Dalton Transactions

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Reactivity of vinylidene complexes of ruthenium with hydrazines and hydroxylamines

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03464C, PaperGabriele Albertin, Stefano Antoniutti, Marco Bortoluzzi, Alessandra Botter, Jesus Castro
Reaction of vinylidene complexes of Ru with hydrazines and hydroxylamines affords nitrile derivatives and amine or water. A reaction path based on 15N NMR studies and DFT calculations is proposed.
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Terbium-based time-gated Forster resonance energy transfer imaging for evaluating protein-protein interactions on cell membranes

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02884H, PaperStina Linden, Manish Kumar Singh, K. David Wegner, Marie Regairaz, Francois Dautry, Francois Treussart, Niko Hildebrandt
Time-gated Tb-to-dye FRET imaging for the investigation of E- and N-cadherin expression on different model cell lines.
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Synthesis and structural characterization of 3,5-dinitro-1,2,4-triazolates

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03583F, CommunicationR. Haiges, G. Belanger-Chabot, S. M. Kaplan, K. O. Christe
Several novel salts with the energetic 3,5-dinitro-1,2,4-triazolate (DNT) anion have been prepared and characterized.
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Synthesis, structural characterization and thermal properties of copper and silver silyl complexes

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03770G, PaperMichael J. Sgro, Warren E. Piers, Patricio E. Romero
A series of copper and silver-silyl complexes containing N-heterocyclic carbene or N-donor ligands were synthesized and characterized in the solid state. A number of different structural forms were observed and many compounds were shown to be volatile.
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Complex magnetic behaviour of Sr2CoNb1-xTixO6 (0 [less-than-or-equal] x [less-than-or-equal] 0.5) as a result of a flexible microstructure

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03112A, PaperMaria Teresa Azcondo, Julio Romero de Paz, Khalid Boulahya, Clemens Ritter, Flaviano Garcia-Alvarado, Ulises Amador
We report the rich magnetic behaviour of Sr2CoNb1-xTixO6 (0 [less-than-or-equal] x [less-than-or-equal] 0.5) oxides as a result of their complex microstructure.
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Rhodathiaborane reaction cycles driven by C2H4 and H2: synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [([small eta]2-C2H4)(PPh3)RhSB8H7(PPh3)]

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03677H, CommunicationSusana Luaces, Ramon Macias, Maria Jose Artigas, Fernando J. Lahoz, Luis A. Oro
New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by the hydrogenation of the alkene ligand.
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Manganese borohydride; synthesis and characterization

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03501A, PaperBo Richter, Dorthe B. Ravnsbaek, Nikolay Tumanov, Yaroslav Filinchuk, Torben R. Jensen
Three manganese borohydride polymorphs are synthesized in solution and found to be structural analogues of three magnesium borohydride polymorphs.
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A highly stable indium phosphonocarboxylate framework as a multifunctional sensor for Cu2+ and methylviologen ions

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03502J, PaperWenyan Dan, Xiaofeng Liu, Mingli Deng, Yun Ling, Zhenxia Chen, Yaming Zhou
An indium phosphonocarboxylate framework (InPCF-1) with a novel 3,4,5-connected topology was synthesized, which serves as a selective and sensitive sensor for Cu2+ and MV2+ ions.
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A porous ZnGaNO photoanode for efficient water oxidation modified by a Co-based electrocatalyst

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03736G, PaperS. C. Yan, Z. G. Zou
Porous ZnGaNO microrods were synthesized by a single crystal internal decomposition route, and exhibited high performance in photoelectrochemical water splitting due to the high specific area and short charge transfer distance of the microstructure.
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Formylated chloro-bridged iridium(III) dimers as OLED materials: opening up new possibilities

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03127J, PaperMichael Y. Wong, Guohua Xie, Clarisse Tourbillon, Martina Sandroni, David B. Cordes, Alexandra M. Z. Slawin, Ifor D. W. Samuel, Eli Zysman-Colman
In this study, a series of four formyl-substituted chloro-bridged iridium(III) dimers were prepared.
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Synthesis, characterization and solid-state photoluminescence studies of six alkoxy phenylene ethynylene dinuclear palladium(II) rods

