Dalton Transactions

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A New Copper Species Based on An Azo-compound Utilized as A Homogeneous Catalyst for Water Oxidation

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03097D, PaperWeibin Yu, Qing-Ya He, Xiu-Fang Ma, Hua-Tian Shi, Xianwen Wei
A new azo-complex [(L)CuII(NO3)] [L = (E)-3-(pyridin-2-yldiazenyl)naphthalen-2-ol (HL)], was prepared via one-pot synthetic method at 60℃ and was structurally characterized by IR, EA, PXRD and single crystal X-ray diffraction. In...
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The origin of the antiferromagnetic behaviour of the charge-transfer compound (HMTTF)[Ni(mnt)2]

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03117B, PaperMerce Deumal, Maria Fumanal, Sergi Vela
The charge-transfer (HMTTF)[Ni(mnt)2] material (1) was the first mixed-stack compound reported to present ferromagnetic (FM) interactions between the donor (D) and acceptor (A) units within each mixed-stack. Despite the presence...
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Facilely synthesized benzotriazole phenolate zirconium complexes as versatile catalysts for copolymerization of carbon dioxide with cyclohexene oxide and lactide polymerization

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02774D, PaperHui-Ju Chuang, Bao-Tsan Ko
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Cluster-controlled dimerisation in supramolecular ruthenium photosensitizer-polyoxometalate systems

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03017F, PaperKirsten Heussner, Katrin Peuntinger, Nils Rockstroh, Carsten Streb, Sven Rau
A supramolecular reaction system is reported where a labile molecular metal oxide cluster enables the unprecedented dimerisation of ruthenium photosensitizers [Ru(L)2(tmbiH2)]2+ (L = 4,4'-di-tert-butyl-2,2'-bipyridine (1a) or 2,2'-bipyridine (1b); tmbiH2 =...
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Tunable optical properties for hybrid inorganic-organic [(TiO2)m(Ti-O-C6H4-O-)k]n superlattice thin films

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02550D, PaperJanne-Petteri Niemela, Maarit Karppinen
A combined atomic layer deposition (ALD) and molecular layer deposition (MLD) process was developed to fabricate inorganic-organic [(TiO2)m(Ti-O-C6H4-O-)k]n thin films from TiCl4, water and hydroquinone (HQ) precursors, and in particular,...
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A Series of Cobalt and Nickel Clusters Based on Thiol-containing Ligands Accompanied by in situ Ligand Formation

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03109A, PaperSong-De Han, Xiao-Hong Miao, Suijun Liu, Xian-He Bu
Eight cobalt and nickel clusters with the formulas of [Co4([small micro]4-O)(MBT)5([small micro]2-Piv)] (1), [Ni3(MBT)2(L1)2(OCH3)2] (2), [Ni4([small micro]3-S)([small micro]3-S2)(MBT)2(L2)] (3), [Ni4(L3)4] (4), [Ni6([small micro]4-S)3(MBT)6][round bullet, filled](C2H5OH)2 (5), H[Co4([small micro]4-O)(HMBI)6][round bullet, filled](NO3)(TEA)0.5(CH3OH)2(H2O) (6), [Ni2(HMBI)4][round bullet, filled](CH3OH)2 (7), and [Ni5(MBI)2(HMBI)4(OCH3)2][round bullet, filled](CH3OH)3(H2O)2 (8) (HPiv = Pivalic acid,...
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An Expedient Approach to Fluorescent 3-Substituted 4H-quinolizin-4 ones via ([small eta]4-vinylketene)-Fe(CO)3 Complexes

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03021D, PaperALFREDO ROSAS-SANCHEZ, Alfredo Toscano, Jose GUadalupe Lopez Cortes, M. Carmen Ortega-Alfaro
An efficient and practical methodology for the synthesis of 3-substituted 4H-quinolizin-4-ones using ([small eta]4-vinylketene)-Fe(CO)3 complexes as key intermediates has been developed. The advantage of this transformation lies in the use of...
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BaMn9II(VO4)6(OH)2: a homospin ferrimagnet with a broken spinel-lattice of B-site

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02930E, PaperWenbin Guo, Zhangzhen He, Ying-Ying Tang, Su-Yun Zhang, Ming Yang, Wen-Dan Cheng
A new vanadate of BaMn9II(VO4)6(OH)2 was synthesized by a conventional hydrothermal method. BaMn9II(VO4)6(OH)2 crystallizes in cubic space group of Pa , which exhibits an edge-sharing MnO6 octahedral network structure with...
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Cyclic Six-membered Palladium Complexes Derived from Palladium Mediated C-N Coupling of Organonitrile and Formamidine

