Royal Society of Chemistry

Rapid degradation of cyclic peroxides by titanium and antimony chlorides

Dalton Transactions - 3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00200A, PaperAnthony Day, Mark Bali, David Armitt, Lynne Wallace
First responders face extraordinary risks when dealing with organic peroxides such as TATP due to the extreme sensitivity of this class of explosives, and to a lack of a robust...
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Dynamic structure elucidation of chemical reactivity by laser pulses and X-ray probes

Dalton Transactions - 3 March, 2015 - 06:17
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00210A, FrontierStuart Andrew Bartlett, Michelle L Hamilton, John Evans
Visualising chemical reactions by X-ray methods is a tantalising prospect. New light sources provide the prospect for studying atomic, electronic and energy transfers accompanying chemical change by X-ray spectroscopy and...
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Iron catalysed Negishi cross-coupling using simple ethyl-monophosphines

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00112A, PaperCaleb A. Brown, Terence A. Nile, Mary F. Mahon, Ruth L. Webster
Reported is a rare example of the use of monophosphines in iron catalysed Negishi cross-coupling. Substrate scope in terms of alkyl bromide and diaryl zinc reagent is explored.
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In search for new bonding modes of the methylenedithiolato ligand: novel tri- and tetra-metallic clusters

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00179J, PaperR. S. Anju, Koushik Saha, Bijan Mondal, Thierry Roisnel, Jean-Francois Halet, Sundargopal Ghosh
Photolysis of arachno-[(Cp*Ru)2(B3H8)(CS2H)] in the presence of [Re2(CO)10] produced [(Cp*Ru)2B3H5(CH2S2){Re(CO)4}2], with a planar 8-membered ring containing heavier transition metals and a main group element.
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A series of lanthanoid selenidoantimonates(V): rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00146C, PaperHong-Ping Xiao, Jian Zhou, Rong-Qing Zhao, Wei-bing Zhang, Yong Huang
This work provides rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes.
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A panchromatic hybrid crystal of iodoplumbate nanowires and J-aggregated naphthalene diimides with long-lived charge-separated states

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03785E, CommunicationJian-Jun Liu, Ying-Fang Guan, Chen Jiao, Mei-Jin Lin, Chang-Cang Huang, Wen-Xin Dai
A panchromatic hybrid crystal of anionic iodoplumbate nanowires and J-aggregated protonated naphthalene diimides has been formed through charge-assisted anion-[small pi] and lone pair-[small pi] interactions.
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Synthesis, X-ray structure and in vitro cytotoxicity studies of Cu(I/II) complexes of thiosemicarbazone: special emphasis on their interactions with DNA

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03764B, Paper Saswati, Ayon Chakraborty, Subhashree P. Dash, Alok K. Panda, Rama Acharyya, Ashis Biswas, Subhadip Mukhopadhyay, Sujit K. Bhutia, Aurelien Crochet, Yogesh P. Patil, M. Nethaji, Rupam Dinda
The interactions of four Cu-TSC complexes with DNA & their cytotoxicity studies against the HeLa cell have been reported.
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O,N,N-Pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00062A, PaperLuka A. Wright, Eric G. Hope, Gregory A. Solan, Warren B. Cross, Kuldip Singh
The structural properties of a series of ONN-Pd(II) chloride pincer complexes have been shown to influence the conversion to 4-chlorotoluene upon oxidation with di-p-tolyliodonium triflate.
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Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of [varepsilon]-caprolactone

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00272A, PaperYahya Al-Khafaji, Xinsen Sun, Timothy J. Prior, Mark R. J. Elsegood, Carl Redshaw
Reaction of the pro-ligands [small alpha],[small alpha],[small alpha][prime or minute],[small alpha][prime or minute]-tetra(3,5-di-tert-butyl-2-hydroxyphenyl-p-(or -m-)xylene-para-(or -meta-)tetraphenol with [MCl5] (M = Nb, Ta) or [Nb(O)Cl3(NCMe)2] afforded complexes capable of the ROP of e-caprolactone at high temperature.
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Tuning the electronic and phosphorescence properties of blue-emitting iridium(III) complexes through different cyclometalated ligand substituents: a theoretical investigation

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00048C, PaperJieqiong Li, Qing Zhang, Hongqing He, Li Wang, Jinglai Zhang
A DFT/TDDFT investigation was performed to estimate the OLED performance of six reported and seven newly designed iridium(III) complexes.
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Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C-H bond cleavage/dimethylamino capture or intact DMPEA complex

