Royal Society of Chemistry

Formation and structure of two luminescent salts of [Au(SCSN3)2]- obtained through the [2 + 3] cyclization of carbon disulfide and azide ion

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13756-13763
DOI: 10.1039/C4DT01902D, PaperSang Ho Lim, Jennifer C. Schmitt, Jason Shearer, Kellie R. England, Marilyn M. Olmstead, Alan L. Balch
The salts, [(H2O)3Na][Au(SCSN3)2] and (Ph4As)[Au(SCSN3)2] contain anions that associate through aurophilic interactions and adopt an unusual eclipsed arrangement of the ligands as seen in the illustration.
The content of this RSS Feed (c) The Royal Society of Chemistry

A 13C-NMR study of azacryptand complexes

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13557-13562
DOI: 10.1039/C4DT01594K, PaperAljoscha A. C. Wild, Kevin Fennell, Grace G. Morgan, Chandralal M. Hewage, J. Paul G. Malthouse
Two complexes are formed when the azacryptand R3Bm binds a metal and carbonate. These complexes interchange slowly when the metal is cadmium but rapidly when the metal is zinc.
The content of this RSS Feed (c) The Royal Society of Chemistry

Contrasting reactivity behaviour of the [RuHCl(CO)(PNP)] complex with electrophilic reagents XOTf (X = H, CH3, Me3Si)

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01570C, PaperA. Ramaraj, Munirathinam Nethaji, Balaji R. Jagirdar
Reaction of a ruthenium hydride complex bearing a pincer ligand with H+ gave [small eta]2-H2 complex whereas, reaction with CH3+ or Me3Si+ electrophiles resulted in elimination of CH3Cl or Me3SiCl via a SN2 type of reaction. The contrasting reactivity behaviour is due to stereoelectronic features of the ruthenium complex.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Variation of electronic transitions and reduction potentials of cerium(IV) complexes

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01386G, PaperUrsula J. Williams, David Schneider, Walter L. Dorfner, Cacilia Maichle-Mossmer, Patrick J. Carroll, Reiner Anwander, Eric J. Schelter
New cerium(IV) compounds, isolated by the reaction of Ce[N(SiHMe2)2]4 with alcohols and phenols, exhibited variable electronic transitions and reduction potentials.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A binuclear Zn(II)-Zn(II) complex from a 2-hydroxybenzohydrazide-derived Schiff base for selective detection of pyrophosphate

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01799D, PaperJunfeng Wang, Bin Liu, Xiumin Liu, Matthew J. Panzner, Chrys Wesdemiotis, Yi Pang
A hydroxybenzohydrazide Schiff base formed a green fluorescent binuclear Zn(II)-Zn(II) complex in ethanol, which responded to various phosphate anions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Carbene based photochemical molecular assemblies for solar driven hydrogen generation

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13683-13695
DOI: 10.1039/C4DT01546K, PaperKatrin Peuntinger, T. David Pilz, Robert Staehle, Markus Schaub, Simon Kaufhold, Lydia Petermann, Markus Wunderlin, Helmar Gorls, Frank W. Heinemann, Jing Li, Thomas Drewello, Johannes G. Vos, Dirk M. Guldi, Sven Rau
Novel binuclear photocatalysts with bridging ligands on NHC basis have been synthesized, characterized and applied as photocatalysts.
The content of this RSS Feed (c) The Royal Society of Chemistry

Exfoliation of one-dimensional TiO5 chain in K2TiO3

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13751-13755
DOI: 10.1039/C4DT01891E, PaperYuji Masubuchi, Ryo Miyazaki, Hiroki Kikuchi, Teruki Motohashi, Shinichi Kikkawa
Potassium titanate, K2TiO3, was exfoliated in acid solution, and Tyndall scattering due to the colloid formation was observed.
The content of this RSS Feed (c) The Royal Society of Chemistry

Bamboo leaf-assisted formation of carbon/nitrogen co-doped anatase TiO2 modified with silver and graphitic carbon nitride: novel and green synthesis and cooperative photocatalytic activity

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13792-13802
DOI: 10.1039/C4DT02101K, PaperZhifeng Jiang, Dong Liu, Deli Jiang, Wei Wei, Kun Qian, Min Chen, Jimin Xie
We have hybridized a ternary system (Ag/CN-TiO2@g-C3N4) via a facile, low-cost, one-step synthesis strategy for the first time without using chemical reagents as C/N sources or employing a toxic reducing agent.
The content of this RSS Feed (c) The Royal Society of Chemistry

In situ synthesis of uniform Fe2O3/BiOCl p/n heterojunctions and improved photodegradation properties for mixture dyes

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13742-13750
DOI: 10.1039/C4DT01999G, PaperNa Li, Xia Hua, Kai Wang, Yujian Jin, Jingjing Xu, Mindong Chen, Fei Teng
Uniform Fe2O3/BiOCl p/n heterojunctions are synthesized by an in situ hydrolysis method, whose degradation rates are four times higher than that of the bare BiOCl.
The content of this RSS Feed (c) The Royal Society of Chemistry

2-Quinoxalinol diamine Cu(II) complex: facilitating catalytic oxidation through dual mechanisms

