Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 16 hours 41 min ago

The kinetics and mechanism of photo-assisted Ag(I)-catalysed water oxidation with S2O82-

16 November, 2014 - 02:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02254H, PaperLihong Yu, Jidan Wang, Dan Guo, Wansheng You, Meiying Liu, Lancui Zhang, Can Li
It is reported that visible light ([small lambda] [greater-than-or-equal] 400 nm) can improve Ag(I)-catalyzed water oxidation into O2 with S2O82- remarkably. The photo-assistant results from the absorbance of the AgO+ species at 375 nm, promoting the rate-determining step (AgO+ + H2O [rightward arrow] Ag+ + H2O2). A reasonable mechanism has been proposed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, crystal structures and two-photon absorption properties of triphenylamine cyanoacetic acid derivative and its organooxotin complexes

16 November, 2014 - 02:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02251C, PaperXuesong Zhao, Jie Liu, Hui Wang, Yan Zou, Shengli Li, Shengyi Zhang, Hongping Zhou, Jieying Wu, Yupeng Tian
Three novel organooxotin complexes (Z1, Z2 and Z3) exhibit large 2PA cross-section per molecular weight and can be used as potential anti-tumor agents.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Lone pair-[small pi] interaction-induced generation of non-interpenetrated and photochromic cuboid 3-D naphthalene diimide coordination networks

16 November, 2014 - 02:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03124E, PaperJian-Jun Liu, Yu-Jian Hong, Ying-Fang Guan, Mei-Jin Lin, Chang-Cang Huang, Wen-Xin Dai
By imposing the lone pair-[small pi] interactions through the addition of lone-pair-bearing molecules, the interpenetration in cuboid 3-D naphthalene diimide coordination networks was prevented and their photochromism was enhanced.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses, structures and properties of two new organic-inorganic hybrid materials based on [varepsilon]-Zn Keggin units {[varepsilon]-PMoV8MoVI4O40-x(OH)xZn4}

16 November, 2014 - 02:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02993C, PaperHao Miao, Gonghao Hu, Jiuyu Guo, Hongxiang Wan, Hua Mei, Yu Zhang, Yan Xu
Two novel hybrids [varepsilon](pyim)2 and [varepsilon]2(pyim)6, based on [varepsilon]-Zn Keggin units, have been synthesized under hydrothermal conditions by controlling pH values.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Benzene absorption in a protuberant-grid-type zinc(II)-organic framework triggered by the migration of guest water molecules

16 November, 2014 - 02:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02169J, CommunicationTien-Wen Tseng, Tzuoo-Tsair Luo, Chang-Hsiu Tsai, Chun-Chi Chen, Gene-Hsiang Lee, Chih-Chieh Wang, Kuang-Lieh Lu
Benzene molecules are reported to be easily and regularly absorbed into specific channels in a 2D protuberant-grid-type Zn(II)-organic framework, which consists of racemic interdigitated bilayers.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Chemistry of group 9 dimetallaborane analogues of octaborane(12)

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03027C, PaperSubrat Kumar Barik, Dipak Kumar Roy, Sundargopal Ghosh
Reaction of octaborane(12) analogue with metal carbonyl compounds yielded condensed metallaborane (A) and boride cluster (B).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Catalytic oxygenation of sp3 "C-H" bonds with Ir(III) complexes of chelating triazoles and mesoionic carbenes

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02879A, PaperStephan Hohloch, Selina Kaiser, Fenja Leena Duecker, Aljosa Bolje, Ramananda Maity, Janez Kosmrlj, Biprajit Sarkar
Ir(III) complexes with chelating triazole and mesoionic carbene ligands are potent pre-catalysts for the direct oxygenation of C-H bonds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Antimony(III) and bismuth(III) amides containing pendant N-donor groups - a combined experimental and theoretical study

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02692F, PaperIva Vranova, Roman Jambor, Ales Ruzicka, Alexander Hoffmann, Sonja Herres-Pawlis, Libor Dostal
The synthesis and structural study dealing with antimony(III) and bismuth(III) amides, derivatives of a pyrrole core, with pendant nitrogen functionalities is presented.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Main group catalysed reduction of unsaturated bonds

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02024C, PerspectiveK. Revunova, G. I. Nikonov
This Perspective article reviews the recent developments in reduction reactions catalysed by main-group element compounds.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Encapsulation and stabilization of polyoxometalates in self-assembled supramolecular hydrogels

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT01372G, CommunicationVamangi M. Pandya, Ulrich Kortz, Sachin A. Joshi
Polyoxometalate assisted pH dependent self-assembled hydrogel formation.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dinuclear nickel(II) complexes with 2,5-diamino-1,4-benzoquinonediimine ligands as precatalysts for the polymerization of styrene: electronic and steric substituent effects