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00247H, PaperAlan R. Kennedy, Robert E. Mulvey, Donna L. Ramsay, Stuart D. Robertson
The cleave and capture capacity of various bimetallic amido-alkyl mixtures is illustrated through reaction with the deprotonation sensitive N,N-dimethylphenylethylamine.
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Hierarchical cupric oxide nanostructures on copper substrate for cold cathode emission: an experimental venture with theoretical correlation

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02944E, PaperSwati Das, Subhajit Saha, Dipayan Sen, Uttam Kumar Ghorai, Kalyan Kumar Chattopadhyay
Wet chemically developed CuO nanoneedles show lower turn-on value along with heightened enhancement factor. Structural anisotropy mediated better field enhancement characteristics is also reflected from the simulated data.
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A family of [MnIII6LnIII2] rod-like clusters

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00300H, PaperThomais G. Tziotzi, Dimitris A. Kalofolias, Demetrios I. Tzimopoulos, Milosz Siczek, Tadeusz Lis, Ross Inglis, Constantinos J. Milios
A family of octametallic heteronuclear manganese-lanthanide [MnIII6Ln2] complexes were isolated and characterized by magnetic measurements.
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Three new mononuclear tri-spin lanthanide-nitronyl nitroxide radical compounds: syntheses, structures and magnetic properties

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03941F, PaperLei-Lei Li, Shuang Liu, Yuan Zhang, Wei Shi, Peng Cheng
Three new mononuclear tri-spin Ln-NITR compounds were synthesized and characterized in which the TbIII compound exhibits field-induced single-molecule magnet behaviour.
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New quaternary arsenide oxides with square planar coordination of gold(I) - structure, 197Au Mossbauer spectroscopic, XANES and XPS characterization of Nd10Au3As8O10 and Sm10Au3As8O10

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00193E, PaperTimo Bartsch, Oliver Niehaus, Dirk Johrendt, Yasuhiro Kobayashi, Makoto Seto, Paula M. Abdala, Manfred Bartsch, Helmut Zacharias, Rolf-Dieter Hoffmann, Birgit Gerke, Ute Ch. Rodewald, Rainer Pottgen
The title compounds were synthesised and characterised.
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Ethylene polymerisation and ethylene/norbornene copolymerisation by using aryloxo-modified vanadium(V) complexes containing 2,6-difluoro-, dichloro-phenylimido complexes

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT04026K, PaperNichabhat Diteepeng, Xiaoyan Tang, Xiaohua Hou, Yue-Sheng Li, Khamphee Phomphrai, Kotohiro Nomura
V(N-2,6-X2C6H3)Cl2(O-2,6-R2C6H3) (X = Cl, F; R = Me, F) showed remarkable activity in ethylene polymerisation and the copolymerisation with norbornene in the presence of Et2AlCl.
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Synthesis of zinc phthalocyanine with large steric hindrance and its photovoltaic performance for dye-sensitized solar cells

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03397C, PaperLi Lin, Bosi Peng, Wenye Shi, Yingying Guo, Renjie Li
An asymmetric zinc phthalocyanine with large steric hindrance (Zn-tri-PcNc-8) shows a best efficiency of 3.01%.
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Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00079C, PaperMelissa Wu. M, Arran M. Gill, Lu Yunpeng, Laura Falivene, Li Yongxin, Rakesh Ganguly, Luigi Cavallo, Felipe Garcia
Treatment of a series of aromatic NHCs with trimethylaluminium produced their corresponding NHC[middle dot]AlMe3 adducts displaying different stabilities. Their stabilities are rationalized using topographic steric maps and NHC % V Bur.
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Two novel octamolybdate nanoclusters as catalysts for dye degradation by air under room conditions

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03377A, PaperMahnaz Najafi, Alireza Abbasi, Majid Masteri-Farahani, Jan Janczak
Two new octamolybdate-based hybrid materials as catalysts for the wet air oxidation of dyes under mild conditions.
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A facile room temperature iodination route to in situ fabrication of patterned copper-iodide/silicon quasi-bulk-heterojunction thin films for photovoltaic application

Dalton Transactions - 3 March, 2015 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03762F, PaperLei Zhang, Yan Lei, Xiaogang Yang, Jiamei Cheng, Chengxiang Wang, Huimin Jia, Zhi Zheng
A facile room temperature iodination approach is developed to in-situ fabrication of monocrystalline CuI/Si quasi-bulk-heterojunction thin films by firstly depositing an elemental copper layer on pyramidally patterned silicon surface followed by a direct elemental reaction with iodine vapour.
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