Royal Society of Chemistry

Assembling Anionic Sb(V)/(III) containing polyoxostibonates stabilized by triphenyltellurium cations

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03319A, PaperBaskar Viswanathan, Nagarjuna Kumar Srungavruksham
Reactions of diphenyltellurium oxide with organostibonic acid and polymeric triphenylantimony oxide have been investigated independently. Single crystal X-ray diffraction studies have revealed the formation of novel and rare mixed valent...
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A study on the formation of the nitro radical anion by ornidazole and its significant decrease in a structurally characterized binuclear Cu(II)-complex: impact in biology

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03362K, PaperSaurabh Das, Ramesh Chandra Santra, Durba Ganguly, Jyotsna Singh, Kasturi Mukhopadhyay
An acetate bridged binuclear Cu(II) complex of the antiparasitic drug ornidazole was synthesized and characterized by different techniques. Structure of the complex determined by single crystal X-ray diffraction was found...
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Sustainable Synthetic Route for [gamma]-Fe2O3/C Hybrid as Anode Material for Lithium-ion batteries

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03278K, PaperFurong Qin, Kai Zhang, Liyuan Zhang, Jie Li, Hai Lu, Yanqing Lai, Zhian Zhang, Yaming Zhou, Yiwei Li, Jing Fang
A facile, high-yield and sustainable method is developed to synthesize iron oxide/C hybrids. Starch is chosen as the carbon source due to its superior gelatinization property and natural abundance, and...
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Structure and water exchange of hydrated oxo halo ions in aqueous solution using QMCF MD simulation, large angle X-ray scattering and EXAFS

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02580F, PaperLars Eklund, Thomas Hofer, Ingmar Persson
Theoretical ab initio quantum mechanical charge field molecular dynamics (QMCF MD) has been applied in conjunction with experimental large angle X-ray scattering (LAXS) and EXAFS measurements to study structure and...
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A Robust Microporous Metal-Organic Framework as a Highly Selective and Sensitive, Instantaneous and Colorimetric Sensor for Eu3+ Ions

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02752C, Paperyanfei gao, Xueqiong Zhang, Wei Sun, Zhiliang Liu
An extremely thermostable magnesium metal-organic framework (Mg-MOF) is reported for use as a highly selective and sensitive, instantaneous and colorimetric sensor for Eu3+ ions. There has been extensive interest in...
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Valence tautomeric dinuclear adducts of Co(II) diketonates with redox-active diquinones for the design of spin qubits: computational modeling

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03053B, PaperVladimir I. Minkin, Alyona A. Starikova, Andrey Starikov
A possibility to employ the mechanism of the intramolecular electron transfers between metal and ligand centers in the valence tautomeric complexes formed as the electrically neutral 2:1 adducts of Co(II)...
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Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

Dalton Transactions - 2 December, 2014 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT03184A, CommunicationDavid J. Harding, Wasinee Phonsri, Phimphaka Harding, Keith S. Murray, Boujemaa Moubaraki, Guy N. L. Jameson
A rare iron(III) symmetry breaking spin crossover compound with an extremely wide [LS-HS] plateau is reported.
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Two Chelating-Amino-Functionalized Lanthanide Metal-Organic Frameworks for Adsorption and Catalysis

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02048K, PaperYu Zhu, Yanmei Wang, Pan Liu, Changkun Xia, Yunlong Wu, Xiaoqing Lu, Jimin Xie
Two chelating-amino-functionalized lanthanide metal-organic frameworks, Er-DADQ and Eu-DADQ, were synthesized with a flexible dicarboxylate ligand based on quinoxaline (H2DADQ = N, N'-dibenzoic acid-2, 3-diaminoquinoxaline). N2 adsorption indicates they exhibits stable...
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Four tetrazolate-based 3D frameworks with diverse subunits directed by inorganic anions and azido coligand: hydrothermal syntheses, crystal structures, and magnetic properties

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03172E, PaperZhao-Jun Hou, Zhong-Yi Liu, Ning Liu, En-Cui Yang, Xiao-Jun Zhao
Four tetrazolate (tz-)-based magnetic metal-organic frameworks, [Cu5([small mu ]3-OH)2(SO4)2(tz)4]n (1), {[Cu3(tz)4Cl2][round bullet, filled]2H2O}n (2), [Cu(N3)(tz)]n (3), and {[Cu5(tz)9]Cl[round bullet, filled]8H2O}n (4), were solvo/hydrothermally synthesized, and structurally and magnetically characterized. Structural analyses reveal that the former two...
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3,3[prime or minute]-Di(pyrazinamoyl)-2,2[prime or minute]-bipyridine: Rational ligand design for the self-assembly of a 1-D coordination polymer

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03220A, PaperNicholas J Hurley, Jeremy Michael Rawson, Melanie Pilkington
This is an Accepted Manuscript, which has been through the RSC Publishing peer review process and has been accepted for publication. Accepted manuscripts are published online shortly after acceptance. This version of the article will be replaced by the fully edited, formatted and proof read Advance Article as soon as this is available.
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Bis-Mixed-Carbene Ruthenium-Thiolate-Alkylidene Complexes: Synthesis and Olefin Metathesis Activity

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03137G, PaperFatme Dahcheh, Douglas W Stephan
series of bis-carbene Ru-hydride species, including (IMes)(Im(OMe)2)(PPh3)RuHCl (1) and (SIMes)(Me2Im(OMe)2)(PPh3)RuHCl (2) were prepared and subsequently shown to react with aryl vinyl-sulfides to give the bis-carbene-alkylidene complexes: Im(OMe)2(SIMes)RuCl(SR)(=CHCH3) (R = p­FC6H4...
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Cyclometallated platinum(II) complexes containing NHC ligands; synthesis, characterization, photophysics and their application as emitters in OLEDs.

