Org. and Biomol. Chem.

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An efficient Au-catalyzed synthesis of isomukonidine, clausine L, mukonidine, glycosinine, mukonal, and clausine V from propadienyl methyl ether

27 February, 2013 - 05:17

Org. Biomol. Chem., 2013, 11,1666-1671
DOI: 10.1039/C2OB27432A, PaperYouai Qiu, Dengke Ma, Chunling Fu, Shengming Ma
Naturally occurring carbazole alkaloids such as isomukonidine, clausine-L, mukonidine, glycosinine, mukonal, and clausine V were synthesized through a gold-catalyzed cyclization reaction of 1-(indol-2-yl)-2-methoxy-2,3-allenols.
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Synthesis of helically twisted [1 + 1]macrocycles assisted by amidinium-carboxylate salt bridges and control of their chiroptical properties

27 February, 2013 - 05:17

Org. Biomol. Chem., 2013, 11,1614-1623
DOI: 10.1039/C2OB27054D, PaperYuji Nakatani, Yoshio Furusho, Eiji Yashima
Novel twisted [1 + 1]macrocycles were prepared through amidinium-carboxylate salt bridges, whose chirality could be controlled by acid-base interactions and zinc coordination.
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