Dalton Transactions

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Tungsten carbonyl [sigma]-complexes with charge-compensated nido-carboranyl thioether ligands

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00176E, PaperSergey V. Timofeev, Olga Zhidkova, Elena Mosolova, Igor B. Sivaev, Ivan Godovikov, Kyrill Suponitsky, Zoya A. Starikova, Vladimir I Bregadze
Charge-compensated nido-carboranyl thioether ligands [7-MeS-10-Me2S-7,8-C2B9H10] and [7,8-(MeS)2-10-Me2S-7,8-C2B9H9] were prepared and fully characterized. They readily react with labile tungsten carbonyls to give [sigma]-complexes - mono-substituted (CO)5W[7-MeS-10-Me2S-7,8-C2B9H10-[small kappa]1-S(1)] and (CO)5W[7,8-(MeS)2-10-Me2S-7,8-C2B9H9-[small kappa]1-S(1)] and chelate (CO)4W[7,8-(MeS)2-10-Me2S-7,8-C2B9H9-[small kappa]2-S(1),S(2)]....
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Enhanced visible light photocatalytic activity of ZnIn2S4 modified by semiconductors

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00147A, PaperSai Yang, Li Li, Wenhui Yuan, Zilong Xia
To improve the visible light photocatalytic activity of ZnIn2S4 sample, we synthesized two kinds of coupled-photocatalysts: TiO2@ZnIn2S4 core-shell type heterostructure composites by a simple and flexible hydrothermal route using TiO2...
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Efficient uptake of dimethyl sulfoxide by desoxomolybdenum(IV) dithiolate complex containing bulky hydrophobic groups

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00075K, PaperYuki Hasenaka, Taka-aki Okamura, Kiyotaka Onitsuka
Desoxomolybdenum(IV) complex containing bulky hydrophobic groups and NH[round bullet, filled][round bullet, filled][round bullet, filled]S hydrogen bonds, (Et4N)[MoIV(OSitBuPh2)(1,2-S2-3,6-{(4-tBuC6H4)3CCONH}2C6H2)2], was synthesized. This complex promotes the oxygen-atom-transfer (OAT) reaction of DMSO by an efficient uptake of the substrate into...
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Novel reactions of homodinuclear Ni2 complexes [Ni(RNPyS4)]2 with Fe3(CO)12 to give heterotrinuclear NiFe2 and mononuclear Fe complexes relevant to [NiFe]- and [Fe]-hydrogenases

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00067J, PaperLi-Cheng Song, Cao Meng, Yong-Xiang Wang
The homodinuclear complexes [Ni(RNPyS4)]2 (1a-1e; RNPyS4 = 2,6-bis(2-mercaptophenylthiomethyl)-4-R-pyridine; R = H, MeO, Cl, Br, i-Pr) were found to be prepared by reactions of the in situ generated Li2[Ni(1,2-S2C6H4)2] with 2,6-bis[(tosyloxy)methyl]pyridine...
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Solvents dependent reactivities of di-, tetra- and hexanuclear manganese complexes: syntheses, structures and magnetic properties

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03822C, PaperHua Yang, Fan Cao, Dacheng Li, Suyuan Zeng, You Song, Jianmin Dou
An unusual solvent effect on the syntheses of five manganese complexes [Mn2(L1)2(Py)4](1), [Mn2(L1)2(DMSO)4](2), [Mn4(L2)2(DMF4](3), [Mn4(L3)2(DMSO)7(H2O)](4), and [Mn6O2(L4)4(OAc)2(OMe)2(DMSO)4][round bullet, filled]MeOH] (5), (H3L1 = 5-(2-oxyphenyl)-pyrazole-3-carboxylic acid; H2L2 = 5-(2-oxyphenyl)-pyrazole-3-carboxylic acid amide; H4L3 = di-[5-(2-oxyphenyl)-pyrazole]-3-hydroxamic...
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Intermetallic germanides with non-centrosymmetric structures derived from the Yb3Rh4Sn13 type

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03155E, PaperR. Gumeniuk, M. Schoneich, K. O. Kvashnina, L. Akselrud, A. A. Tsirlin, M. Nicklas, W. Schnelle, O. Janson, Q. Zheng, C. Curfs, U. Burkhardt, U. Schwarz, A. Leithe-Jasper
New germanides with composition RE3Pt4Ge13 (RE = Y, Pr, Sm, Gd, Tb, Tm) have been prepared by high-pressure, high-temperature synthesis.
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Reaction mechanism for the highly efficient catalytic decomposition of peroxynitrite by the amphipolar iron(III) corrole 1-Fe

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00086F, PaperShlomit Avidan-Shlomovich, Zeev Gross
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Bright Luminescence in Lanthanide Coordination Polymers with Tetrafluoroterephthalate as a Bridging Ligand

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03733B, PaperUwe Ruschewitz, Miriam Sobieray, Jens Gode, Christiane Seidel, Claus Feldmann, Marieke Po[German sz ligature}
see attached file
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2-Phenylbenzothiazole Conjugated with Cyclopentadienyl Tricarbonyl [CpM(CO)3] (M = Re, 99mTc) Complexes as Potential Imaging Probes for [small beta]‑Amyloid Plaques

