xiaojun Wang, Huili Li, Jinliang Li, Likun Pan, Jing Zhang, Guoquan Min, Zhuo Sun, Changqing Sun
ZnO-NaSrBO3:Tb3+ composites were synthesized using microwave-assisted reaction for visible light photocatalytic degradation of methylene blue with a high degradation rate.
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Biomolecule-mediated CdS-TiO2-reduced graphene oxide ternary nanocomposites for efficient visible light-driven photocatalysis

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,193-201
DOI: 10.1039/C4DT02749C, PaperSoumen Dutta, Ramakrishna Sahoo, Chaiti Ray, Sougata Sarkar, Jayasmita Jana, Yuichi Negishi, Tarasankar Pal
Charge recombination in yellow CdS has been overcome by rGO and interfacial TiO2 to show maximum visible-light-driven photocatalytic activity.
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Chiral mononuclear lanthanide complexes and the field-induced single-ion magnet behaviour of a Dy analogue

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,223-229
DOI: 10.1039/C4DT02889A, PaperShuang-Yan Lin, Chao Wang, Lang Zhao, Jianfeng Wu, Jinkui Tang
A rare series of enantiopure mononuclear lanthanide complex pairs were obtained by using a chiral macrocyclic ligand and thiocyanate. The Dy complex was revealed to be a rare seven-coordinated lanthanide-based SIM encapsulated in a macrocyclic ligand.
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The synthesis, characterisation and cytotoxicity of bisintercalating (2,2[prime or minute]:6[prime or minute],2[prime or minute][prime or minute]-terpyridine)platinum(II) complexes

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,87-96
DOI: 10.1039/C4DT02773F, CommunicationBenjamin W. J. Harper, Janice R. Aldrich-Wright
Dinuclear (2,2[prime or minute]:6[prime or minute],2[prime or minute][prime or minute]-terpyridine)platinum(II) complexes were synthesised by tethering either thiol or pyridine based linkers. The cytotoxicity of the complexes was determined against human ovarian carcinoma cells (A2780) and its cisplatin-resistant sub-line A2780cis, as well as L1210 murine leukemia cells.
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Stabilization of Cu2O nanoparticles on a 2D metal-organic framework for catalytic Huisgen 1,3-dipolar cycloaddition reaction

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,83-86
DOI: 10.1039/C4DT02661F, CommunicationKolleboyina Jayaramulu, Venkata M. Suresh, Tapas Kumar Maji
A 2D porous matrix with stabilized Cu2O NPs (Cu2O@MOF) has been studied for use in the catalytic 1,3-dipolar Huisgen cycloaddition reaction for the preparation of 1,2,3-triazoles.
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1,1-Carboboration to tellurium-boron intramolecular frustrated Lewis pairs

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,71-74
DOI: 10.1039/C4DT03241A, CommunicationFu An Tsao, Douglas W. Stephan
The tellurium acetylide Ph(CH2)2TeCCPh reacts with boranes via 1,1-carboboration to give a series of borylated vinyl telluroethers.
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Self-assembled synthesis of hierarchical Zn2GeO4 core-shell microspheres with enhanced photocatalytic activity

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,75-82
DOI: 10.1039/C4DT02803A, CommunicationWeiwei Zhao, Chao Zhang, Yanmei Shi, Rui Wu, Bin Zhang
Hierarchical Zn2GeO4 core-shell microspheres exhibit enhanced photocatalytic activity and stability towards photocatalytic degradation of organic pollutants.
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Cyclic trinuclear copper(I), silver(I), and gold(I) complexes: a theoretical insight

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,377-385
DOI: 10.1039/C4DT02514H, PaperGiovanni F. Caramori, Rafael M. Piccoli, Maximiliano Segala, Alvaro Munoz-Castro, Raul Guajardo-Maturana, Diego M. Andrada, Gernot Frenking
Analysis of the bonding and magnetic response in ligand supported coinage metal macrocycles.
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Cleavage of an aryl carbon-nitrogen bond of a phosphazido iron(II) complex promoted by hydride metathesis

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,54-57
DOI: 10.1039/C4DT03136A, CommunicationTakahiko Ogawa, Tatsuya Suzuki, Nicholas M. Hein, Fraser S. Pick, Michael D. Fryzuk
The unexpected reaction of a Fe(II) enamidophosphazide complex with KBEt3H, which results in the elimination of N2 and 1,3-Me2C6H4 to generate a dinuclear Fe(II) derivative with bridging phosphinimido units, is presented along with mechanistic studies.
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Tuning the luminescence behaviors of a chloroplatinum(II) complex by component exchanges of dynamic acylhydrazone bonds

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,66-70
DOI: 10.1039/C4DT02912G, CommunicationJianjun Liang, Huanting Huang, Lipeng He, Nijuan Liu, Yanhuan Chen, Weifeng Bu
The exchange reactions of dynamic acylhydrazone bonds with acylhydrazine or aldehyde lead to controllable emissions of a cationic chloroplatinum(II) complex in water.
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Three multi-nuclear clusters and one infinite chain induced by a pendant 4-butyl-1H-pyrazole ligand for modification of Keggin anions

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,386-394
DOI: 10.1039/C4DT02821J, PaperAi-xiang Tian, Ya-li Ning, Jun Ying, Xue Hou, Tian-jiao Li, Xiu-li Wang
By utilizing a pendant 4-butyl-1H-pyrazole, four POM-based multi-nuclear clusters or infinite chain subunits are formed: tetra-, tri- and penta-nuclear clusters in 1, 3 and 4 and an infinite chain in 2.
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Benzene absorption in a protuberant-grid-type zinc(II)-organic framework triggered by the migration of guest water molecules

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,62-65
DOI: 10.1039/C4DT02169J, CommunicationTien-Wen Tseng, Tzuoo-Tsair Luo, Chang-Hsiu Tsai, Chun-Chi Chen, Gene-Hsiang Lee, Chih-Chieh Wang, Kuang-Lieh Lu
Benzene molecules are reported to be easily and regularly absorbed into specific channels in a 2D protuberant-grid-type Zn(II)-organic framework, which consists of racemic interdigitated bilayers.
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Antimony(III) and bismuth(III) amides containing pendant N-donor groups - a combined experimental and theoretical study

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,395-400
DOI: 10.1039/C4DT02692F, PaperIva Vranova, Roman Jambor, Ales Ruzicka, Alexander Hoffmann, Sonja Herres-Pawlis, Libor Dostal
The synthesis and structural study dealing with antimony(III) and bismuth(III) amides, derivatives of a pyrrole core, with pendant nitrogen functionalities is presented.
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Dinuclear nickel(II) complexes with 2,5-diamino-1,4-benzoquinonediimine ligands as precatalysts for the polymerization of styrene: electronic and steric substituent effects

8 December, 2014 - 07:54

Dalton Trans., 2015, 44,368-376
DOI: 10.1039/C4DT02858A, PaperKeiji Ohno, Akira Nagasawa, Takashi Fujihara
Substituent effects of the electron-donating ability and bulkiness of R in [{Ni(acac)}2([small mu ]-RAp)] (RApH2: azophenines) on properties and catalytic activity are reported.
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