Royal Society of Chemistry

Towards single molecule switches

Chem. Soc. Rev. - 5 hours 50 min ago

Chem. Soc. Rev., 2015, 44,2998-3022
DOI: 10.1039/C4CS00377B, Review ArticleJia Lin Zhang, Jian Qiang Zhong, Jia Dan Lin, Wen Ping Hu, Kai Wu, Guo Qin Xu, Andrew T. S. Wee, Wei Chen
Scanning tunneling microscope (STM) controlled reversible switching of a single-dipole molecule imbedded in hydrogen-bonded binary molecular networks on graphite.
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Cancer biomarker detection: recent achievements and challenges

Chem. Soc. Rev. - 5 hours 50 min ago

Chem. Soc. Rev., 2015, 44,2963-2997
DOI: 10.1039/C4CS00370E, Review ArticleLi Wu, Xiaogang Qu
We provide an overview covering the existing challenges and latest developments in achieving high selectivity and sensitivity cancer-biomarker detection.
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Specific light-up bioprobes based on AIEgen conjugates

Chem. Soc. Rev. - 5 hours 50 min ago

Chem. Soc. Rev., 2015, 44,2798-2811
DOI: 10.1039/C4CS00444B, Tutorial ReviewJing Liang, Ben Zhong Tang, Bin Liu
This review summarizes the synthesis, the operation mechanism and design principles of specific AIE light-up bioprobes with applications in bio-analyte sensing, cell imaging and cancer therapy.
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FDPHOTOC15: Parameters influencing the photo-induced electron transfer from tryptophan containing peptides to a RuII complex: a systematic study

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00059A, PaperKevin Garnir, Sandra Estalayo-Adrian, Remy Lartia, Julien De Winter, Eric Defrancq, Mathieu Surin, Vincent Lemaur, Pascal Gerbaux, Cecile Moucheron
Ruthenium (II) polyazaaromatic complexes gained interest in the last decades as biomolecular tools especially in the development of new phototherapeutic agents. Those light emissive Ru complexes based on pi-deficient ligands...
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FDPHOTOC15: Solvent tuned single molecule dual emission in protic solvents: effect of polarity and H-bonding

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00054H, PaperSylviane Chevreux, Clemence Allain, Liam Wilbraham, Keitaro Nakatani, Patrice Jacques, Ilaria Ciofini, Gilles LEMERCIER
Phen-PENMe2 has been recently proposed as a promising new molecule displaying solvent-tuned dual emission highlighting an original and newly-described OPICT ("Orthogonal [small pi]-Orbital Planar Intramolecular Charge Transfer") model. Study was continued...
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Kinetics of CO/CO2 and H2/H2O reactions at Ni-based and ceria-based solid-oxide-cell electrodes

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00048C, PaperChristopher Graves, Christodoulos Chatzichristodoulou, Mogens Mogensen
Solid oxide electrochemical cells (SOCs) are an energy conversion technology that can be operated reversibly, to efficiently convert chemical fuels to electricity (fuel cell mode) as well as to store...
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FDCDU15 - Carbon Dioxide Utilisation: A framework for the analysis of the security of supply of utilising Carbon Dioxide as a chemical feedstock

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00038F, PaperEric Fraga, Melvin Ng
Recent developments in catalysts have enhanced the potential for the utilisation of carbon dioxide as a chemical feedstock. Appropriate catalysts make possible and/or energy efficient a range of chemical pathways...
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Enhanced Raman Scattering from Aromatic Dithiols Electrosprayed into Plasmonic Nanojunctions

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00036J, PaperPatrick ElKhoury, Grant E Johnson, Irina V. Novikova, Yu Gong, Alan Joly, James E. Evans, Mikhail Zamkov, Julia Laskin, Wayne Hess
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Nanoparticles and self-organisation: the emergence of hierarchical properties from the nanoparticle soup (i.e., the small is getting bigger). Concluding remarks for FD 181

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00094G, PaperDavid Schiffrin
No abstract required
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Photosynthetic Water Oxidation: Binding and Activation of Substrate Waters for O-O Bond Formation

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00087D, PaperDavid Vinyard, Sahr Khan, Gary Brudvig
Photosynthetic water oxidation occurs at the oxygen-evolving complex (OEC) of Photosystem II (PSII). The OEC, which contains a Mn4CaO5 inorganic cluster ligated by oxides, waters and amino-acid residues, cycles through...
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FD2015-Single Molecule Microscopy: Optical micro-spectroscopy of single metallic nanoparticles: Quantitative extinction and transient resonant Four-Wave Mixing