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03106G, PaperAnastasia I. Solomatina, Dmitry Krupenya, Vladislav V. Gurzhiy, Ilya Zlatkin, Anatoly P Pushkarev, Mikhail N Bochkarev, Nicholas Alan Besley, Elena Bichoutskaia, Sergey P Tunik
A series of square planar [Pt(N^C)(NHC)L] complexes containing cyclometallated N^C ligands (phenylpyridine and benzoquinoline) and N-heterocyclic carbene (NHC): N^C = 2-phenylpyridine, 7,8-benzoquinoline; NHC= 1,3-dibenzylbenzimidazolium, 1,3-diethylbenzimidazolium, 1,3-dibenzylimidazolium; L = Cl, Br,...
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Synthesis, structure, magnetic properties and EPR spectroscopy ‎of a copper(II) coordination polymer with ditopic hydrazone ‎ligand and acetate bridges

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03060E, PaperRahman Bikas, Pavlo Aleshkevych, Hassan Hosseini-Monfared, Joaquin Sanchiz, Ritta Szymczak, Tadeusz Lis
A new one dimensional coordination polymer of copper(II), [Cu4(L)2([small mu ]2-1,1-OAc)2([small mu ]2-1,3-OAc)4]n ‎‎(1), has been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis ‎‎[HL = (E)-N'-(phenyl(pyridin-2-yl)methylene)isonicotinhydrazide, OAc = acetate anion]....
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A fluoride bridged {CrIII4DyIII4} single molecule magnet

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03100H, CommunicationKeith S. Murray, Stuart Langley, Boujemaa Moubaraki, Craig M Forsyth
The synthesis of a heterometallic octanuclear {CrIII4DyIII4} complex containing fluoride bridges displays SMM behaviour, with highly coercive magnetic hysteresis loops. Intriguingly multiple relaxation processes are revealed and the relaxation times...
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Synthesis of Aromatic Functionalized Cage-Rearranged Silsesquioxanes (T8, T10, and T12) via Nucleophilic Substitution Reactions

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02941K, CommunicationSupansa Chimjarn, Rungthip Kunthom, Prapassorn Chancharone, Rapheepraew Sodkhomkhum, Preeyanuch Sangtrirutnugul, Vuthichai Ervithayasuporn
Organic-inorganic hybrid nano-building blocks of aromatic nitro-, aldehyde-, and bromo-functionalized polyhedral oligomeric silsesquioxanes were easily prepared through nucleophilic substitutions, starting from the reactions between octakis(3-chloropropyl)octasilsesquioxane and phenoxide derivatives. These phenoxide...
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Novel Ce3+ activated Lu3MgAl3SiO12 garnet phosphor for blue chip light-emitting diodes with excellent performance

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03144J, PaperYurong Shi, Ge Zhu, Mikami Masayoshi, Yasuo Shimomura, Yuhua Wang
A novel Ce3+ activated Lu3MgAl3SiO12:Ce phosphor was synthesized and found to crystallize in the garnet structure. The crystal structure of synthesized phosphors has been characterised by X-ray diffraction and refined...
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Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand

Dalton Transactions - 2 December, 2014 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02727B, PaperT. C. Davenport, T. D. Tilley
A series of "diamond-core" bridged dinuclear first-row transition metal complexes with the dinucleating ligand DPFN are prepared and characterized.
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P,C-bond cleavage in the ligand sphere of a nickel(II) complex

Dalton Transactions - 2 December, 2014 - 06:17

Dalton Trans., 2015, Advance Article
DOI: 10.1039/C4DT02158D, PaperOpen Access Open Access Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Simon P. Walg, Alexandra D. Schmidt, Marcus Schmitz, Saeid Farsadpour, Johannes Lang, Mark Niebergall, Yu Sun, Peter W. Roesky, Gereon Niedner-Schatteburg, Werner R. Thiel
P,C-bond cleavage at a pyrimidinyl ligand results in a pentacoordinate nickel(II) complex coordinated by a carbanionic ligand.
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Assembly of a M4L4 "folded-cube" using a T-shaped, right-angled ligand

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03198A, CommunicationIsmail Elguraish, Kelong Zhu, Leslie A Hernandez, Hazem Amarne, Jingwei Luo, Nicholas V Vukotic, Stephen J Loeb
A new pyridine ligand based on a T-shaped 2,4,7 trisubstituted benzimidazole framework was synthesized with a 90o angle between the two nitrogen donors. When combined with convergent [Pt(dppp)]2+ corners, eight...
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Ferromagnetic Ordering in the Radical Cation Salt BBDTA[round bullet, filled]Au(CN)2 at 8.2 K

Dalton Transactions - 2 December, 2014 - 06:17
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03208J, CommunicationWataru Fujita
An organic radical cation salt, BBDTA[round bullet, filled]Au(CN)2, with a slipped [small pi]-stacking columnar structure and intercolumnar short contacts, shows ferromagnetic ordering at 8.2 K, the highest reported temperature among the BBDTA+ cation...
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