Royal Society of Chemistry

The Strength of Actinide-Element Bonds from the Quantum Theory of Atoms in Molecules

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02323D, PaperQian-Rui Huang, Jennifer Kingham, Nikolas Kaltsoyannis
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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A flexible zwitterion-ligand based lanthanide metal-organic framework for luminescence sensing of metal ion and small molecules

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02445A, CommunicationRong-Mei Wen, Song-De Han, Guo-Jian Ren, Ze Chang, Yunwu Li, Xian-He Bu
A new lanthanide metal-organic framework has been constructed by using a tripodal flexible zwitterion (H3LBr3) ligand which taking chair-shaped configuration. The luminescence of the compound displays highly selective sensing of...
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Polyoxometalate-based complex with visible-light photochromism as electrocatalyst for generating hydrogen from water

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01685H, PaperYun Gong, Yong Xi Yang, Miao M Zhang, Xiao Lin Gao, Jun Li Yin, Jian Hua Lin
Two polyoxometalate (POM)-based complexes formulated as (HL1)2(Mo8O26)[middle dot]2HL1 [middle dot]11H2O (L1 = 3- (5- (1H -pyrazol -4 -yl) -1H -1,2,4 -triazol -3 -yl) pyridine) (1) and Co2(L2)4[P2MoVI5O23MoII(H2O)2][middle dot]3H2O (L2 = 4-(5-(2H-1,2,4-triazol-3 -yl) -2H...
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Photocatalytic reactivity tuning by heterometal and addenda metal variation in Lindqvist polyoxometalates

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02682A, PaperJohannes Tucher, Stefanie Schlicht, Fabian Kollhoff, Carsten Streb
A systematic study into the effects of metal substitution on the visible-light photocatalytic activity of prototype metal oxide cluster anions is presented. Four isostructural Lindqvist clusters [VxM6-xO19](2+x)- (M = W,...
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Facile tandem Suzuki coupling/transfer hydrogenation reaction by bis-heteroscorpionate Pd-Ru complex

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02465F, CommunicationSrikanta Patra, Niranjan Dehury, Suman Kumar Tripathy, Anupam Sahoo, Niladri Maity
Abstract: Heterodimetallic complex [{(p-cym)RuCl}([small micro]-pz4lut)PdCl2]ClO4 (1) and its homodimetallic analogues {[(PdCl2)2([small micro]-pz4lut)] (2) and [{(p-cym)RuCl}2([small micro]-pz4lut)]Cl2 (3) using bis(pyrazol-1-yl)methane based bis-heteroscorpionate ligand (pz4lut) have been developed. The complexes have been characterised using various...
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Ammonia-mediated, large-scale synthesis of ammonia borane

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02467B, CommunicationP Veeraraghavan Ramachandran, Hitesh Mistry, Ameya S Kulkarni, Pravin D Gagare
A simple, large-scale synthesis of ammonia borane from NaBH4 and (NH4)2SO4 at 0 oC-rt in THF containing 5% NH3 is described. The presence of ammonia is critical for the reaction...
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Thermoelectric properties of the Ca5Al2-xInxSb6 solid solution

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02206H, PaperAlex Zevalkink, Jessica Swallow, Saneyuki Ohno, Umut Aydemir, Sabah Bux, G. Jeffrey Snyder
Zintl phases are attractive for thermoelectric applications due to their complex structures and bonding environments.
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Reversible photochromic switching in a Ru(II) polypyridyl complex

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02430C, Communicationduenpen unjaroen, johan b Kasper, Wesley Browne
Fully reversible photoswitching of the coordination mode of the ligand MeN4Py (1,1-di(pyridin-2-yl)-N,N'-bis(pyridin-2-yl-methyl)-ethan-1-amine) in its ruthenium(II) complex with visible light is reported. Irradiation with visible light results in dissociation of a...
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Lattice water molecules tuned spin-crossover for an iron (Ⅱ) complex with thermal hysteresis

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02587C, PaperYang-Hui Luo, Li-Jing Yang, Qing-Ling Liu, Wei Wang, Yang Ling, Baiwang Sun
A new iron (Ⅱ) complex based on 4,4'-dimethyl-2,2'-bipyridine ligand [Fe(4,4'-dmbpy)3 (ClO4)(SCN)[round bullet, filled]3H2O (1[round bullet, filled]3H2O)] has been prepared and characterized. Structural studies and Hirshfeld surfaces analysis for complex 1[round bullet, filled]3H2O at three different temperatures...
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Discrete and polymeric Cu(II) complexes featuring substituted indazole ligands: Their synthesis and structural chemistry

