Dalton Transactions

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Sustainable synthetic route for [gamma]-Fe2O3/C hybrid as anode material for lithium-ion batteries

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2150-2156
DOI: 10.1039/C4DT03278K, PaperFurong Qin, Kai Zhang, Liyuan Zhang, Jie Li, Hai Lu, Yanqing Lai, Zhian Zhang, Yaming Zhou, Yiwei Li, Jing Fang
A sustainable synthesis has been developed for [gamma]-Fe2O3/C hybrid, which showed superior electrochemical performance as an anode material for lithium-ion batteries.
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Exploring the effect of axial ligand substitution (X = Br, NCS, CN) on the photodecomposition and electrochemical activity of [MnX(N-C)(CO)3] complexes

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2122-2131
DOI: 10.1039/C4DT03079F, PaperJay Agarwal, Charles J. Stanton III, Travis W. Shaw, Jonathon E. Vandezande, George F. Majetich, Andrew B. Bocarsly, Henry F. Schaefer III
Four new Mn(I)-NHC compounds are tested for light stability and catalytic efficiency for reducing CO2 to CO.
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Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(II) complexes

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2110-2121
DOI: 10.1039/C4DT03508A, PaperSalah S. Massoud, Mark Spell, Catherine C. Ledet, Thomas Junk, Radovan Herchel, Roland C. Fischer, Zdenek Travnicek, Franz A. Mautner
Five new dinuclear bridged-phenoxido dichlorido-metal(II) complexes [M2([small mu ]-LClO)(X)2Cl2]PF6/ClO4 complexes, where M(II) = Co, Ni, Cu (1-4) and Zn (5); X = CH3OH, H2O or 0 were synthesized and structurally characterized. Complexes 1-4 revealed weak to moderate antiferromagnetic coupling.
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Anion complexation, transport and structural studies of a series of bis-methylurea compounds

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2138-2149
DOI: 10.1039/C4DT02893G, PaperMartina Olivari, Riccardo Montis, Louise E. Karagiannidis, Peter N. Horton, Lucy K. Mapp, Simon J. Coles, Mark E. Light, Philip A. Gale, Claudia Caltagirone
A new family of bis-methylureas have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane have been studied.
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Manganese-calcium clusters supported by calixarenes

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2132-2137
DOI: 10.1039/C4DT02952F, PaperRebecca O. Fuller, George A. Koutsantonis, Ivan Lozic, Mark I. Ogden, Brian W. Skelton
An investigation inspired by the structure of the oxygen-evolving complex of photosystem II has resulted in the isolation and structural characterization of the first examples of Mn/Ca clusters supported by a calixarene ligand.
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New heteroleptic magnesium complexes for MgO thin film application

21 January, 2015 - 20:17

Dalton Trans., 2015, 44,2103-2109
DOI: 10.1039/C4DT03497J, PaperHyo-Suk Kim, Sheby Mary George, Bo Keun Park, Seung Uk Son, Chang Gyoun Kim, Taek-Mo Chung
Novel magnesium precursors for the ALD/CVD process of MgO thin films were synthesized as heteroleptic complexes. These complexes show high volatility and good thermal properties which proved to be superior to homoleptic parent complexes.
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Organometallic Chemistry of Ethynyl Boronic Acid MIDA Ester, HC[identical with]CB(O2CCH2)2NMe.

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03695F, PaperAnthony Hill, Craig D Stewart, Jas Stuart Ward
The reactions of HC[identical with]CBMIDA (BMIDA = B(O2CCH2)2NMe) with a range of ruthenium complexes afford the first isolated examples of [sigma]-alkynyl, [sigma]-alkenyl and vinylidene complexes bearing 4-coordinate boron substituents. Specifically, the...
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Employment of Triketone to Construct Dysprosium(III) Single-Molecule Magnet

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03494E, PaperChao Wang, Shuang-Yan Lin, Jianfeng Wu, Sen-Wen Yuan, Jinkui Tang
The initial employment of triketone ligand in 4f coordination chemistry afforded a series of isomorphic dinuclear complexes. The magnetic studies revealed that antiferromagnetic interaction exists in digadolinium(III) compound, while the...
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Color-tunable and white-light emission of one-dimensional L-di-2-thenoyltartaric acid mixed-lanthanide coordination polymers

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03457K, PaperChang Feng, Jingwen Sun, Pengfei Yan, Yuxin Li, Tianqi Liu, Qingyan Sun, Guangming Li
Abstract: A series of L-di-2-thenoyltartaric acid lanthanide coordination polymers, namely, {[La2L3(CH3OH)6(H2O)][round bullet, filled]CH3OH[round bullet, filled]H2O}n (1), {[Ln2L3(CH3OH)x(H2O)6-x][round bullet, filled]aCH3OH[round bullet, filled]bH2O}n, [Ln = Eu (2), x = 2, a = 0.5, b = 0.25; Ln = Gd (3),...
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Relationship between strength of hydrogen bonding and spin crossover behaviour in a series of iron(III) Schiff base complexes

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03400G, PaperIvan Nemec, Radovan Herchel, Zdenek Travnicek
X-ray crystal structures and magnetic properties of an isostructural series of iron(III) Schiff base complexes with the general formula [Fe(L5)(NCR)][round bullet, filled]Solv (where H2L5 = N,N'-bis(2-hydroxy-naphthylidene)-1,6-diamino-4-azahexane, R = S, Solv = tetrahydrofuran,...
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Gas sensing and electrochemical properties of tetra and octa 2H-chromen-2-one substituted iron(II) phthalocyanines

