Royal Society of Chemistry

In search for new bonding modes of the methylenedithiolato ligand: novel tri- and tetra-metallic clusters

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00179J, PaperR. S. Anju, Koushik Saha, Bijan Mondal, Thierry Roisnel, Jean-Francois Halet, Sundargopal Ghosh
Photolysis of arachno-[(Cp*Ru)2(B3H8)(CS2H)] in the presence of [Re2(CO)10] produced [(Cp*Ru)2B3H5(CH2S2){Re(CO)4}2], with a planar 8-membered ring containing heavier transition metals and a main group element.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A series of lanthanoid selenidoantimonates(V): rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00146C, PaperHong-Ping Xiao, Jian Zhou, Rong-Qing Zhao, Wei-bing Zhang, Yong Huang
This work provides rare examples of lanthanoid selenidoantimonates based on dinuclear lanthanide complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A panchromatic hybrid crystal of iodoplumbate nanowires and J-aggregated naphthalene diimides with long-lived charge-separated states

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03785E, CommunicationJian-Jun Liu, Ying-Fang Guan, Chen Jiao, Mei-Jin Lin, Chang-Cang Huang, Wen-Xin Dai
A panchromatic hybrid crystal of anionic iodoplumbate nanowires and J-aggregated protonated naphthalene diimides has been formed through charge-assisted anion-[small pi] and lone pair-[small pi] interactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

O,N,N-Pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00062A, PaperLuka A. Wright, Eric G. Hope, Gregory A. Solan, Warren B. Cross, Kuldip Singh
The structural properties of a series of ONN-Pd(II) chloride pincer complexes have been shown to influence the conversion to 4-chlorotoluene upon oxidation with di-p-tolyliodonium triflate.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Tetraphenolate niobium and tantalum complexes for the ring opening polymerization of [varepsilon]-caprolactone

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00272A, PaperYahya Al-Khafaji, Xinsen Sun, Timothy J. Prior, Mark R. J. Elsegood, Carl Redshaw
Reaction of the pro-ligands [small alpha],[small alpha],[small alpha][prime or minute],[small alpha][prime or minute]-tetra(3,5-di-tert-butyl-2-hydroxyphenyl-p-(or -m-)xylene-para-(or -meta-)tetraphenol with [MCl5] (M = Nb, Ta) or [Nb(O)Cl3(NCMe)2] afforded complexes capable of the ROP of e-caprolactone at high temperature.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Heterobimetallic metallation studies of N,N-dimethylphenylethylamine (DMPEA): benzylic C-H bond cleavage/dimethylamino capture or intact DMPEA complex

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00247H, PaperAlan R. Kennedy, Robert E. Mulvey, Donna L. Ramsay, Stuart D. Robertson
The cleave and capture capacity of various bimetallic amido-alkyl mixtures is illustrated through reaction with the deprotonation sensitive N,N-dimethylphenylethylamine.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

New quaternary arsenide oxides with square planar coordination of gold(I) - structure, 197Au Mossbauer spectroscopic, XANES and XPS characterization of Nd10Au3As8O10 and Sm10Au3As8O10

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00193E, PaperTimo Bartsch, Oliver Niehaus, Dirk Johrendt, Yasuhiro Kobayashi, Makoto Seto, Paula M. Abdala, Manfred Bartsch, Helmut Zacharias, Rolf-Dieter Hoffmann, Birgit Gerke, Ute Ch. Rodewald, Rainer Pottgen
The title compounds were synthesised and characterised.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ethylene polymerisation and ethylene/norbornene copolymerisation by using aryloxo-modified vanadium(V) complexes containing 2,6-difluoro-, dichloro-phenylimido complexes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT04026K, PaperNichabhat Diteepeng, Xiaoyan Tang, Xiaohua Hou, Yue-Sheng Li, Khamphee Phomphrai, Kotohiro Nomura
V(N-2,6-X2C6H3)Cl2(O-2,6-R2C6H3) (X = Cl, F; R = Me, F) showed remarkable activity in ethylene polymerisation and the copolymerisation with norbornene in the presence of Et2AlCl.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Intramolecular N-coordination in ketiminoboranes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00196J, CommunicationCatherine E. Bacon, Liz Mansour, John J. Hayward, Jeremy M. Rawson
Ketiminoboranes, R2C[double bond, length as m-dash]NB-R[prime or minute]2, pioneered by Wade et al., are formally isoelectronic with allenes but undergo intramolecular cyclisation when R = 2-pyridyl to form heterocyclic boranes with N-donor capability.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Thermoelastic and structural properties of ionically conducting cerate perovskites: (II) SrCeO3 between 1273 K and 1723 K