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13578-13583
DOI: 10.1039/C4DT01562B, PaperYuancheng Li, TaeBum Lee, Kushan Weerasiri, Tanyu Wang, Emily E. Buss, Michael L. McKee, Anne E. V. Gorden
The Cu(II) complex 1, Cu(II)-6-N-3,5-di-tert-butylsalicylidene-6,7-quinoxalinol-diamine, has been developed to address problems with current methods of catalytic oxidation using tert-butyl hydroperoxide (TBHP).
The content of this RSS Feed (c) The Royal Society of Chemistry

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4([small mu ]2-OH)3} building block based metal organic framework through a dinuclear complex

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02045F, CommunicationXin-Ming Wang, Rui-Qing Fan, Liang-Sheng Qiang, Ping Wang, Yu-Lin Yang, Yu-Lei Wang
A rare 3D tetranuclear {In4([small mu ]2-OH)3} building block based MOF {[In4/3([small mu ]2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)][middle dot]2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1).
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Cationic iridium(III) complexes bearing ancillary 2,5-dipyridyl(pyrazine) (2,5-dpp) and 2,2[prime or minute]:5[prime or minute],2[prime or minute][prime or minute]-terpyridine (2,5-tpy) ligands: synthesis, optoelectronic characterization and light-emittin

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13672-13682
DOI: 10.1039/C4DT02100B, PaperKamrul Hasan, Loic Donato, Yulong Shen, Jason D. Slinker, Eli Zysman-Colman
Four green to deep red emitting cationic iridium(III) complexes are reported as emitters for LEECs.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ethyleneglycol tungsten complexes of calix[6 and 8]arenes: synthesis, characterization and ROP of [varepsilon]-caprolactone

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13612-13619
DOI: 10.1039/C4DT01936A, PaperYuanzhuo Li, Ke-Qing Zhao, Chun Feng, Mark R. J. Elsegood, Timothy J. Prior, Xinsen Sun, Carl Redshaw
Ethylene glycolate tungsten complexes bearing calix[n]arene ligands (n = 6, 8) have been structurally characterized and exhibit catalytic activity for the ROP of [varepsilon]-caprolactone in the presence of benzyl alcohol.
The content of this RSS Feed (c) The Royal Society of Chemistry

Experimental determination of redox cooperativity and electronic structures in catalytically active Cu-Fe and Zn-Fe heterobimetallic complexes

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13661-13671
DOI: 10.1039/C4DT01841A, PaperMalkanthi K. Karunananda, Francisco X. Vazquez, E. Ercan Alp, Wenli Bi, Soma Chattopadhyay, Tomohiro Shibata, Neal P. Mankad
Mossbauer and XANES analyses were used to examine metal-metal bonding and redox cooperativity in catalytically active Cu-Fe and Zn-Fe complexes.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and structural investigation of R2Si (R = Me, Ph) bridged di-N-heterocyclic carbenes

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13704-13710
DOI: 10.1039/C4DT01681E, PaperRajendra S. Ghadwal, Sven O. Reichmann, Elena Carl, Regine Herbst-Irmer
Silyl-functionalized di-N-heterocyclic carbenes are readily available on treatment of a lithiated NHC with a dichlorosilane. A copper complex of a Di-NHC is shown.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ruthenium, osmium and rhodium complexes of 1,4-diaryl 1,4-diazabutadiene: radical versus non-radical states

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13731-13741
DOI: 10.1039/C4DT01241K, PaperSarat Chandra Patra, Amit Saha Roy, Vadivelu Manivannan, Thomas Weyhermuller, Prasanta Ghosh
Molecular and electronic structures of the ruthenium, osmium and rhodium complexes of 1,4-di(3-nitrophenyl)-1,4-diazabutadiene (LDAB) and their redox series are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Multi-component assembly and luminescence tuning of lanthanide hybrids based with both zeolite L/A and SBA-15 through two organically grafted linkers

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01169D, PaperLei Chen, Bing Yan
Novel luminescent micro-mesoporous multi-component lanthanide hybrid materials are prepared by assembling both functionalized zeolite A/L and modified SBA-15 through two organically grafted silane linkers.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Structural, magnetic, and electrochemical properties of the high pressure form of Na2Co[PO4]F

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13630-13636
DOI: 10.1039/C4DT01418A, PaperHamdi Ben Yahia, Daisuke Mori, Masahiro Shikano, Hironori Kobayashi, Yoshiyuki Inaguma
The high pressure form of Na2Co[PO4]F.
The content of this RSS Feed (c) The Royal Society of Chemistry

Syntheses, characterization, and structural studies of copper(I) complexes containing 1,1[prime or minute]-bis(di-tert-butylphosphino)ferrocene (dtbpf) and their application in palladium-catalyzed Sonogashira coupling of aryl halides

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, 43,13620-13629
DOI: 10.1039/C4DT01411A, PaperManoj Trivedi, Gurmeet Singh, Abhinav Kumar, Nigam P. Rath
The syntheses and characterization of halo- and cyano-bridged copper(I) complexes are reported.
The content of this RSS Feed (c) The Royal Society of Chemistry

Boron-centered soft ligands based on tetrazole units and their complexes with sodium, potassium and bismuth ions

Dalton Transactions - 29 min 16 sec ago

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01931H, PaperMuhammad Imran, Andreas Mix, Beate Neumann, Hans-Georg Stammler, Uwe Monkowius, Petra Bleckenwegner, Norbert W. Mitzel
Syntheses of sodium and potassium tetrazolylborate salts based on 1-methyl-5-thiotetrazole and 1-phenyl-5-thiotetrazole are described and used as precursors for corresponding bismuth(III) and bismuth(II) complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.