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03301A, Paperzafer Odabas, Selcuk Altun, Efe Baturhan Orman, Ahmet Alt[i without dot]ndal, Ali Riza Ozkaya
The synthesis of novel alpha tetra, beta tetra and beta octa 4-(4-methoxyphenyl)-8-methyl-coumarin-7-oxy, and beta octa 4-chloro-5-(4-(4-methoxyphenyl)-8-methylcoumarin-7-oxy substituted iron(II) phthalocyanines has been achieved by the reaction of corresponding phthalonitriles with iron(II)acetate....
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Homodinuclear Lanthanide {Ln2} (Ln = Gd, Tb, Dy, Eu) Complexes Prepared from a o-Vanillin based Ligand: Luminescence and Single-Molecule Magnetism Behavior

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03429E, PaperVadapalli Chandrasekhar, Prasenjit Bag, Sivakumar Sri, Chandresh Kumar Rastogi, Valeriu Mereacre, Sourav Biswas
Four dinuclear lanthanide complexes [Gd2 (H2L)2 ([small micro]-piv)2 (piv)2][round bullet, filled]2CHCl3 (1), [Tb2 (H2L)2 ([small micro]-piv)2 (piv)2][round bullet, filled]2CHCl3 (2), [Dy2 (H2L)2 ([small micro]-piv)2 (piv)2][round bullet, filled]2CHCl3 (3) and [Eu2 (H2L)2 ([small micro]-piv)2 (piv)2][round bullet, filled]2CHCl3 (4) were synthesized by the reaction...
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Two series of reactants' ratio-dependent lanthanide organic frameworks derived from nicotinic acid N-oxide and oxalate: Synthesis, crystal structures and luminescence properties

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03668A, PaperYanyan Yu, Lijuan Zhang, Yunshan Zhou, Zareen Zuhra
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Activation of the manganese(I) tricarbonyl core by selective variation of bidentate ligands (L,L[prime or minute]-Bid = N,N[prime or minute] and N,O donor atom sets) in fac-[Mn(CO)3(L,L[prime or minute]-Bid)(CH3OH)]n complexes

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03524K, PaperT. N. Twala, M. Schutte-Smith, A. Roodt, H. G. Visser
A range of fac-[Mn(CO)3(L,L[prime or minute]-Bid)(H2O)]n complexes has been synthesized and the methanol substitution has been investigated for the first time.
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Highly selective colorimetric sensing of Hg(II) ions in aqueous medium and in the solid state via formation of a novel M-C bond

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03289F, PaperC. Parthiban, R. Manivannan, Kuppanagounder P. Elango
For the first time an easy-to-make receptor 2-chloro-3-(thiazol-2-ylamino)naphthalene-1,4-dione (R1) for highly selective sensing of Hg(II) ions in aqueous solution and in the solid state through the formation of an Hg-C bond was developed.
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Structural and magnetic properties of the ruthenium double perovskites Ba2-xSrxYRuO6

19 January, 2015 - 19:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03682D, PaperBen Ranjbar, Adriano Pavan, Brendan Kennedy, Zhaoming Zhang
The crystal structures of the series of ordered double perovskites Ba2-xSrxYRuO6 (0 [less-than-or-equal] x [less-than-or-equal] 2) were studied by high resolution synchrotron X-ray diffraction. The materials displayed a sequence of...
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Theoretical studies on the AnO2n+ (An = U, Np; n = 1, 2) complexes with di-(2-ethylhexyl)phosphoric acid

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03321C, PaperJuan Luo, Cong-Zhi Wang, Jian-Hui Lan, Qun-Yan Wu, Yu-Liang Zhao, Zhi-Fang Chai, Chang-Ming Nie, Wei-Qun Shi
The AnO2n+ (An = U, Np; n = 1, 2) extraction complexes with HDEHP (di-(2-ethylhexyl)phosphoric acid) in nitric acid solutions.
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Synthesis and characterization of substituted Schiff-base ligands and their d10 metal complexes: structure-induced luminescence tuning behaviors and applications in co-sensitized solar cells

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03602F, PaperYu-Wei Dong, Rui-Qing Fan, Ping Wang, Li-Guo Wei, Xin-Ming Wang, Hui-Jie Zhang, Song Gao, Yu-Lin Yang, Yu-Lei Wang
The structure-induced luminescence tuning behaviors of Schiff-base ligand based d10 metal complexes and their applications in co-sensitized solar cells.
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The peculiar behavior of Picha in the formation of metallacrown complexes with Cu(II), Ni(II) and Zn(II) in aqueous solution

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03264K, PaperLuciano Marchio, Nicola Marchetti, Corrado Atzeri, Valentina Borghesani, Maurizio Remelli, Matteo Tegoni
The thermodynamic stability of copper, nickel and zinc metallacrown complexes with picolinehydroxamic acid in aqueous solution has been rationalized.
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Luminescent Pt(II) complexes bearing dual isoquinolinyl pyrazolates: fundamentals and applications

19 January, 2015 - 19:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03028A, PaperHsiao-Yun Ku, Bihai Tong, Yun Chi, Hao-Che Kao, Chia-Chi Yeh, Chih-Hao Chang, Gene-Hsiang Lee
Pt(II) complex [Pt(Lx)2], LxH = 6-t-butyl-1-(3-trifluoromethyl-1H-pyrazol-5-yl) isoquinoline, with three colored morphologies can be interconverted by grinding and/or wetting with solvents.
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