Royal Society of Chemistry

Synthesis and characterization of the ZnO/mpg-C3N4 heterojunction photocatalyst with enhanced visible light photoactivity

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13105-13114
DOI: 10.1039/C4DT01347F, PaperDaimei Chen, Kewei Wang, Tiezhen Ren, Hao Ding, Yongfa Zhu
The photocatalytic activity enhancement of the ZnO/mpg-C3N4 is due to the high separation and easy transfer of photogenerated electron-hole pairs.
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Facile synthesis of novel MoS2@SnO2 hetero-nanoflowers and enhanced photocatalysis and field-emission properties

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13136-13144
DOI: 10.1039/C4DT01436G, PaperJinzhu Li, Ke Yu, Yinghua Tan, Hao Fu, Qingfeng Zhang, Weitao Cong, Changqing Song, Haihong Yin, Ziqiang Zhu
A novel MoS2@SnO2 hetero-nanoflower was successfully synthesized by a facile hydrothermal method. The composite showed more excellent photocatalytic and field emission properties than that of MoS2.
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Au nanoparticles in carbon nanotubes with high photocatalytic activity for hydrocarbon selective oxidation

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12982-12988
DOI: 10.1039/C4DT01077A, PaperJuan Liu, Ruihua Liu, Haitao Li, Weiqian Kong, Hui Huang, Yang Liu, Zhenhui Kang
High conversion efficiency (14.7%) and high selectivity (86.88% for cyclohexanone) catalytic oxidation of cyclohexane under mild conditions is achieved with Au confined in carbon nanotubes.
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New triethoxysilylated 10-vertex closo-decaborate clusters. Synthesis and controlled immobilization into mesoporous silica

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13087-13095
DOI: 10.1039/C4DT00772G, PaperFatima Abi-Ghaida, Zahra Laila, Ghassan Ibrahim, Daoud Naoufal, Ahmad Mehdi
Triethoxysilylated borate clusters comprising the closo-decaborate cage were synthesized and immobilized into the pores of SBA-15 mesoporous silica.
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Alkaline earth metal-based metal-organic framework: hydrothermal synthesis, X-ray structure and heterogeneously catalyzed Claisen-Schmidt reaction

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13006-13017
DOI: 10.1039/C4DT00575A, PaperDebraj Saha, Tanmoy Maity, Subratanath Koner
Two alkaline earth metal based carboxylate framework systems, [Mg(HL)(H2O)2]n (1) and [Ca(H2L)2]n (2) (H3L = chelidamic acid) have been hydrothermally synthesized and characterized. Both compound 1 and its dehydrated species heterogeneously catalyze Claisen-Schmidt reaction.
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A series of 3D metal organic frameworks based on [24-MC-6] metallacrown clusters: structure, magnetic and luminescence properties

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,12989-12995
DOI: 10.1039/C4DT01593B, PaperKai Wang, Hua-Hong Zou, Zi-Lu Chen, Zhong Zhang, Wei-Yin Sun, Fu-Pei Liang
Four isostructural MOFs based on [24-MC-6] metallacrown cluster SUBs have been reported. They have a (4,6)-connected 3D frameworks and exhibit interesting magnetic and luminescence properties, as well as magnetocaloric effect.
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DNA/protein interaction and cytotoxic activity of imidazole terpyridine derived Cu(II)/Zn(II) metal complexes

Dalton Transactions - 13 August, 2014 - 02:54

Dalton Trans., 2014, 43,13018-13031
DOI: 10.1039/C4DT01378F, PaperV. M. Manikandamathavan, T. Weyhermuller, R. P. Parameswari, M. Sathishkumar, V. Subramanian, Balachandran Unni Nair
Metal centre plays an important role in the mode of DNA binding, cleavage, protein binding and cytotoxicity.
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Asymmetric borylation of [small alpha],[small beta]-unsaturated esters catalyzed by novel ring expanded N-heterocyclic carbenes based on chiral 3,4-dihydro-quinazolinium compounds

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6554-6556
DOI: 10.1039/C4OB01101E, CommunicationLiliang Huang, Yong Cao, Manping Zhao, Zhongfeng Tang, Zhihua Sun
A series of novel ring expanded N-heterocyclic carbene (NHC) precursors were synthesized, which showed excellent enantioselectivities for borylation of [small alpha],[small beta]-unsaturated esters.
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Demonstration of a common indole-based aromatic core in natural and synthetic eumelanins by solid-state NMR

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6730-6736
DOI: 10.1039/C4OB01066C, PaperSubhasish Chatterjee, Rafael Prados-Rosales, Sindy Tan, Boris Itin, Arturo Casadevall, Ruth E. Stark
Comparing natural and synthetic eumelanin pigment structures: high-field 2D solid-state NMR reveals a common indole-based aromatic core for ubiquitous protective pigments that inspire engineered materials.
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N-Bromoacetamide-mediated domino cyclization and elimination of homoallylic trichloroacetimidates: a novel approach toward the synthesis of 1-bromo-2-amino-3-butene derivatives

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6653-6660
DOI: 10.1039/C4OB01126K, PaperRui Zhu, Kai Yu, Zhenhua Gu
Allylic amides 3 were synthesized efficiently from homoallylic trichloroacetimidates 1via domino bromo-cyclization and elimination reactions.
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Novel phthalamides containing sulfiliminyl moieties and derivatives as potential ryanodine receptor modulators