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00041F, PaperKevin S. Knight, Richard Haynes, Nikolaos Bonanos, Feridoon Azough
Thermodynamic gruneisen parameter and bond valence parameters for strontium cerate perovskite.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis of zinc phthalocyanine with large steric hindrance and its photovoltaic performance for dye-sensitized solar cells

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03397C, PaperLi Lin, Bosi Peng, Wenye Shi, Yingying Guo, Renjie Li
An asymmetric zinc phthalocyanine with large steric hindrance (Zn-tri-PcNc-8) shows a best efficiency of 3.01%.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00079C, PaperMelissa Wu. M, Arran M. Gill, Lu Yunpeng, Laura Falivene, Li Yongxin, Rakesh Ganguly, Luigi Cavallo, Felipe Garcia
Treatment of a series of aromatic NHCs with trimethylaluminium produced their corresponding NHC[middle dot]AlMe3 adducts displaying different stabilities. Their stabilities are rationalized using topographic steric maps and NHC % V Bur.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Carboranes in the chemist's toolbox

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00231A, PerspectiveRussell N. Grimes
A carborane-fullerene dyad for organic field-effect transistors illustrates one of the many diverse areas of technology in which the special properties of these polyhedral boron clusters are being exploited.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Chirality detection of two enantiomorphic 3D lanthanide coordination polymers by vibrational circular dichroism spectra

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00404G, CommunicationXiu-Ying Zheng, Han Zhang, Ling-Yun Cao, Xiang-Jian Kong, La-Sheng Long, Lan-Sun Zheng
Two enantiomorphic 3D lanthanide coordination polymers with chiral helical chains were synthesized based on an achiral ligand. The absolute configurations of the two structures were evidenced by the observation of strong signals in vibrational circular dichroism (VCD) spectra.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Chiral crystallization and optical properties of three metal complexes based on two non-centrosymmetric tripodal ligands

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00292C, PaperMing-Dao Zhang, Zhi-Qiang Shi, Min-Dong Chen, He-Gen Zheng
Three chiral coordination polymers 1-3 with novel architectures were constructed by asymmetric induction. Complex 3 can satisfy the fundamental requirement of second-order nonlinear optical material.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

A facile room temperature iodination route to in situ fabrication of patterned copper-iodide/silicon quasi-bulk-heterojunction thin films for photovoltaic application

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03762F, PaperLei Zhang, Yan Lei, Xiaogang Yang, Jiamei Cheng, Chengxiang Wang, Huimin Jia, Zhi Zheng
A facile room temperature iodination approach is developed to in-situ fabrication of monocrystalline CuI/Si quasi-bulk-heterojunction thin films by firstly depositing an elemental copper layer on pyramidally patterned silicon surface followed by a direct elemental reaction with iodine vapour.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Macrocyclic dinuclear, helical, layered and 3-D Ag(I) complexes constructed from AgX (X = NO3- and ClO4-) and flexible bis(pyridyl) ligands with a chelating spacer: syntheses, structures and photoluminescence properties

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00265F, PaperJing Huang, Zhao-Peng Deng, Ying-Hui Xiao, Li-Hua Huo, Shu-Nan Zhao, Fa-Yuan Ge, Shan Gao
Eight novel Ag(I)-bis(pyridyl) complexes with diverse structures have been synthesized.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Fixation of atmospheric carbon dioxide by ruthenium complexes bearing an NHC-based pincer ligand: formation of a methylcarbonato complex and its methylation

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00476D, CommunicationYasuhiro Arikawa, Takuo Nakamura, Shinji Ogushi, Kazushige Eguchi, Keisuke Umakoshi
Capture of CO2 from air gave a methylcarbonato ruthenium complex, which was reacted with methylating reagents to release dimethylcarbonate.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Electron transfer and catalysis with high-valent metal-oxo complexes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C5DT00204D, PerspectiveShunichi Fukuzumi
High-valent metal-oxo complexes are produced by thermal and photoinduced electron-transfer reactions, acting as catalysts for oxygenation of substrates using water or dioxygen as an oxygen source.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Influence of the ligand frameworks on the coordination environment and properties of new phenylmercury(II) [small beta]-oxodithioester complexes

Dalton Transactions - 15 hours 14 min ago

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03816A, PaperGunjan Rajput, Manoj Kumar Yadav, Michael G. B. Drew, Nanhai Singh
New luminescent PhHg(II) dithioester complexes 1-3 have been synthesized and their crystal structures revealed O,S-coordination in 1 and 2 whereas less preferred S,S-coordination is observed in 3. The keto-form of [small beta]-oxodithioester ligands is stabilized in these complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.