Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC18139H, CommunicationYaojia Jiang, Vanessa Zhong Yue Khong, Emmanuvel Lourdusamy, Cheol-Min Park
A dual synthetic manifold for 2-aminofurans and 2-unsubstituted furans has been developed based on cycloaddition of copper carbenoids with enamines.
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC30261F, CommunicationTeck Peng Loh, Jian Xiao, Kai Zhao
The acid free asymmetric intermolecular [small alpha]-alkylation of aldehydes with alcohols has been discovered using trifluoroethanol as solvent. This unprecedented green system affords the enantioenriched functionalized aldehydes in high yields, good...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC30569K, CommunicationDae Won Cho, Mamoru Fujitsuka, Jung Ho Ryu, Myoung Hee Lee, Hwan Kyu Kim, Tetsuro Majima, chan im
Novel boron dipyrromethane (BODIPY) derivatives were synthesized to have significant absorption and emission in the longer wavelength region. BODIPY showed anomalous S2 emission from the second excited (S2) state at...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17802H, CommunicationVandana Kumar Bhalla, Harshveer Arora, Abhimanew Dhir, Manoj Kumar
A new triphenylene based receptor 3 has been designed and synthesized which behaves as 'turn on' sensor for Zn2+ ions. Zinc ensemble of 3 (Zn-3) has been evaluated for its...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC30172E, CommunicationEtienne Mazoyer, Kai C. Szeto, Jean-Marie Basset, Christopher P Nicholas, mostafa taoufik
The first example of propylene production from 2-butene in promising yield is described by reacting trans-2-butene over tungsten hydrides precursor W-H/Al2O3 at 150 [degree]C and different pressures in a continuous...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17154F, CommunicationHaiyang Gao, Haibin Hu, Zhu Fangming, Wu Qing
New nickel complexes bearing the amine-imine ligand were successfully synthesized and used as catalyst precursors for ethylene polymerization in a living fashion. A bulky amine-imine nickel complex containing two 2,6-diisopropyl...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17702A, CommunicationBabak Karimi, Majid Vafaeezadeh
Incorporation of a hydrophobic Bronsted acid ionic liquid (HBAIL) inside the nanospace of SBA-15-Pr-SO3H lead to the highly powerful and hydrophobic super Bronsted acid catalyst. The resulting catalyst showed excellent...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17393J, CommunicationZahra Khedri, Musleh M. Muthana, Yanhong Li, Saddam M. Muthana, Hai Yu, Hongzhi Cao, Xi Chen
A library of alph2-3- and alpha2-6-linked sialyl galactosides containing C9-modified sialic acids was synthesized from C6-modified mannose derivatives using an efficient one-pot three-enzyme system. These sialosides were used in a...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC30305A, CommunicationHuanghao Yang, Aixian Zheng, Juan Li, Jinru Wang, Xiaorong Song, Guo Nan Chen
A simple, highly sensitive and enzyme-free DNAzyme sensor based on target-catalyzed hairpin assembly is developed, which permits detection of 0.1 pM target DNA. Furthermore, this DNAzyme sensor is capable of...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17695E, Feature ArticleShiyong Liu
Fluorescent polymeric assemblies and nanoparticles (NPs) of nanoscale dimensions have become a focus of intensive investigations during the past few decades due to combined advantages such as improved biocompatibility, water...
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Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC17940G, CommunicationHidetoshi Goto, Yuko Yokochi, Eiji Yashima
An achiral polythiophene formed a unique optically active metal-induced supramolecular aggregate upon complexation with chiral amines or in the presence of a chiral polythiophene in a good solvent for the polymers, thus showing an induced circular dichroism.
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Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC18098G, CommunicationTakanori Matsuda, Yuya Suda, Akira Takahashi
1,4-Rhodium migration occurs twice during the course of the rhodium-catalysed arylative ring-opening/spirocyclisation reaction of (3-arylcyclobutylidene)acetates affording 1,1[prime or minute]-spirobiindanones.
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Chem. Commun., 2012, Advance Article
DOI: 10.1039/C1CC15851A, CommunicationGuoxian Gu, Huihui Wang, Pi Liu, Chenzeng Fu, Zhonghua Li, Xuefeng Cao, Yunping Li, Qinghong Fang, Feng Xu, Jie Shen, Peng George Wang
A novel bisaryl maleimide derivative hit was found in a 124-kinase-assay, which targeted three out of 124 human kinases. Structurally diversified bisaryl maleimides were prepared using click chemistry.
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Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC17332H, CommunicationMatthew R. Kelley, Jan-Uwe Rohde
Reaction of an Ir^I complex with O₂ generates an (alkene)peroxoiridium(III) intermediate whose decay and subsequent reaction with 1,5-cyclooctadiene produces 4-cycloocten-1-one.
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC17422G, CommunicationYongxi Zhao, Lin Qi, Feng Chen, Yanhua Dong, Yu Kong, Yayan Wu, Chunhai Fan
An ultrasensitive fluorescence assay for nicotinamide adenine dinucleotide (NAD+) was developed by target-triggered ligation-rolling circle amplification (L-RCA). This novel approach can detect as low as 1 pM NAD+, much lower...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC18188F, CommunicationYi Xie, Min Zhou, Jian Bao, Minshan Tao, Rui Zhu, Yongquan Zeng, Zongwen Wei
Alternate dielectric component is first introduced into nanowall skeleton. This novel model as an electrode can optimize the process of photon absorption, charge separation/migration and surface reaction, resulting in superior...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC18011A, CommunicationYuichiro Koide, Mitsuyasu Kawaguchi, Urano Yasuteru, kenjiro Hanaoka, Toru Komatsu, Masahiro Abo, Takuya Terai, Tetsuo Nagano
We have designed and synthesized a reversible near-infrared (NIR) fluorescence probe, 2-Me TeR, for reactive oxygen species (ROS), utilizing the redox properties of the tellurium (Te) atom. 2-Me TeR is...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC30208J, CommunicationXiaohui Wang, Yanzhu Guo, Dong Li, Hui Chen, Run-Cang Sun
Novel fluorescent amphiphilic cellulose nanoaggregates sensing system is designed and applied in detecting explosives in aqueous solution. Due to the maximized interaction between sensing material and analyte within the cellulose-based...
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Chem. Commun., 2012, Accepted Manuscript
DOI: 10.1039/C2CC00015F, CommunicationYinque Liu, Fan Zhang, Chunyang He, Dongqing Wu, Xiaodong Zhuang, Minzhao Xue, Xinliang Feng
A series of novel H-shaped molecules consisting of 2,3,7,8-tetraazaanthracene core and thiophene arms have been developed. The electrochemical study reveals their typical n-type characters. The solid state packing and optoelectronic...
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Chem. Commun., 2012, Advance Article
DOI: 10.1039/C2CC16279B, CommunicationYong Wang, Yu Zheng, Fan Yang, Xiurong Yang
A dual polarisation interferometry technique was used to investigate the interaction of Hg²⁺ with a T-rich oligonucleotide and construct a Hg²⁺ biosensor.
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