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02428A, PaperChris Samuel Hawes, Paul Kruger
Reported here are the syntheses of four indazole-based ligands and the structural characterisation of four Cu(II) complexes derived from them. The ligands 1-(2-pyridyl)-1H-indazole, L1, and 2-(2-pyridyl)-2H-indazole, L2, have been characterised...
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Assemblies Of Salen-Type Oxidovanadium(IV) Complexes: Substituent Effects And In Vitro Proteintyrosine Phosphatase Inhibition

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02344G, PaperPiotr Zabierowski, Janusz Szklarzewicz, Ryszard Grybos, Barbara Modryl, Wojciech Nitek
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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A Co(II) Thiocyanato Coordination Polymer with 4-(3-Phenyl-propyl)pyridine: Influence of the co-Ligand on the Magnetic Properties

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02271H, PaperJulia Werner, Michal Rams, Zbigniew Tomkowicz, Christian Nather
Three new coordination compounds of composition Co(NCS)2(4-(3-phenylpropyl)pyridine)4 (1), Co(NCS)2(4-(3-phenylpropyl)pyridine)4(H2O)2 (2) and [Co(NCS)2(4-(3-phenylpropyl)-pyridine)2]n (3) were prepared and investigated. The crystal structures of compounds 1 and 2 consist of discrete complexes, in...
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Spontaneous Resolution of Polyoxometalate-Based Inorganic-Organic Hybrids Driven by Solvent and Common Ion

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT01954G, PaperYongge Wei, Jiangwei Zhang, Zhenlin Zhao, Jin Zhang, Shan She, Yichao Huang
Three single-sided triol functionalized Anderson POMs hybrids have been successfully synthesized. With suitable solvents and the effect driven by common ion synergy, spontaneous resolution of enantiomer occurred upon crystallization and...
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2-(1-Aryliminoethyl)-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridyl iron(II) dichloride: Synthesis, characterization, and the highly active and tunable active species in ethylene polymerization

Dalton Transactions - 18 September, 2014 - 12:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02102A, PaperFang Huang, Qifeng Xing, Tongling Liang, Zygmunt Flisak, Bin Ye, Xinquan Hu, Wenhong Yang, Wen Hua Sun
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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DMSO containing ruthenium(II) hydrazone complexes: in vitro evaluation of biomolecular interaction and anticancer activity

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01032A, PaperM. Alagesan, P. Sathyadevi, P. Krishnamoorthy, N. S. P. Bhuvanesh, N. Dharmaraj
Four new Ru-DMSO complexes of neutral, bidentate hydrazones were synthesized and two of them were characterized by single crystal XRD. All these complexes showed significant interaction with DNA/protein and specificity towards cancer cells without affecting normal cells.
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Probing structural variation and multifunctionality in niobium doped bismuth vanadate materials

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01788A, PaperSameera Saithathul Fathimah, Padala Prabhakar Rao, Vineetha James, Athira K. V. Raj, G. R. Chitradevi, Sandhyakumari Leela
Multifunctional materials in BiV1-xNbxO4 solid solutions display high NIR reflecting brilliant yellow hues with notable MB dye degradation under sunlight.
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Synthesis, crystal structure and optical properties of a naphthylbisimide-Ni complex: a framework on TiO2 for visible light H2 production

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02006E, CommunicationSukhen Bala, Indranil Mondal, Arijit Goswami, Ujjwal Pal, Raju Mondal
Facile synthesis of a stable photoactive pyridine-pyrazole based naphthylbisimide-Ni complex on TiO2 shows remarkably high photocatalytic H2 production with 7886 TON from visible light induced water splitting.
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Selective synthesis of cis- and trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02214A, CommunicationLesley C. Lewis-Alleyne, Bassem S. Bassil, Tobias Bottcher, Gerd-Volker Roschenthaler
NHCMeSiCl4 was used to selectively synthesise cis and trans-[(NHCMe)2PtCl2], as well as [NHCMePt(cod)Cl][NHCMePtCl3], which revealed the first ever N-heterocyclic carbene analogue of the Cossa's salt anion.
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The crystal structure and magnetic properties of a Zintl phase EuIrIn4: the first member of the Eu-Ir-In family

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01620C, PaperSumanta Sarkar, Matthias J. Gutmann, Sebastian C. Peter
EuIrIn4 is the first member of the Eu-Ir-In family to be synthesized by the metal flux method using indium as the active flux. It is the first YNiAl4 type variant of RETX4 with 9th group transition metals and lanthanides.
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pH-dependent assembly of two polyoxometalate host-guest structural isomers based on Keggin polyoxoanion templates

Dalton Transactions - 18 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02050B, PaperLei Zhang, Wenbin Yang, Xiaofei Kuang, Xiaoyuan Wu, Canzhong Lu
Two polyoxometalate-templated supramolecular isomers have been obtained by hydrothermal reactions under different pH values and their photoluminescence properties have been investigated.
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