Dalton Transactions

Syndicate content RSC - Dalton Trans. latest articles
RSC - Dalton Trans. latest articles
Updated: 1 day 1 hour ago

Syntheses, crystal structures, and optical properties of five metal complexes constructed from a V-shaped thiophene-containing ligand and different dicarboxylate ligands

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13250-13258
DOI: 10.1039/C4DT01400F, PaperZhi-Qiang Shi, Zi-Jian Guo, He-Gen Zheng
Five new metal complexes constructed from the V-shaped ligand 2,8-di(1H-imidazol-1-yl)dibenzothiophene (DIDP) and different aromatic dicarboxylic acids have been synthesized and structurally characterized in detail. All these complexes show optical semiconductive properties.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structure and luminescence properties of new chloro-germanate phosphors Ca3GeO4Cl2:Eu2+

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13370-13376
DOI: 10.1039/C4DT01306A, PaperXue Chen, Zhiguo Xia, Quanlin Liu
The crystal structure and luminescence properties of blue-emitting chloro-germanate phosphors Ca3GeO4Cl2:Eu2+ are discussed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ruthenium sensitizers having an ortho-dicarboxyl group as an anchoring unit for dye-sensitized solar cells: synthesis, photo- and electrochemical properties, and adsorption behavior to the TiO2 surface

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13208-13218
DOI: 10.1039/C4DT01450B, PaperHironobu Ozawa, Kei Fukushima, Takahito Sugiura, Ayako Urayama, Hironori Arakawa
A novel ruthenium sensitizer with a 3[prime or minute],4[prime or minute]-dicarboxyterpyridine (TUS-28) has been synthesized as an improved model sensitizer of the dye-sensitized solar cells.
The content of this RSS Feed (c) The Royal Society of Chemistry

Triptycene based organometallic complexes: a new class of acceptor synthons for supramolecular ensembles

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13270-13277
DOI: 10.1039/C4DT01298D, PaperSourav Chakraborty, Snehasish Mondal, Sourav Bhowmick, Jianqiu Ma, Hongwei Tan, Subhadip Neogi, Neeladri Das
New triptycene based organometallic complexes have been synthesized and subsequently used for design of the triptycene motif containing nanoscalar trigonal prisms. Flexible 3,3[prime or minute]-bipyridine is employed as a donor unit.
The content of this RSS Feed (c) The Royal Society of Chemistry

Isomeric chain structures of {[Mn(H2O)4]2Ru2(CO3)4Br2}nn-: syntheses, structural diversity and magnetic properties

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13316-13324
DOI: 10.1039/C4DT01522C, PaperXiao-Feng Hou, Yan-Yan Jia, Jian-Hui Yang, Zhi Cao, Bin Liu
Isomeric (twisted and zigzag) double-chain {[Mn(H2O)4]2Ru2(CO3)4Br2}nn- complexes show two-step magnetic ordering (5.0 K and 2.6 K) and metamagnetic behavior (1.2 kOe).
The content of this RSS Feed (c) The Royal Society of Chemistry

Imatinib intermediate as a two in one dual channel sensor for the recognition of Cu2+ and I- ions in aqueous media and its practical applications

19 August, 2014 - 05:17

Dalton Trans., 2014, 43,13299-13306
DOI: 10.1039/C4DT01516A, PaperSamadhan R. Patil, Jitendra P. Nandre, Devising Jadhav, Shilpa Bothra, S. K. Sahoo, Manisha Devi, Chullikkattil P. Pradeep, Pramod P. Mahulikar, Umesh D. Patil
An imatinib intermediate was developed for the colorimetric sensing of Cu2+ ions in aqueous solution.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, characterization and reactivity studies of electrophilic ruthenium(II) complexes: a study of H2 activation and labilization

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13410-13423
DOI: 10.1039/C4DT00295D, PaperK. S. Naidu, Yogesh P. Patil, Munirathinam Nethaji, Balaji R. Jagirdar
Synthesis of some new highly electrophilic ruthenium complexes bearing the 1,2-bis(dipentafluorophenyl phosphino)ethane ligand and their reactivity studies towards activation and labilization of molecular hydrogen are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