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00079C, PaperLukas Payne, George Zoriniants, Francesco Masia, Kenton P Arkill, Paul Verkade, Darren Rowles, Wolfgang W Langbein, Paola Borri
We report a wide-field imaging method to rapidly and quantitatively measure the optical extinction cross-section [sigma]ext (also polarisation resolved) of a large number of individual gold nanoparticles, for statistically-relevant single...
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FDCDU15 - Carbon Dioxide Utilisation: Thioether-Triphenolate Bimetallic Iron(III) Complexes as Robust and Highly Efficient Catalysts for Cycloaddition of Carbon Dioxide to Epoxides

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00070J, PaperAntonio Buonerba, Francesco Della Monica, Assunta De Nisi, Ermanno Luciano, Stefano Milione, Alfonso Grassi, Carmine Capacchione, Bernhard Rieger
The selective and effective synthesis of organic carbonates under mild conditions, starting from carbon dioxide and oxiranes, catalyzed by metal complexes is currently in the focus of interest for both...
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FDPHOTOC15: The Development of Supramolecular Assemblies for Photocatalytic Hydrogen Generation from Water

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00068H, PaperHan Vos, Wesley Browne, Mary Pryce, Annemarie Huijser, Qing Pan, Sven Rau, Philipp Lang, laura O'Reilly, Tanja Kowacs
A series of supramolecular assemblies of the type [Ru(L-L)2(L'-L)MX2)]n+ are reported where L-L is 2,2'-bipyridine (bipy) 4,4'-di-tetra-butyl-bipyridine (tbbipy) or 4,4'-diethoxycarbonyl-2,2'-bipyridine (dceb) and L-L' is tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazine (tpphz), 2,2':5',2"-terpyridine (2,5-bpp), 2,2':6',2"-terpyridine, (2,6-bpp),...
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Crystal nucleation from solutions - transition states, rate determining steps and complexity

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C5FD00037H, PaperRoger J. Davey, Kevin R. Back, Rachel A. Sullivan
To cite this article before page numbers are assigned, use the DOI form of citation above.
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FD Corrosion Chemistry: Introductory Lecture Introductory Lecture on Corrosion Chemistry: A Focus on Anodic Hydrogen Evolution on Al and Mg

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00066A, PaperGerald Frankel, Santiago Fajardo, Brandon Lynch
The increase in the rate of hydrogen evolution (HE) on dissolving Mg surfaces with increasing anodic current density or potential, which is sometimes called the negative difference effect, has been...
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Near-field Raman Spectroscopy of Nanocarbon Materials

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00050E, PaperZachary Lapin, Ryan Beams, L. G. Cancado, Lukas Novotny
Nanocarbon materials, including the sp2 hybridized two-dimensional graphene and one-dimensional carbon nanotubes, and the sp1 hybridized one-dimensional carbyne, are being considered for the next generation of integrated optoelectronic devices. The...
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Low-current field-assisted assembly of copper nanoparticles for current collectors

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C4FD00263F, PaperLehao Liu, Bong Gill Choi, Siu On Tung, Tao Hu, Yajie Liu, Tiehu Li, Tingkai Zhao, Nicholas A. Kotov
To cite this article before page numbers are assigned, use the DOI form of citation above.
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Concluding remarks

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Advance Article
DOI: 10.1039/C5FD00042D, PaperAllan S. Myerson
To cite this article before page numbers are assigned, use the DOI form of citation above.
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FDPHOTOC15: Raising the Barrier for Photoinduced DNA Charge Injection with a Cyclohexyl Artificial Base Pair

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00043B, PaperFrederick D Lewis, Arunoday P. N. Singh, Michelle A. Harris, Ryan Michael Young, Stephen A. Miller, Michael R Wasielewski
The effects of an artificial cyclohexyl base pair on the quantum yields of fluorescence and dynamics of charge separation and charge recombination have been investigated for several synthetic DNA hairpins....
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Introductory lecture: nanoplasmonics

Faraday Disc. - 7 hours 50 min ago
Faraday Discuss., 2015, 178,9-36
DOI: 10.1039/C5FD90020D, PaperMark L. Brongersma
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