Royal Society of Chemistry

Copper(I)-assisted red-shifted phosphorescence in Au(I)Cu(I) heteropolynuclear complexes

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02154A, PaperVincent J. Catalano, Jose M. Lopez-de-Luzuriaga, Miguel Monge, M. Elena Olmos, David Pascual
The introduction of a copper(I) center into a gold(I) precursor with P,N-donor ligands leads to a large red-shift of the emissions in the solid state. Theoretical calculations reveal the nature of the emissive states.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl5 and carboxylic acids: a crystallographic, spectroscopic and computational study

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02201G, PaperMarco Bortoluzzi, Fabio Marchetti, Guido Pampaloni, Stefano Zacchini
The reactivity of MoCl5 with carboxylic acids has been elucidated for the first time. The reactions are featured by the chlorinating behaviour of MoCl5, rather than affording the respective carboxylato complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Stoichiometric reductions of alkyl-substituted ketones and aldehydes to borinic esters

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02648A, CommunicationLauren E. Longobardi, Connie Tang, Douglas W. Stephan
A series of alkyl-substituted ketones are shown to activate hydrogen in the presence of B(C6F5)3, affording the corresponding borinic esters RR[prime or minute]CHOB(C6F5)2.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Dual inhibition of topoisomerases I and II by ruthenium(II) complexes containing asymmetric tridentate ligands

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02142H, PaperKejie Du, Jiewen Liang, Yi Wang, Junfeng Kou, Chen Qian, Liang-Nian Ji, Hui Chao
Five novel ruthenium(II) complexes, [Ru(dtzp)(dppt)]2+ (1), [Ru(dtzp)(pti)]2+ (2), [Ru(dtzp)(ptn)]2+ (3), [Ru(dtzp)(pta)]2+ (4) and [Ru(dtzp)(ptp)]2+ (5) (where dtzp = 2,6-di(thiazol-2-yl)pyridine, dppt = 3-(1,10-phenanthroline-2-yl)-5,6-diphenyl-as-triazine), pti = 3-(1,10-phenanthroline-2-yl)-as-triazino-[5,6-f]isatin, ptn = 3-(1,10-phenanthroline-2-yl)-as-triazino[5,6-f]naphthalene, pta =...
The content of this RSS Feed (c) The Royal Society of Chemistry

Superparamagnetic carbon nanotubes (SWNTs) immobilized pincer Pt and Pd complexes synthesis: highly active and selective catalysts for cyclohexane O2 oxidation

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02099E, PaperGOPAL Mishra, Shinzo Suzuki, Kelly Machado, Jaya Mishra
Single-walled carbon nanotubes (SWNTs) with Ni/Co have prepared by arc discharge technique using Ni/Co carbon composite rod in inert atmosphere and surface modified by the 3-aminophenyl trimethoxysilane. These NH2-functionalized magnetic...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, Structures, and Norbornene Polymerization Behavior of C(sp3), N-Chelated Palladacycles Bearing o-Aryloxide-N-Heterocyclic Carbene Ligands

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02198C, PaperLiang Dang, Jing Guo, Haibin Song, Binyuan Liu, Baiquan Wang
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
The content of this RSS Feed (c) The Royal Society of Chemistry

Temperature Dependent Iodide Oxidation by MLCT Excited States

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01683A, PaperAtefeh Taheri, Gerald John Meyer
The metal-to-ligand charge transfer (MLCT) excited states of two related heteroleptic Ru(II) compounds [Ru(bpy)2(deeb)]2+and [Ru(bpy)2(deebq)]2+, where bpy is 2,2'-bipyridine, deeb is 4,4'-(CO2CH2CH3)2-2,2'-bipyridine and deebq is 4,4'-(CO2CH2CH3)2-2,2'-biquinoline, were characterized in fluid...
The content of this RSS Feed (c) The Royal Society of Chemistry

Ultrasmall NHC-coated gold nanoparticles obtained through solvent free thermolysis of organometallic Au(I) complexes

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02160F, CommunicationJulian Crespo, Yannick Guari, Alfonso Ibarra, Joulia Larionova, Tania Lasanta, Danielle Laurencin, Jose M. Lopez-de-Luzuriaga, Miguel Monge, M. Elena Olmos, Sebastien Richeter
Thermolysis of gold(I) complexes bearing pentafluorophenyl and N-heterocyclic carbene ligands with long alkyl chains affords NHC-stabilized ultrasmall Au nanoparticles.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Novel layered crystalline organic polymer-inorganic hybrid material comprising calcium phosphate with unique architectures for superior performance catalyst support

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01374C, PaperJing Huang, Mei Tang, Xin Li, Guo-Zhen Zhong, Chang Ming Li
A organic copolymer-inorganic hybrid material, calcium phosphonate-phosphate (CaPS-PVPA) was fabricated under mild conditions. In particular, CaPS-PVPA was not prepared with traditional methods such as a hydrothermal one, but with amorphous...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, Structures, and Reactivity of the Base-Stabilized Silanone Molybdenum Complexes

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02159B, CommunicationTakako Muraoka, Keisuke Abe, Haruhiko Kimura, Youhei Haga, Keiji Ueno, Yusuke Sunada
Base-stabilized silanone molybdenum complexes were synthesized by the oxygenation of the M=Si bond in the silyl(silylene)molybdenum complex with 1 eq of PNO in the presence of Lewis base L. PNO-coordinated...
The content of this RSS Feed (c) The Royal Society of Chemistry