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT00493K, PaperJoao Figueira, Wojciech Czardybon, Jose Carlos Mesquita, Joao Rodrigues, Fernando Lahoz, Luca Russo, Arto Valkonen, Kari Rissanen
Solid-state photoluminescence studies of six dinuclear [PdCl(PEt3)2]) rods revealed a decrease in the emission intensity when moving from the free ligands to the Pd complexes.
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Bidentate NHC^pyrozolate ligands in luminescent platinum(II) complexes

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03651D, PaperAbbas Raja Naziruddin, Anzhela Galstyan, Adriana Iordache, Constantin G. Daniliuc, Cristian A. Strassert, Luisa De Cola
The tuning of luminescence from blue to yellow was achieved with platinum complexes containing NHC^pyrozolate and functionalized-phenyl-pyridine or triazole-pyridine ligands.
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Single ion magnet behaviour in a two-dimensional network of dicyanamide-bridged cobalt(II) ions

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03574G, CommunicationJoanna Palion-Gazda, Tomasz Klemens, Barbara Machura, Julia Vallejo, Francesc Lloret, Miguel Julve
The 2D coordination polymer of dca-bridged cobalt(II), [Co(dca)2(atz)2]n, exhibits slow relaxation of the magnetization at low temperatures being thus a new example of single-ion magnet (SIM).
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Structural and magnetic properties of oxyquinolinate clusters of cobalt(II) and manganese(II) and serendipitous intake of carbonate during synthesis

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02999B, CommunicationPrithiviraj Khakhlary, Christopher E. Anson, Abhishake Mondal, Annie K. Powell, Jubaraj B. Baruah
During transformation of a Co4 oxiquinolinate cluster to a Co10 cluster, serendipitous intake of a carbonate ion was observed.
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Synthesis and spectroscopic properties of luminescent tantalum(V)-[small beta]-diketonate complexes and their use as optical sensors and the preparation of nanostructured Ta2O5

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03548H, PaperAna P. Ramos, Dayane C. O. dos Reis, Rafael R. Pereira, Luis G. Dias, Rogeria R. Goncalves
This work proposes a simple and inexpensive method to prepare a new series of [small beta]-diketonate-tantalum complexes.
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Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03835E, CommunicationZhichao Miao, Huahua Zhao, Jian Yang, Jun Zhao, Huanling Song, Lingjun Chou
Mesoporous Mn-Zr composite oxides with a crystalline wall and different manganese contents were designed and achieved by a facile EISA strategy.
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A silver-alkynyl cluster encapsulating a fluorescent polyoxometalate core: enhanced emission and fluorescence modulation

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03826F, PaperChao-Yu Song, Dong-Feng Chai, Rui-Ren Zhang, Hong Liu, Yun-Feng Qiu, Hua-Dong Guo, Guang-Gang Gao
A fluorescent polyoxometalate-based silver(I)-alkynyl cluster exhibits sensitivity towards high energy UV irradiation and selectivity for detection of S2-.
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Unprecedented structural variations in trinuclear mixed valence Co(II/III) complexes: theoretical studies, pnicogen bonding interactions and catecholase-like activities

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03446E, PaperAlokesh Hazari, Lakshmi Kanta Das, Ramakant M. Kadam, Antonio Bauza, Antonio Frontera, Ashutosh Ghosh
Cis-trans configurational changes of trinuclear mixed valence Co(II/III) complexes of a Schiff base ligand and an unusual structure with its reduced form are reported.
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Unprecedented iminobenzosemiquinone and iminobenzoquinone coordinated mononuclear Cu(II) complex formation under air

25 January, 2015 - 21:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03263B, PaperManas Kumar Mondal, Abul Kalam Biswas, Bishwajit Ganguly, Chandan Mukherjee
Ligand H4LS(AP/AP) comprised of two orthogonally placed non-innocent unit that were bridged by a common -ortho S atom. It reacted with CuCl2[middle dot]2H2O and provided a mononuclear diamagnetic Cu(II) complex where two non-innocent units were in two different oxidation states.
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1,2,4-Triazole-derived Carbene Complexes of Gold: Characterization, Solid-State Aggregation and Ligand Disproportionation

25 January, 2015 - 21:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03201B, PaperShuai Guo, Jan Christopher Bernhammer, Han Vinh Huynh
Ligand redistribution reactions are well documented for silver(I) N-heterocyclic carbene (NHC) complexes of the type [AgX(NHC)] (X = halido ligand), but only two reports have been described in the literature...
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