New insights into the chemistry of di- and trimetallic iron dithiolene derivatives. Structural, Mossbauer, magnetic, electrochemical and theoretical studies

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13187-13195
DOI: 10.1039/C4DT01462F, PaperSonia Bruna, Isabel Cuadrado, Esther Delgado, Carlos J. Gomez-Garcia, Diego Hernandez, Elisa Hernandez, Rosa Llusar, Avelino Martin, Nieves Menendez, Victor Polo, Felix Zamora
The synthesis of two new iron dithiolene derivatives and the study of their physical properties are described.
The content of this RSS Feed (c) The Royal Society of Chemistry

Self-assembly and modified luminescence properties of NaY(MoO4)2:Tb3+, Eu3+ inverse opals

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13293-13298
DOI: 10.1039/C4DT01792G, PaperShaobo Cui, Yongsheng Zhu, Wen Xu, Pingwei Zhou, Lei Xia, Xu Chen, Hongwei Song, Wei Han
Three-dimensional (3D) inverse opal photonic crystals can not only modulate the emissions of the inserted emitters, they also have the advantage of a large surface to volume ratio, the concentration quenching and energy transfer process can be greatly suppressed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Pd-Ni alloy nanoparticle doped mesoporous SiO2 film: the sacrificial role of Ni to resist Pd-oxidation in the C-C coupling reaction

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13325-13332
DOI: 10.1039/C4DT01438C, PaperJony Saha, Koushik Bhowmik, Indranee Das, Goutam De
A Pd-Ni alloy nanoparticle doped mesoporous SiO2 film shows good catalytic activity for C-C coupling with recyclability because the Ni in Pd-Ni inhibits Pd-oxidation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Polymethyl methacrylate (PMMA)-bismuth ferrite (BFO) nanocomposite: low loss and high dielectric constant materials with perceptible magnetic properties

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13232-13241
DOI: 10.1039/C4DT00947A, PaperMohaseen S. Tamboli, Prakash K. Palei, Santosh S. Patil, Milind V. Kulkarni, Noormahmad N. Maldar, Bharat B. Kale
Formation mechanism of PMMA-BFO nanocomposites.
The content of this RSS Feed (c) The Royal Society of Chemistry

Induced circular dichroism of polyoxometalates via electrostatic encapsulation with chiral organic cations

17 August, 2014 - 04:54

Dalton Trans., 2014, 43,13178-13186
DOI: 10.1039/C4DT00866A, PaperYizhan Wang, Lei Shi, Yang Yang, Bao Li, Lixin Wu
The encapsulation of POMs with chiral organic cations via electrostatic interactions provides a facile and effective method for constructing optically pure POM-based materials.
The content of this RSS Feed (c) The Royal Society of Chemistry

Titanium and Zirconium Complexes of N,N'-Bis(2,6-diisopropylphenyl)-1,4-diaza-butadiene Ligand: Syntheses, Structures and Their use in Catalytic Hydrosilylation Reactions

15 August, 2014 - 04:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02013H, PaperTarun Kanti Panda, Srinivas Anga, Kishor Naktode, A Harinath
We report here a number of dianionic 1,4-diaza-1,3-butadiene complexes of titanium and zirconium by salt metathesis reaction. The reaction of either CpTiCl3 or Cp2TiCl2 with dilithium salt of N,N'-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene [1;...
The content of this RSS Feed (c) The Royal Society of Chemistry

trans-Platinum(II) complex of 3-aminoflavone - synthesis, X-ray crystal structure and biological activities in vitro

15 August, 2014 - 04:17

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01501K, PaperMalgorzata Fabijanska, Kazimierz Studzian, Leszek Szmigiero, Agnieszka J. Rybarczyk-Pirek, Arno Pfitzner, Barbara Cebula-Obrzut, Piotr Smolewski, Elzbieta Zyner, Justyn Ochocki
This paper describes the synthesis of trans-Pt(3-af)2Cl2 for use as a potential anticancer compound, and the evaluation of its structure by spectral analyses and X-ray crystallography.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Hunting the human DPP III active conformation: combined thermodynamic and QM/MM calculations

