Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 1 day 1 hour ago

Structural and electronic characterization of multi-electron reduced naphthalene (BIAN) cobaloximes

18 July, 2015 - 17:17

Dalton Trans., 2015, 44,13017-13029
DOI: 10.1039/C5DT00924C, PaperOwen M. Williams, Alan H. Cowley, Michael J. Rose
Synthesis, spectroscopy and DFT studies on cobian-oximes provide insight to multi-electron processes in electrocatalytic processes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses, structure solutions, and catalytic performance of two novel layered silicates

16 July, 2015 - 16:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00487J, PaperJie Liang, Jie Su, Yanping Chen, Zhaofei Li, Kuo Li, Hao Zhang, Xiaodong Zou, Fuhui Liao, Yingxia Wang, Jianhua Lin
Two novel layered silicates, PKU-13 and PKU-13a, were hydrothermally synthesized by using trimethylpropylammonium hydroxide as the structure directing agent (SDA). Their structures were solved by powder X-ray diffraction data in...
The content of this RSS Feed (c) The Royal Society of Chemistry

Gold nanoparticles decorated graphene sheet-polypyrrole based nanocomposite: Synthesis, characterization and genosensing application

16 July, 2015 - 16:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01193K, PaperIda Tiwari, Mandakini Gupta, Chandra Mouli Pandey, Vandini Mishra
We herein report the synthesis of gold nanoparticles (GNPs) decorated-graphene sheets (GO-GNPs) with the template of graphene oxide (GO) by a one-pot solution-based method. Polypyrrole-GO decorated GNPs nanocomposite (GO-GNPs/PPY) has...
The content of this RSS Feed (c) The Royal Society of Chemistry

Kinetico-mechanistic studies on the formation of seven-membered [C,N]-platinacycles: the effect of methyl or fluoro substituents on the aryl ancillary ligands

12 July, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT01926E, PaperMargarita Crespo, Merce Font-Bardia, Manuel Martinez
The rate determining step for the formation of seven-membered platinacycles from cyclometallated Pt(IV) aryl complexes is determined by the nature of the substituents on the aryl groups.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A (pentafluoroethyl)(trifluoromethyl)carbene complex of iridium and reductive activation of its sp3 [small alpha], [small beta], and [gamma] carbon-fluorine bonds to give perfluoro-2-butyne, perfluoro-1,2,3-butatriene and perfluoro-1-irida-2-methyl-2-cycl

12 July, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02075A, PaperJian Yuan, Russell P. Hughes, Arnold L. Rheingold
Inner-sphere reduction of a (pentafluoroethyl)(trifluoromethyl)carbene ligand affords perfluorobutyne, perfluorobutatriene and perfluorometallacyclobutene ligands.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

P-Trifluoromethyl ligands derived from Josiphos in the Ir-catalysed hydrogenation of 3,4-dihydroisoquinoline hydrochlorides

12 July, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02019K, PaperR. Schwenk, A. Togni
Ferrocenyl phosphines containing a stereogenic P-CF3 group show improved selectivities in the Ir-catalysed hydrogenation of dihydroisoquinolinium derivatives.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)

12 July, 2015 - 15:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT02020D, CommunicationAurelia Falcicchio, Sten O. Nilsson Lill, Filippo M. Perna, Antonio Salomone, Donato I. Coppi, Corrado Cuocci, Dietmar Stalke, Vito Capriati
A multitude of non-covalent interactions, investigated by X-ray crystallography and computational chemistry techniques, proved to be responsible of the spontaneous self-assembly of a bis(trifluoroborate) dipotassium salt.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Correction: Facile synthesis of phosphine free ultra-small PbSe nanocrystals and their light harvesting studies in ETA solar cells

12 July, 2015 - 15:54
Dalton Trans., 2015, 44,12884-12884
DOI: 10.1039/C5DT90119G, CorrectionOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Javeed Akhtar, Mateusz Banski, Mohammad Azad Malik, Neerish Revaprasadu, Artur Podhorodecki, Jan Misiewicz
The content of this RSS Feed (c) The Royal Society of Chemistry

A giant magnetocaloric effect with a tunable temperature transition close to room temperature in Na-deficient La0.8Na0.2-x[square]xMnO3 manganites

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12796-12803
DOI: 10.1039/C5DT01254F, PaperM. Wali, R. Skini, M. Khlifi, E. Dhahri, E. K. Hlil
A giant magnetocaloric effect induced by sodium-deficiency in a La0.8Na0.2-x[square]xMnO3 (0.00 [less-than-or-equal] x [less-than-or-equal] 0.15) polycrystalline sample is reported in the present research work.
The content of this RSS Feed (c) The Royal Society of Chemistry

Solvent-free heterogeneous catalysis for cyanosilylation in a dynamic cobalt-MOF

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12711-12716
DOI: 10.1039/C5DT01456E, PaperXin Cui, Mei-Chen Xu, Ling-Juan Zhang, Ru-Xin Yao, Xian-Ming Zhang
The terminal coordinated water molecule has been successfully removed in a butterfly-like cobalt cluster based 3D frameworks by SCSC transformation, which can efficiently heterogeneous catalyze cyanosilylation of aldehydes and exhibit size-selectivity effect under solvent-free conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Distribution of Al atoms in the clathrate-I phase Ba8AlxSi46-x at x = 6.9

