Royal Society of Chemistry

A Step Closer to the Binary: The 1[infinity][Bi6I20]2- Anion

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00813A, PaperJohanna Heine
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Controllable synthesis of various kinds of copper sulfides (CuS, Cu7S4, Cu9S5) for high-performance supercapacitors

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00402K, PaperYing Wang, Fuyang Liu, Ying Ji, min yang, Wei Liu, Wei Wang, Qiushi Sun, Ziqing Zhang, Xudong Zhao, Xiaoyang Liu
Abstract Three types of copper sulfides including CuS, Cu7S4 and Cu9S5 were successfully synthesized under different concentrations of ethylenediamine in a liquid phase synthesis process. The whole shape evolution of...
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Regulation of Cerium(IV)-driven O2 Evolution Reaction using Composites of Liposome and Lipophilic Ruthenium Complexes

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00793C, CommunicationTomomi Koshiyama, Nao Kanda, Koki Iwata, Masayuki Honjo, Sana Asada, Tatsuru Hatae, Yasuhiro Tsuji, Masaki Yoshida, Masaya Okamura, Reiko Kuga, Shigeyuki Masaoka, Masaaki Ohba
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Carboxy Derivatised Ir(III) Complexes: Synthesis, Electrochemistry, Photophysical Properties and Photocatalytic Hydrogen Generation

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00324E, PaperMary Pryce, Han Vos, Avishek Paul, Yvonne Halpin, Nivedita Das
In this contribution the synthesis and characterisation of a series of novel mixed ligand iridium(III) complexes, functionalised with a carboxy ester or phosphonate groups are reported. These groupings are introduced...
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Fluorescent benzene-centered mono-, bis- and tris-triazapentadiene-boron complexes

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00908A, PaperChristoph Glotzbach, Nadine Godeke, Roland Frohlich, Constantin-Gabriel Daniliuc, Shohei Saito, Shigehiro Yamaguchi, Ernst-Ulrich Wurthwein
The synthesis and photophysical properties in solution and in the solid state of novel sterically crowded 1,3,5-triazapentadiene-boron complexes are described. The absorbance properties are interpreted on the basis of DFT calculations.
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Spin-state Transition in Unstrained & Strained Ultra-thin BiCoO$_3$ Films

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT00025D, PaperTilak Das, Tanusri Saha-Dasgupta
Using first principles density functional theory (DFT) based calculations supplemented with Hubbard U term (DFT+U), we theoretically study the structural, electronic and magnetic properties of ultra-thin films of perovskite compound...
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Cationic, luminescent cyclometalated iridium(III) complexes based on substituted 2-phenylthiazole ligands

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8488-8496
DOI: 10.1039/C4DT03054K, PaperEmily C. Stokes, Emily E. Langdon-Jones, Lara M. Groves, James A. Platts, Peter N. Horton, Ian A. Fallis, Simon J. Coles, Simon J. A. Pope
Ten cationic heteroleptic iridium(III) complexes involving substituted phenylthiazole ligands reveal phosphorescence emission in solution.
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Application of three-coordinate copper(I) complexes with halide ligands in organic light-emitting diodes that exhibit delayed fluorescence

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8369-8378
DOI: 10.1039/C4DT02853H, PaperMasahisa Osawa, Mikio Hoshino, Masashi Hashimoto, Isao Kawata, Satoshi Igawa, Masataka Yashima
Conventional bottom-emitting devices with three-layered structures containing sublimable three-coordinate copper(I) complexes produce bright green luminescence with maximum external quantum efficiencies (EQE) of 18.6-22.5%.
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Blue phosphorescent N-heterocyclic carbene chelated Pt(II) complexes with an [small alpha]-duryl-[small beta]-diketonato ancillary ligand

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8433-8443
DOI: 10.1039/C4DT03085K, PaperSoo-Byung Ko, Hee-Jun Park, Shaolong Gong, Xiang Wang, Zheng-Hong Lu, Suning Wang
Blue phosphorescent Pt(II) complexes that display bright blue emission in the solid state have been obtained employing NHC-based C[logical and]C*-chelate ligands and an [small alpha]-duryl-[small beta]-diketonato ancillary ligand that provides steric blocking to minimize intermolecular interactions.
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Luminescent Re(I) terpyridine complexes for OLEDs: what does the DFT/TD-DFT probe reveal?

