Royal Society of Chemistry

Selective synthesis of cis- and trans-[(NHCMe)2PtCl2] and [NHCMePt(cod)Cl][NHCMePtCl3] using NHCMeSiCl4

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02214A, CommunicationLesley C. Lewis-Alleyne, Bassem S. Bassil, Tobias Bottcher, Gerd-Volker Roschenthaler
NHCMeSiCl4 was used to selectively synthesise cis and trans-[(NHCMe)2PtCl2], as well as [NHCMePt(cod)Cl][NHCMePtCl3], which revealed the first ever N-heterocyclic carbene analogue of the Cossa's salt anion.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Structural diversity and magnetic properties of six metal-organic polymers based on semirigid tricarboxylate ligand of 3,5-bi(4-carboxyphenoxy)benzoic acid

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01953A, PaperLiming Fan, Weiliu Fan, Weikuo Song, Liming Sun, Xian Zhao, Xiutang Zhang
Six new metal-organic complexes with structural diversities constructed from 3,5-bi(4-carboxyphenoxy)benzoic acid and metal ions were synthesized and characterized.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

The crystal structure and magnetic properties of a Zintl phase EuIrIn4: the first member of the Eu-Ir-In family

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01620C, PaperSumanta Sarkar, Matthias J. Gutmann, Sebastian C. Peter
EuIrIn4 is the first member of the Eu-Ir-In family to be synthesized by the metal flux method using indium as the active flux. It is the first YNiAl4 type variant of RETX4 with 9th group transition metals and lanthanides.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Probing the photophysical capability of mono and bis(cyclometallated) Fe(II) polypyridine complexes using inexpensive ground state DFT

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01939C, PaperI. M. Dixon, S. Khan, F. Alary, M. Boggio-Pasqua, J.-L. Heully
Inexpensive ground state DFT calculations allow the computational design of photophysically promising FeN4C2 complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Coordination chemistry of Co complexes containing tridentate SNS ligands and their application as catalysts for the oxidation of n-octane

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01750A, PaperLynette Soobramoney, Muhammad D. Bala, Holger B. Friedrich
Fully characterized cobalt complexes of tridentate SNS ligands were selective (up to 90%) for the oxidation of n-octane to octanones.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Multifunctional mesoporous hollow silica nanocapsules for targeted co-delivery of cisplatin-pemetrexed and MR imaging

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02144D, PaperSasmita Mohapatra, Smruti Ranjan Rout, Rajan Narayan, Tapas K. Maiti
Theranostic hollow mesoporous silica nanocapsules for simultaneous loading of anticancer drugs cisplatin and pemetrexed with individual releasing property have been developed.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Anion-controlled formation of an aminal-(bis)imine Fe(II)-complex

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT02180K, CommunicationChandan Giri, Filip Topic, Prasenjit Mal, Kari Rissanen
The subcomponent self-assembly of 1,2-diaminobenzene and 2-formylpyridine with iron(II) salts yields an unprecedented complex containing both the aminal and imine groups and can be controlled by the choice of counter-anion.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Structure and photoluminescence of silver(I) trinuclear halopyrazolato complexes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01978D, PaperYui Morishima, David James Young, Kiyoshi Fujisawa
Luminescent silver(I) complexes of substituted halopyrazolate anions are either dimeric trinuclear or trinuclear structures held together with weak interactions.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Expanded ring N-heterocyclic carbene adducts of group 15 element trichlorides: synthesis and reduction studies

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14858-14864
DOI: 10.1039/C4DT02074J, PaperAnastas Sidiropoulos, Brooke Osborne, Alexandr N. Simonov, Deepak Dange, Alan M. Bond, Andreas Stasch, Cameron Jones
Adducts of an expanded ring N-heterocyclic carbene (6-Dip) with ECl3 (E = P, As or Sb) have been prepared, and the reduction of one, [(6-Dip)PCl3], is shown to give an unusual tetraphosphorus dicationic complex.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, novel luminescence properties, and surface-enhanced Raman scattering of Au/Y2O3:Eu3+ composite nanotubes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14720-14725
DOI: 10.1039/C4DT01973C, PaperJiamin Su, Guofeng Wang, Ying Li, Rong Li, Bingyu Xu, Yuping Wang, Jisen Zhang
Au/Y2O3:Eu3+ composite nanotubes were synthesized by a hydrothermal method. Novel luminescence properties were observed in Y2O3:Eu3+ nanotubes by composing with Au particles. The effects of the Au content on the photoluminescence of the Au/Y2O3:Eu3+ were investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Multifunctional MOFs through CO2 fixation: a metamagnetic kagome lattice with uniaxial zero thermal expansion and reversible guest sorption

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14766-14771
DOI: 10.1039/C4DT02205J, PaperTony D. Keene, Michael J. Murphy, Jason R. Price, Natasha F. Sciortino, Peter D. Southon, Cameron J. Kepert
The properties of atmospheric CO2 fixation, metamagnetism, reversible guest adsorption and zero thermal expansion have been combined in a single robust MOF, [Cu3(bpac)3(CO3)2](ClO4)2[middle dot]H2O (1[middle dot]H2O).
The content of this RSS Feed (c) The Royal Society of Chemistry