14 November, 2014 - 01:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02858A, PaperKeiji Ohno, Akira Nagasawa, Takashi Fujihara
Substituent effects of the electron-donating ability and bulkiness of R in [{Ni(acac)}2([small mu ]-RAp)] (RApH2: azophenines) on properties and catalytic activity are reported.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02585G, PaperClement Camp, Oliver Cooper, Julie Andrez, Jacques PECAUT, M Mazzanti
Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid...
The content of this RSS Feed (c) The Royal Society of Chemistry

Abnormal luminescent property of Mn2+ in [small alpha]-LiZnBO3:Mn2+

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02626H, PaperHongrun Wang, Li Wu, Huan Yi, Biao Wang, Liwei Wu, Yuelong Gu, Yi Zhang
Mn2+-activated red phosphor [small alpha]-LiZnBO3:Mn2+ was synthesized by solid state reaction. ESR spectra prove that the doped ions are Mn2+. The doped Mn2+ ion is inclined to occupy Zn2+ site which...
The content of this RSS Feed (c) The Royal Society of Chemistry

Small Molecular Amine Mediated Synthesis of Hydrophilic CdS Nanorods and their Photoelectrochemical Water Splitting Performance

14 November, 2014 - 01:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02671C, PaperChunlin Bao, Guo Xing Zhu, Jing Yang, Miaomiao Liu, Rongxian Zhang, Xiao Ping Shen
Photoelectrochemical (PEC) water splitting is a promising route for solar energy harvesting and storage, but it has been highly limited by the performance of the semiconductor photoelectrodes. Herein, we report...
The content of this RSS Feed (c) The Royal Society of Chemistry

Multi-step mechanism and integrity of titanate nanoribbons

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02573C, PaperVanessa Bellat, Remi CHASSAGNON, Olivier HEINTZ, Lucien SAVIOT, David VANDROUX, Nadine Millot
A one-step hydrothermal treatment of TiO2 powders in strongly basic conditions has been used to synthesize titanate nanoribbons. The nanoparticles were thoroughly characterized using several methods including transmission electron microscopy...
The content of this RSS Feed (c) The Royal Society of Chemistry

Two types of lanthanide selenidostannates(IV) first prepared under same solvothermal conditions

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03099K, PaperJian Zhou, Hong Xiao, Hong-Ping Xiao, Tao Yang, Hua-Hong Zou, Xing Liu, Rongqing Zhao, Qiuling Tang
Two types of lanthanide selenidostannates(IV) [Ln2(tepa)2([small mu ]-OH)2Sn2Se6] {Ln = Y(Ia), Pr (Ib), Dy (Ic), Er (Id), Tm(Ie); tepa = tetraethylenepentamine} and [Ln2(tepa)2([small mu ]2-OH)2Cl2]2[Sn4Se10][round bullet, filled]4H2O {Ln = Y (IIa), Dy (IIb), Er (IIc), Tm(IId)}...
The content of this RSS Feed (c) The Royal Society of Chemistry

Series of open-framework aluminoborates containing B5O10 clusters

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02632B, PaperGuo-Yu Yang, Li Wei, Guo-Ming Wang, Huan He, Bai-Feng Yang
Three new open-framework aluminoborates (ABOs), Rb2AlB5O10[round bullet, filled]4H2O (1), [C5N2H16]AlB5O10 (2, C5N2H16 = N-ethyl-1,3-diaminopropane) and [H2dap][(CH3)2NH]AlB5O10 (3, dap = 1,2-diaminopropane) have been made under solvothermal conditions and characterized by elemental analysis, IR,...
The content of this RSS Feed (c) The Royal Society of Chemistry

A strategy to improve the energy conversion efficiency and stability of quantum dot-sensitized solar cells using manganese-doped cadmium sulfide quantum dots

12 November, 2014 - 01:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03063J, PaperChandu V. V. M. Gopi, M. Venkata-Haritha, Soo-Kyoung Kim, Hee-Je Kim
Better stability and higher performance of Mn-doped CdS QDSSCs (PCE = 2.85%) than those of CdS QDSSCs (PCE = 2.11%).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

In situ tetrazole templated chair-like decanuclear azido-cobalt(II) SMM containing both tetra- and octa-hedral Co(II) ions

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03211J, CommunicationYuan-Zhu Zhang, Song Gao, Osamu Sato
An azido-bridged chair-like decanuclear cluster: [CoII10(bzp)8(Metz)2(N3)18].4MeOH.2H2O (1, bzp = 2-benzoylpyridine and HMetz = 5-methyl-1H-tetrazole) was prepared with in situ tetrazolate anions as templates in a sealed system. 1 containing both...
The content of this RSS Feed (c) The Royal Society of Chemistry

The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes

12 November, 2014 - 01:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02773F, CommunicationBenjamin William John Harper, Janice Rae Aldrich-Wright
Dinuclear (2,2':6',2''-terpyridine)platinum(II) (PtTerpy) complexes were synthesised by tethering either thiol or pyridine based linkers. All intermediates and resulting complexes were characterised using a combination of 1H and 195Pt NMR, two-dimensional...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.