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02721C, PaperGanapathi Anantharaman, Vivek Gupta, Vedhagiri Karthik
Reactions of N,N'-bis(2,6-diisopropylphenyl) formamidinium chloride (1) with palladium acetate in acetonitrile or propanenitrile results in the formation of cyclic six-membered triazapentadiene-palladium dichloride complexes (4 and 5). In case of reaction...
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Development of a cyclometalated iridium complex with specific intramolecular hydrogen-bonding that acts as a fluorescent marker for the endoplasmic reticulum and causes photoinduced cell death

24 October, 2014 - 21:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT00845F, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.Soumik Mandal, Dipak K. Poria, Ritabrata Ghosh, Partho Sarothi Ray, Parna Gupta
A phosphorescent iridium(III) complex shows selective localization and high fluorescence in the endoplasmic reticulum along with photoinduced cell death of breast carcinoma cells.
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A nuclear chocolate box: the periodic table of nuclear medicine

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02846E, PerspectivePhilip J Blower
Radioisotopes of elements from all parts of the periodic table find both clinical and research applications in radionuclide molecular imaging and therapy (nuclear medicine). This article provides an overview of...
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Synthesis and characterisation of lanthanide-hydroporphyrin dyads

24 October, 2014 - 21:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02448F, PaperRuisheng Xiong, Julien Andres, Kira Scheffler, K. Eszter Borbas
Hydroporphyrin-linked lanthanide complexes with variations in tetrapyrrole structure, linker length and mode of attachment are reported.
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EuroTracker[registered sign] dyes: design, synthesis, structure and photophysical properties of very bright europium complexes and their use in bioassays and cellular optical imaging

24 October, 2014 - 21:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02785J, PerspectiveStephen J. Butler, Martina Delbianco, Laurent Lamarque, Brian K. McMahon, Emily R. Neil, Robert Pal, David Parker, James W. Walton, Jurriaan M. Zwier
The creation of the most emissive series of europium complexes is traced and examples given of their use in imaging.
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Can a pentamethylcyclopentadienyl ligand act as a proton-relay in f-element chemistry? Insights from a joint experimental/theoretical study

24 October, 2014 - 21:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02387K, PaperChristos E. Kefalidis, Lionel Perrin, Carol J. Burns, David J. Berg, Laurent Maron, Richard A. Andersen
Isomerisation of buta-1,2-diene to but-2-yne by (Me5C5)2Yb is a thermodynamically favourable reaction, with the [capital Delta]rG[degree] estimated from experimental data at 298 K to be -3.0 kcal mol-1.
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Dual ligand-based fluorescence and phosphorescence emission at room temperature from platinum thioxanthonyl complexes

24 October, 2014 - 21:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02410A, PaperFabian Geist, Andrej Jackel, Rainer F. Winter
Platinum complexes with [sigma]-bonded thioxanthonyl (Tx) ligands exhibit, on irradiation into the Tx [small pi][rightward arrow][small pi]* band, dual Tx-based fluorescence and phosphorescence emission with phosphorescence quantum yields of up to 19% in fluid solution at room temperature.
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Zinc complexes as fluorescent chemosensors for nucleic acids: new perspectives for a "boring" element

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02881C, PerspectiveAlessio Terenzi, Antonino Lauria, Anna Maria Almerico, Giampaolo Barone
Zinc(II) complexes are effective and selective nucleic acid-binders and strongly fluorescent molecules in the low energy range, from the visible to the near infrared. These two properties have been often...
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Redox-active multinuclear Pd(II) complexes with bis- and tris-mesoionic carbenes

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03239J, CommunicationBiprajit Sarkar, Ramananda Maity, Margarethe van der Meer
Synthesis of a ligand platform to generate di- and tri-mesoionic carbenes is reported together with their multinuclear Pd(II) complexes. A complete structural characterization and preliminary electrochemical data are presented.
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Arene-ligated heteroleptic terphenolate complexes of thorium

24 October, 2014 - 21:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02995J, PaperJamie McKinven, Gary S. Nichol, Polly L. Arnold
Bulky terphenolate ligands allow the synthesis of rare heteroleptic thorium chloride, and borohydride complexes; in the absence of donor solvents, the terphenolate ligands protect the metal ions through neutral Th-[small eta]6-arene interactions in a thorium bis(arene) sandwich motif.
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Stable anode performance of vanadium oxide hydrate semi-microsphers and their graphene based composite microspheres in sodium-ion batteries

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02988G, PaperHailong Fei, Zhiwei Li, Wenjing Feng, Xin Liu
A simple and versatile method for preparation of new crystalline vanadium oxide hydrate semi-microspheres is developed via a simple hydrothermal route, which are tested as a novel high-energy anode material...
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[([small eta] 5-C5Me5)Ru]+ fragments ligated to polyaromatic hydrocarbons: an experimental and computational approach of pathways for haptotropic migration

24 October, 2014 - 21:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02736A, PaperJean-Rene HAMON, Matias Rioja, Paul Hamon, Thierry Roisnel, Sourisak Sinbandhit, Mauricio Fuentealba, Karina Letelier, Jean Yves Saillard, Andres Vega
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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