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12680-12687
DOI: 10.1039/C5DT01198A, PaperMatej Bobnar, Bodo Bohme, Michael Wedel, Ulrich Burkhardt, Alim Ormeci, Yurii Prots, Christina Drathen, Ying Liang, Hong Duong Nguyen, Michael Baitinger, Yuri Grin
The distribution of Al and Si atoms in Ba8Al6.9Si39.1 was elucidated by combining the results of NMR, X-ray diffraction and chemical analysis.
The content of this RSS Feed (c) The Royal Society of Chemistry

Alkynyl functionalized Al/P-based frustrated Lewis pairs - aluminium alkynide elimination and evidence for the formation of 3H-phosphaallenes [R-P[double bond, length as m-dash]C[double bond, length as m-dash]C(H)-tBu]

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12670-12679
DOI: 10.1039/C5DT01607J, PaperHans Klocker, Steffi Roters, Alexander Hepp, Werner Uhl
Hydroalumination of dialkynylphosphines by H-Al[CH(SiMe3)2]2 afforded alkenyl-alkynyl phosphines which eliminate dialkylaluminium alkynides spontaneously to form phosphaallenes, aryl-P[double bond, length as m-dash]C[double bond, length as m-dash]C(H)-tBu.
The content of this RSS Feed (c) The Royal Society of Chemistry

Bis([sigma]-B-H) complexes of copper(I): precursors to a heterogeneous amine-borane dehydrogenation catalyst

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12530-12534
DOI: 10.1039/C5DT02144H, CommunicationAdi E. Nako, Andrew J. P. White, Mark R. Crimmin
A series of bis([sigma]-B-H) complexes of copper(I) have been prepared by displacement of arene solvent from a [small beta]-diketiminate copper(I) complex by four-coordinate boranes, H3B-L (L = NMe3, lutidine).
The content of this RSS Feed (c) The Royal Society of Chemistry

MOF crystal growth: UV resonance Raman investigation of metal-ligand binding in solution and accelerated crystal growth methods

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12824-12831
DOI: 10.1039/C5DT01588J, PaperThomas D. Petersen, Gurusamy Balakrishnan, Colin L. Weeks
Resonance Raman spectroscopy can detect metal-ligand binding in solution during the formation of MOF crystals.
The content of this RSS Feed (c) The Royal Society of Chemistry

Is bond stretch isomerism in mononuclear transition metal complexes a real issue? The misleading case of the MoCl5/tetrahydropyran reaction system

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12653-12659
DOI: 10.1039/C5DT01378J, PaperFrancesco Paolo Di Nicola, Massimiliano Lanzi, Fabio Marchetti, Guido Pampaloni, Stefano Zacchini
The MoCl5/tetrahydropyran reaction system provides an opportunity for discussing the possible generation of bond stretch isomers.
The content of this RSS Feed (c) The Royal Society of Chemistry

Double [3 + 2]-dimerisation cascade synthesis of bis(triazolyl)bisphosphanes, a new scaffold for bidentate bisphosphanes

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12539-12545
DOI: 10.1039/C5DT02197A, CommunicationCoralie Laborde, Muh-Mei Wei, Arie van der Lee, Eric Deydier, Jean-Claude Daran, Jean-Noel Volle, Rinaldo Poli, Jean-Luc Pirat, Eric Manoury, David Virieux
Highly convergent synthesis of bis(triazolylphosphane oxides) by a tandem copper-mediated Huisgen reaction-oxidative coupling.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dimer formation upon deprotonation: synthesis and structure of a m-terphenyl substituted (R,S)-dilithium disiloxanolate disilanol

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12818-12823
DOI: 10.1039/C5DT01992C, PaperDaniel Cas, Natascha Hurkes, Stefan Spirk, Ferdinand Belaj, Clemens Bruhn, Gerald N. Rechberger, Rudolf Pietschnig
The primary products in deprotonating m-terphenylsilanetriol were detected in traces besides disiloxanes as major products, which were characterized as donor adducts.
The content of this RSS Feed (c) The Royal Society of Chemistry

Gallium fluoroarsenates

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12804-12811
DOI: 10.1039/C5DT01094B, PaperKayleigh L. Marshall, Jennifer A. Armstrong, Mark T. Weller
Gallium fluoroarsenates, templated with simple metal or complex organic cations, form structures derived from octahedrally coordinated gallium and AsO4 tetrahedra, and displaying various polyhedra-linking dimensionalities.
The content of this RSS Feed (c) The Royal Society of Chemistry

Thermodynamics of technetium: reconciling theory and experiment using density functional perturbation analysis

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12735-12742
DOI: 10.1039/C5DT01639H, PaperPhilippe F. Weck, Eunja Kim
The structure, lattice dynamics and thermodynamic properties of bulk technetium were investigated within the framework of density functional theory. The predicted thermal expansion and isobaric heat capacity are in excellent agreement with available experimental data.
The content of this RSS Feed (c) The Royal Society of Chemistry

Nickel(II) radical complexes of thiosemicarbazone ligands appended by salicylidene, aminophenol and aminothiophenol moieties

12 July, 2015 - 15:54

Dalton Trans., 2015, 44,12743-12756
DOI: 10.1039/C5DT00944H, PaperAmelie Kochem, Gisele Gellon, Olivier Jarjayes, Christian Philouze, Amaury du Moulinet d'Hardemare, Maurice van Gastel, Fabrice Thomas
The neutral nickel(II) complexes are chameleon pro-radical compounds: under their one-electron oxidized form they feature an iminosemiquinonate (or iminothiosemiquinonate) radical, while under their reduced form they are [small alpha]-diimine [small pi]-radicals.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2015 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.