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6643-6652
DOI: 10.1039/C4OB00716F, PaperSha Zhou, Tao Yan, Yuxin Li, Zhehui Jia, Baolei Wang, Yu Zhao, Yuanyuan Qiao, Lixia Xiong, Yongqiang Li, Zhengming Li
The present work firstly reported that the new diamides incorporating sulfiliminyl moieties are potential candidate structures for new ryanodine receptor modulators.
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Enhanced catalysis and enantioselective resolution of racemic naproxen methyl ester by lipase encapsulated within iron oxide nanoparticles coated with calix[8]arene valeric acid complexes

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6634-6642
DOI: 10.1039/C4OB01048E, PaperSerkan Sayin, Enise Akoz, Mustafa Yilmaz
In this study, two types of nanoparticles have been used as additives for the encapsulation of Candida rugosa lipase via the sol-gel method.
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An acridinium-based sensor as a fluorescent photoinduced electron transfer probe for proton detection modulated by anionic micelles

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6677-6683
DOI: 10.1039/C4OB00559G, PaperStefano Basili, Tiziana Del Giacco, Fausto Elisei, Raimondo Germani
Photoinduced electron transfer has been demonstrated to be the quenching mechanism for the fluorescent pH sensor based on the 9-amino-10-methylacridinium chromophore. The presence of anionic micelles causes a significant increase in the detection sensitivity of pH.
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SN2 regioselectivity in the esterification of 5- and 7-membered azacycloalkane quaternary salts: a DFT study to reveal the transition state ring conformation prevailing over the ground state ring strain

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6717-6724
DOI: 10.1039/C4OB00695J, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Akihiro Kimura, Susumu Kawauchi, Takuya Yamamoto, Yasuyuki Tezuka
SN2 regioselectivity in 5- and 7-membered azacycloalkanes quaternary salts is directed by the transition state ring conformation.
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Synthesis and evaluation of antineurotoxicity properties of an amyloid-[small beta] peptide targeting ligand containing a triamino acid

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6684-6693
DOI: 10.1039/C4OB00959B, PaperDmytro Honcharenko, Partha Pratim Bose, Jyotirmoy Maity, Firoz Roshan Kurudenkandy, Alok Juneja, Erik Floistrup, Henrik Biverstal, Jan Johansson, Lennart Nilsson, Andre Fisahn, Roger Stromberg
A new triamino acid enables synthesis of an amyloid-[small beta] peptide (A[small beta]) targeting ligand with additional A[small beta]-ligand interactions that gives protection towards A[small beta]-induced reduction of gamma oscillations in hippocampal slice preparation.
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Azabicycles construction: the transannular ring contraction with N-protected nucleophiles

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6570-6579
DOI: 10.1039/C4OB01311E, Review ArticleAntonio Rizzo, Syuzanna R. Harutyunyan
Synthetic strategies are one of the most critical factors for the success of a synthetic campaign, but most importantly they are crucial for the economy and the efficiency of the sequence.
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Convenient access to readily soluble symmetrical dialkyl-substituted [small alpha]-oligofurans

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6661-6671
DOI: 10.1039/C4OB00898G, PaperEdward E. Korshin, Gregory M. Leitus, Michael Bendikov
A combination of heteroatom directed lithiation/CuCl2-induced homocoupling, Wittig olefination/Pd-catalyzed transfer hydrogenation followed by Suzuki-Miyaura or Stille cross-coupling enables convenient access to dialkyl-substituted [small alpha]-oligofurans of potential interest for organic electronics.
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Synthesis of methyl 2-cyano-3,12-dioxo-18[small beta]-olean-1,9(11)-dien-30-oate analogues to determine the active groups for inhibiting cell growth and inducing apoptosis in leukemia cells

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6706-6716
DOI: 10.1039/C4OB00703D, PaperXiaojing Li, Yuetong Wang, Yuan Gao, Lei Li, Xin Guo, Dan Liu, Yongkui Jing, Linxiang Zhao
A series of CDODO-Me-12 analogues were synthesized with improved ability to inhibit cell growth and induce apoptosis in HL-60 cells.
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Desilylative activation of TMSCN in chemoselective Strecker-Ugi type reaction: functional fused imidazoles as building blocks as an entry route to annulated purines

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6694-6705
DOI: 10.1039/C4OB00882K, PaperSankar K. Guchhait, Vikas Chaudhary
Nucleophilic activation of TMSCN as an isocyanide equivalent by DABCO-THF in the Strecker-Ugi reaction facilitates the synthesis of functional imidazoles which, as building blocks, afford access to C8-N9 annulated purines.
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Catalyst-free activation of methylene chloride and alkynes by amines in a three-component coupling reaction to synthesize propargylamines

Org. and Biomol. Chem. - 12 August, 2014 - 15:17

Org. Biomol. Chem., 2014, 12,6725-6729
DOI: 10.1039/C4OB00986J, PaperVikas S. Rawat, Thulasiram Bathini, S. Govardan, Bojja Sreedhar
Propargylamines are synthesized via metal-free activation of the C-halogen bond of dihalomethanes and the C-H bond of terminal alkynes in a three-component coupling without catalyst or additional base and under mild reaction conditions.
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