13 August, 2014 - 03:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02003K, PaperAntonija Tomic, Sanja Tomic
Multiple choices of the protein active conformations in flexible metalloenzymes complicate study of their catalytic mechanism. We used three different conformations of human dipeptidyl-peptidase III (DPP III) to investigate influence...
The content of this RSS Feed (c) The Royal Society of Chemistry

Two New Zinc(II) Coordination Complexes with Helix Characteristics Showing Both Interpenetration and Self-catenation Features: a Platform for Synthesis of Chiral and Catenated Structures Assembled by Length-Modulated Dicarboxylates

13 August, 2014 - 03:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01431F, PaperYue Wang, Yan Qi, Vladislav Blatov, jimin Zheng, Qun Li, Chao Zhang
Two new zinc coordination complexes, namely, [Zn2(tib)4/3(L1)2][round bullet, filled]DMA (1) and [Zn2(tib)4/3(L2)2][round bullet, filled]H2O (2) (tib = 1,3,5-tris(1-imidazolyl)benzene, H2L1 = biphenyl-4,4'-dicarboxylic acid, H2L2 = 4,4'-(2,2'-oxybis(ethane-2,1-diyl)bis(oxy))dibenzoic acid and DMA = N,N-dimethylacetamide) are obtained by using...
The content of this RSS Feed (c) The Royal Society of Chemistry

Two-photon sensitized visible and near-IR luminescence of lanthanide complexes using a fluorene-based donor-[small pi]-acceptor diketonate

13 August, 2014 - 03:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01507J, PaperAdam W. Woodward, Andrew Frazer, Alma R. Morales, Jin Yu, Anthony F. Moore, Andres D. Campiglia, Evgheni V. Jucov, Tatiana V. Timofeeva, Kevin D. Belfield
Lanthanide ion complexes were prepared with 2PA antenna ligands. Photophysical characterization suggest the strong potential of the new complexes as imaging probes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Thermal structural characterization of the acentric layered perovskite LiHSrTa2O7 : X-ray and neutron diffraction, SHG and Raman experiments

13 August, 2014 - 03:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01723D, Papermarie-pierre Crosnier-Lopez, Cyrille Galven, Denis Mounier, Thierry Pagnier, E. Suard, Francoise Le Berre
The present work concerns the thermal structural characterization of the acentric Ruddlesden-Popper LiHSrTa2O7. A previous study, performed with powder neutron diffraction data, has revealed that at room temperature, LiHSrTa2O7 crystallizes...
The content of this RSS Feed (c) The Royal Society of Chemistry

Switching and redox isomerism in first-row transition metal complexes containing redox active Schiff base ligands

13 August, 2014 - 03:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01699H, PaperAshok Sasmal, Eugenio Garribba, Carlos J. Gomez Garcia, Cedric Desplanches, Samiran Mitra
The reversible redox isomerisms in first row transition metals complexes of the type ML2 were studied. The six ML2 complexes (M = MnIII (1), FeII (2), CoIII (3) , NiII...
The content of this RSS Feed (c) The Royal Society of Chemistry

Na-doped Ni-Rich LiNi0.5Co0.2Mn0.3O2 cathode material with both high rate capability and high tap density for lithium ion batteries

13 August, 2014 - 03:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01611D, PaperWeibo Hua, Jibin Zhang, Zhuo Zheng, Wenyuan Liu, Xihao Peng, Xiao-Dong Guo, Benhe Zhong, Yan-Jie Wang, xinlong wang
Na-doped Ni-rich LiNi0.5Co0.2Mn0.3O2 cathode material, Li0.97Na0.03Ni0.5Co0.2Mn0.3O2, is synthesized by a hydroxide co-precipitation route. The structural characterization reveals that the substitution of Na for Li results in a more ordered [small alpha]-NaFeO2...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.