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8529-8542
DOI: 10.1039/C4DT02917H, PaperGunasekaran Velmurugan, Ponnambalam Venuvanalingam
The electronic structure and spectroscopic properties of a series of rhenium(I) terpyridine complexes were investigated using density functional theory (DFT) and time dependent density functional theory (TD-DFT) methods.
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A new class of luminescent Cu(I) complexes with tripodal ligands - TADF emitters for the yellow to red color range

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8506-8520
DOI: 10.1039/C4DT02631D, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Timo Gneu[German sz ligature}, Markus J. Leitl, Lars H. Finger, Nicholas Rau, Hartmut Yersin, Jorg Sundermeyer
A new class of emissive and neutral Cu(I) compounds with tripodal ligands is presented. The complexes were characterized chemically, computationally, and photophysically.
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Improving the carrier balance of light-emitting electrochemical cells based on ionic transition metal complexes

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8330-8345
DOI: 10.1039/C4DT01675K, PerspectiveHai-Ching Su, Jia-Hong Hsu
Improved carrier balance of a light-emitting electrochemical cell reduces exciton quenching near the doped layers, rendering a higher device efficiency.
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Emission energy of azole-based ionic iridium(III) complexes: a theoretical study

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8497-8505
DOI: 10.1039/C4DT03046J, PaperPaula Pla, Jose M. Junquera-Hernandez, Henk J. Bolink, Enrique Orti
Tuning the emission color of azole-based iridium(III) complexes by changing the number and position of nitrogen atoms in the azole ring.
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A new insight into the chemistry of iridium(III) complexes bearing phenyl phenylphosphonite cyclometalate and chelating pyridyl triazolate: the excited-state proton transfer tautomerism via an inter-ligand PO-HN hydrogen bond

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8406-8418
DOI: 10.1039/C4DT02922D, PaperCheng-Huei Lin, Jia-Ling Liao, Yu-Sin Wu, Kuan-Yu Liao, Yun Chi, Chi-Lin Chen, Gene-Hsiang Lee, Pi-Tai Chou
Ir(pdpit)(pppo)(bptz) complex (3) reveals a PO-H-N inter- ligand H-bond from which proton transfer takes place.
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FIrpic: archetypal blue phosphorescent emitter for electroluminescence

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8318-8329
DOI: 10.1039/C4DT02991G, PerspectiveEtienne Baranoff, Basile F. E. Curchod
FIrpic is the most investigated bis-cyclometallated iridium complex. This Perspective reviews the main experimental and theoretical aspects of FIrpic as well as its use as sky-blue emitter for OLED.
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Tetraphenylborate versus tetraimidazolylborate as counterions for cationic iridium(III) complexes: enhanced electrochemical stabilities and electroluminescence

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8521-8528
DOI: 10.1039/C4DT02830A, PaperDongxin Ma, Lian Duan, Yong Qiu
Tetraimidazolylborate is first used as the counterion of cationic iridium complexes to improve both electrochemical stabilities and device performance.
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A heterotrimetallic Ir(III), Au(III) and Pt(II) complex incorporating cyclometallating bi- and tridentate ligands: simultaneous emission from different luminescent metal centres leads to broad-band light emission

Dalton Transactions - 4 May, 2015 - 22:54

Dalton Trans., 2015, 44,8394-8405
DOI: 10.1039/C4DT02761B, PaperRebeca Munoz-Rodriguez, Elena Bunuel, Noelia Fuentes, J. A. Gareth Williams, Diego J. Cardenas
Di- and tri-nuclear metal complexes incorporating Au(III), Ir(III) and Pt(II) units linked via a 1,3,5-triethynylbenzene core.
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Recent advances in transition metal-catalyzed C-H bond functionalization of ferrocene derivatives

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01373A, PerspectiveLuis A. Lopez, Enol Lopez
Transition metal-catalyzed C-H bond functionalizations of ferrocene derivatives have emerged in the last few years as a versatile tool in synthetic organometallic chemistry. These protocols offer significant advantages over more...
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Direct-synthesis method towards copper-containing Periodic Mesoporous Organosilicas: detailed investigation of the copper distribution in the material

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C4DT03719G, PaperFeng Lin, Xiangyan Meng, Elena Kukueva, Thomas Altantzis, Myrjam Mertens, Sara Bals, Pegie Cool, Sabine Van Doorslaer
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Synthesis and characterization of group 4 metal alkoxide complexes containing imine based bis-bidentate ligands: Effective catalysts for the ring opening polymerization of lactides, epoxides and polymerization of ethylene

Dalton Transactions - 4 May, 2015 - 22:54
Dalton Trans., 2015, Accepted Manuscript
DOI: 10.1039/C5DT01092F, PaperDebashis Chakraborty, Sagnik Kumar Roymuhury, Ramkumar V
A series of Ti(IV), Zr(IV) and Hf(IV) complexes containing imine based bis-bidentate ligands were synthesized and characterized by various spectroscopic techniques, elemental analysis and X-ray crystallography. The ligands m-xysal-(tBu)4 (L1(tBu)4),...
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