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00023H, PaperJianhua Jia, Mengchao Cui, Jiapei Dai, BL Liu
Technetium-99m-labeled cyclopentadienyl tricarbonyl complexes conjugated with the 2-phenylbenzothiazole binding motif were synthesized. The rhenium surrogates 20, 21, 22 and 23 were demonstrated to have moderate to high affinities for A[small beta]1-42...
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Core-level photoemission spectra of Mo0.3Cu0.7Sr2ErCu2Oy, a superconducting perovskite derivative. Unconventional structure/property relations

25 February, 2015 - 04:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00459D, PaperSOURAV MARIK, M A Alario-Franco, Emilio Moran, Olivier Toulemonde, Christine Labrugere
Detailed studies of the electronic states for Mo0.3Cu0.7Sr2ErCu2Oy samples with different oxygen contents are presented here. The influence of oxygenation in the electronic states for the Mo0.3Cu0.7Sr2ErCu2Oy system from a...
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Predicting the reactivity of hydride donors in water: thermodynamic constants for hydrogen

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03841J, PerspectiveSamantha J. Connelly, Eric S. Wiedner, Aaron M. Appel
To improve prediction and comparison of hydride reactivity, self-consistent thermodynamic constants for H+/[radical dot]/- and H2 are proposed for water.
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Why are the {Cu4N4} rings in copper(I) phosphinimide clusters [Cu{[small mu ]-N[double bond, length as m-dash]PR3}]4 (R = NMe3 or Ph) planar?

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00255A, PaperThomas P. Robinson, Richard D. Price, Matthew G. Davidson, Mark A. Fox, Andrew L. Johnson
The molecular structures of the new copper phosphinimide complexes [Cu{[small mu ]-N[double bond, length as m-dash]PR3}]4 (1, R = NMe2 and 2, R = Ph) reveal the presence of planar eight-membered {Cu4N4} rings, which have been shown by DFT calculation to be due to steric factors rather than electronics.
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Lead-free antiferroelectric: xCaZrO3-(1 - x)NaNbO3 system (0 [less-than-or-equal] x [less-than-or-equal] 0.10)

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03919J, PaperHiroyuki Shimizu, Hanzheng Guo, Sebastian E. Reyes-Lillo, Youichi Mizuno, Karin M. Rabe, Clive A. Randall
Crystal chemistry modification stabilized antiferroelectricity in NaNbO3-based polycrystalline ceramics.
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Lanthanide hydroxide ribbons assembled in a 2D network: slow relaxation of the magnetization in the dysprosium(III) complex

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00185D, CommunicationXiaozhou Ma, Na Xu, Chen Gao, Leilei Li, Bingwu Wang, Wei Shi, Peng Cheng
Infinite lanthanide hydroxide ribbons were successfully assembled in 2D networks, among which the dysprosium(III) complex shows slow relaxation of the magnetization.
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A (3,6)-connected layer with an unprecedented adeninate nucleobase-derived heptanuclear disc

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT04020A, CommunicationZheng-Yu Liu, Hong-Yun Zhang, En-Cui Yang, Zhong-Yi Liu, Xiao-Jun Zhao
A (3,6)-connected layer with an adeninate nucleobase-derived CuII7 disc was reported, in which six spin-parallel CuII ions in the exterior of the disc are antiferromagnetically coupled with the central one to give an S = 5/2 ground-state.
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Synthesis and characterization of an immobilizable photochemical molecular device for H2-generation

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03730H, PaperMarkus Braumuller, Martin Schulz, Dieter Sorsche, Michael Pfeffer, Markus Schaub, Jurgen Popp, Byung-Wook Park, Anders Hagfeldt, Benjamin Dietzek, Sven Rau
The immobilizable photocatalyst (4) was synthesized and successfully applied in visible-light-driven hydrogen-generation experiments, supporting its applicability in photoelectrosynthesis cells.
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Icosahedral metallacarborane/carborane species derived from 1,1[prime or minute]-bis(o-carborane)

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00081E, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Gobika Thiripuranathar, Wing Y. Man, Cesar Palmero, Antony P. Y. Chan, Bernhard T. Leube, David Ellis, David McKay, Stuart A. Macgregor, Laure Jourdan, Georgina M. Rosair, Alan J. Welch
Both unisomerised and isomerised singly-metallated derivatives of 1,1[prime or minute]-bis(o-carborane) with both {Ru(arene)} and (CoCp} fragments have been prepared and characterised.
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Regiospecific synthesis of tetrasubstituted phthalocyanines and their liquid crystalline order

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00076A, PaperPetru Apostol, Ahmed Bentaleb, Mbolotiana Rajaoarivelo, Rodolphe Clerac, Harald Bock
The right place, size and shape of substituent make the cyclotetramerisation of alkoxy-phthalonitriles regiospecific and yield columnar liquid crystals with attainable clearing points.
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Binuclear platinum-iridium complexes: synthesis, reactivity and luminescence

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03966A, PaperBrian T. Sterenberg, Christian T. Wrigley, Richard J. Puddephatt
The reactivity of a Pt-Ir metal-metal bonded complex has been studied as a model for bimetallic Pt-Ir catalysts.
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Imidazole derivative-functionalized carbon dots: using as a fluorescent probe for detecting water and imaging of live cells

25 February, 2015 - 04:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00128E, PaperXudong Wang, Dan Wang, Yali Guo, Chengduan Yang, Anam Iqbal, Weisheng Liu, Wenwu Qin, Dan Yan, Huichen Guo
A highly sensitive carbon dot-imidazole (CD-imidazole) nanoprobe is prepared through covalently conjugating the imidazole group onto the surface of carbon dots for water fluorescence .
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