Controlled growth and gas sorption property of IRMOF-3 nano/microcrystals

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02429J, PaperJi-Min Yang, Qing Liu, Yan-Shang Kang, Wei-Yin Sun
IRMOF-3 nano/microcrystals with controllable morphology and size were successfully obtained by simple solvothermal method. The shape evolution of IRMOF-3 crystals from cube, to truncated cube, cuboctahedron, truncated octahedron and finally...
The content of this RSS Feed (c) The Royal Society of Chemistry

Ca-Ca interaction in inverse sandwich Ca-C8H8-Ca

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02282C, PaperNan-nan Liu, Si-meng Gao, yihong ding
The inverse sandwich Ca-C8H8-Ca is predicted to be an open-shell singlet state. Since the C8H8 ligand prevents the spin-up and spin-down electrons of different calcium atoms from forming the Ca-Ca...
The content of this RSS Feed (c) The Royal Society of Chemistry

Characterization of the Extracted Complexes of Trivalent Lanthanides with Purified Cyanex 301 in Comparison with Trivalent Actinide Complexes

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02553A, PaperXihong He, Guoxin Tian, Jing CHEN, Linfeng Rao
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ultrafast Spectroscopy and Structural Characterization of a Photochromic Isomerizing Ruthenium Bissulfoxide Complex

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01402B, PaperAlbert King, Jason Malizia, James Engle, Christopher Ziegler, Jeffrey Rack
Irradiation of [Ru(bpy)2(bpSOp)](PF6)2 (where bpy is 2,2'-bipyridine and bpSOp is 1,3-bis(phenylsulfinyl)propane) results in the formation of two new isomers, namely the S,O- and O,O-bonded species. The crystal structure of the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Titanium imido complexes stabilised by bis(iminophosphoranyl)methanide ligands: the influence of N-substituents on solution dynamics and reactivity

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, 43,15098-15110
DOI: 10.1039/C4DT00746H, PaperAdrien T. Normand, Alexandre Massard, Philippe Richard, Coline Canovas, Cedric Balan, Michel Picquet, Audrey Auffrant, Pierre Le Gendre
The synthesis, structural study and assessment in catalytic hydroamination of Ti imido complexes with bis(iminophosphoranyl)methanide ligands are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

TOF-SIMS characterization of impurity enrichment and redistribution in solid oxide electrolysis cells during operation

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, 43,14949-14958
DOI: 10.1039/C4DT01053A, PaperRagnar Kiebach, Kion Norrman, Christodoulos Chatzichristodoulou, Ming Chen, Xiufu Sun, Sune D. Ebbesen, Mogens B. Mogensen, Peter Vang Hendriksen
TOF-SIMS was used to investigate the enrichment and redistribution of impurities in solid oxide cells during operation.
The content of this RSS Feed (c) The Royal Society of Chemistry

Photoreduction and light-induced triplet-state formation in a single-site fluoroalkylated zinc phthalocyanine

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, 43,14942-14948
DOI: 10.1039/C4DT00621F, PaperHans Moons, Andrei Loas, Sergiu M. Gorun, Sabine Van Doorslaer
Anaerobic red-light illumination leads to reduction of perfluoroisopropyl-substituted zinc(II) phthalocyanine in ethanol, while low power UV illumination favours the formation of a triplet excited state.
The content of this RSS Feed (c) The Royal Society of Chemistry

Facile Synthesis of CuInGaS2 Quantum Dots Nanoparticles for Bilayer-Sensitized Solar Cells

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02150A, CommunicationJinjin Zhao, Jiangbin Zhang, Wenna Wang, Peng Wang, Feng Li, Deliang Ren, Huayan Si, Xiuguo Sun, Fengqiu Ji, Yanzhong Hao
CuIn0.7Ga0.3S2 Quantum Dots (QDs) with particle size of 2-5 nm were directly synthesised by a vacuum one-pot-nanocasting process and homogeneously anchored on TiO2 nanocrystals (<50nm) for the first time. We...
The content of this RSS Feed (c) The Royal Society of Chemistry

The Influence of NaYF4:Yb,Er Size/Phase on Multimodality of Co-encapsulated Magnetic Photon- Upconverting Polymeric Nanoparticles

Dalton Transactions - 30 September, 2014 - 15:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01597E, PaperMichael Challenor, Peijun Gong, Dirk Lorenser, Michael House, Robert Woodward, Timothy Guy St Pierre, Melinda Fitzgerald, Sarah Dunlop, David Sampson, Swaminathan Iyer
We report the synthesis, characterisation and evaluation of the in vitro biocompatibility of polymeric nanoparticles with both magnetic and upconverting fluorescent properties. The particles consist of superparamagnetic iron oxide nanoparticles...
The content of this RSS Feed (c) The Royal Society of Chemistry

Analysis of trivalent cation complexation to functionalized mesoporous silica using solid-state NMR spectroscopy

Dalton Transactions - 30 September, 2014 - 15:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02380C, PaperJennifer Shusterman, Harris Mason, Anthony Bruchet, Mavrik Zavarin, Annie B. Kersting, Heino Nitsche
The first comprehensive study of Al(III) and Sc(III) interactions with a novel hybrid material, N-[5-(trimethoxysilyl)-2-aza-1-oxopentyl]caprolactam functionalized mesoporous silica, was conducted using solid-state NMR spectroscopy.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.