Variation of guest selectivity within [Fe4L4]8+ tetrahedral cages through subtle modification of the face-capping ligand

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14550-14553
DOI: 10.1039/C4DT02337D, CommunicationAlan Ferguson, Robert W. Staniland, Christopher M. Fitchett, Marie A. Squire, Bryce E. Williamson, Paul E. Kruger
We report here the host-guest behaviour of two isoelectronic [Fe4L4]8+ tetrahedral cages that differ only in the nature of their face-capping ligand and possess either triazine (L1) or benzene (L2) cores.
The content of this RSS Feed (c) The Royal Society of Chemistry

Ruthenium(II) complexes of N-heterocyclic carbenes derived from imidazolium-linked cyclophanes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14710-14719
DOI: 10.1039/C4DT01473A, PaperGiovanni F. Caramori, Leone C. Garcia, Diego M. Andrada, Gernot Frenking
Metal-ligand bonds in ruthenium(II) complexes of N-heterocyclic carbenes derived from imidazolium-linked cyclophanes with a remarkable covalent character are shown.
The content of this RSS Feed (c) The Royal Society of Chemistry

C-H bond activation and S-atom transfer from cobalt(III) thiolate and isothiocyanate complexes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14696-14700
DOI: 10.1039/C4DT01823K, PaperHongwei Xu, Paul G. Williard, Wesley H. Bernskoetter
The anionic ligand of cis,mer-(PMe3)3Co(CH3)2X controls competitive reductive C-C bond elimination, C-H bond cyclometallation, and S-atom transfer reactivity.
The content of this RSS Feed (c) The Royal Society of Chemistry

Computational evaluation of tris(carbene)borate donor properties in {NiNO}10 complexes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14689-14695
DOI: 10.1039/C4DT01426J, PaperRuth A. Juarez, Wei-Tsung Lee, Jeremy M. Smith, Haobin Wang
A computational methodology for delineating the donor strength of tripodal ligands has been established, as applied to tris(carbene)borate {NiNO}10 complexes. The accessibility of nickel(IV) nitrides via oxygen atom abstraction is also investigated.
The content of this RSS Feed (c) The Royal Society of Chemistry

Iron(III) complexes of tripodal tetradentate 4N ligands as functional models for catechol dioxygenases: the electronic vs. steric effect on extradiol cleavage

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14653-14668
DOI: 10.1039/C3DT52145A, PaperMani Balamurugan, Prabha Vadivelu, Mallayan Palaniandavar
The extradiol (E) to intradiol (I) product selectivity (E/I, 0.1-2.0) depends upon the asymmetry in bidentate coordination of catecholate, as determined by the stereoelectronic properties of the ligands.
The content of this RSS Feed (c) The Royal Society of Chemistry

Tris(hydroxymethyl)aminomethane modified layered double hydroxides greatly facilitate polyoxometalate intercalation

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14570-14576
DOI: 10.1039/C4DT01827C, PaperYang Chen, Dongpeng Yan, Yu-Fei Song
The Na3[PW12O40] intercalated tris(hydroxymethyl)aminomethane (Tris)-modified LDH is prepared for the first time without the necessity of degassing CO2, resulting in the formation of a new intercalated assembly of Tris-LDH-PW12 under mild conditions.
The content of this RSS Feed (c) The Royal Society of Chemistry

Complex perovskite oxide nanocrystals: low-temperature synthesis and crystal structure

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14499-14513
DOI: 10.1039/C4DT01376J, PerspectiveFederico A. Rabuffetti, Richard L. Brutchey
This Perspective reviews our recent efforts towards the low-temperature synthesis of complex perovskite oxide ABO3 (A = Sr, Ba; B = Ti, Zr) nanocrystals using the vapor diffusion sol-gel method and the determination of their room-temperature crystal structure.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and characterisation of zirconium complexes for cell tracking with Zr-89 by positron emission tomography

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, 43,14851-14857
DOI: 10.1039/C4DT01928H, PaperTrevor J. Ferris, Putthiporn Charoenphun, Levente K. Meszaros, Gregory E. D. Mullen, Philip J. Blower, Michael J. Went
Preparation of Zr(IV) complexes containing monobasic bidentate ligands under radiopharmaceutical conditions has been evaluated. 89Zr(oxinate)4 is the most promising candidate for cell tracking.
The content of this RSS Feed (c) The Royal Society of Chemistry

Metal-mediated coupling of amino acid esters with isocyanides leading to new chiral acyclic aminocarbene complexes

Dalton Transactions - 22 September, 2014 - 12:54

Dalton Trans., 2014, Advance Article
DOI: 10.1039/C4DT01917B, PaperTatyana B. Anisimova, M. Fatima C. Guedes da Silva, Vadim Yu. Kukushkin, Armando J. L. Pombeiro, Konstantin V. Luzyanin
Palladium(II)-mediated coupling of amino acid esters with isocyanides leads to new chiral acyclic aminocarbene complexes.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2011 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.