Royal Society of Chemistry

Hierarchy in inorganic membranes

Chem. Soc. Rev. - 12 November, 2015 - 04:17

Chem. Soc. Rev., 2015, Advance Article
DOI: 10.1039/C5CS00597C, Review ArticleJuergen Caro
Inorganic membranes usually possess an unsymmetrical cross section showing a hierarchical structure: the ZIF-8 separation layer is deposited on a graded titania support.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Nano-ellipsoids at fluid-fluid interface: effect of surface charge on adsorption, buckling and emulsification

Faraday Disc. - 12 November, 2015 - 02:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00136F, PaperVenkateshwarrao Dugyala, Anjali Thiriveni, Upendar Siliveru, Ethayaraja Mani, Madivala G Basavaraj
In this contribution, we discuss the role of surface charge on the adsorption of shape anisotropic particles to fluid-fluid interfaces in the context of their application in particle-stabilized emulsions. Starting...
The content of this RSS Feed (c) The Royal Society of Chemistry

FDASSEMBLY Chiral Self-assembly of Helical Particles

Faraday Disc. - 12 November, 2015 - 02:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00132C, PaperHima Bindu Kolli, Giorgio Cinacchi, Alberta Ferrarini, Achille Giacometti
The shape of the building blocks plays a crucial role in directing self-assembly towards desired architectures. Out of the many different shapes, helix has a unique position. Helical structures are...
The content of this RSS Feed (c) The Royal Society of Chemistry

Large-scale dynamic assembly of metal nanostructures in plasmofluidic field

Faraday Disc. - 12 November, 2015 - 02:17
Faraday Discuss., 2015, Accepted Manuscript
DOI: 10.1039/C5FD00127G, PaperPartha Pratim Patra, Rohit Chikkaraddy, Sreeja Thampi, Ravi Tripathi, G.V. Pavan Kumar
We discuss two aspects of plasmofluidic assembly of plasmonic nanostructures at metal-fluid interface. First, we experimentally show how triple and four spots evanescent-wave excitation can lead to unconventional assembly of...
The content of this RSS Feed (c) The Royal Society of Chemistry

Regioselective modification of unprotected glycosides

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08199H, Feature ArticleAdriaan J Minnaard, Manuel Jager
Selective modification of unprotected carbohydrates is difficult due to the similar reactivity of the hydroxyl groups. In carbohydrate synthesis, therefore, even straightforward transformations often require multiple synthetic steps. The development...
The content of this RSS Feed (c) The Royal Society of Chemistry

Ternary NiFeMn Layered Double Hydroxides as High-efficient Oxygen Evolution Catalysts

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08845C, CommunicationZhiyi Lu, Li Qian, Yang Tian, Yaping Li, Xiaoming Sun, Xue Duan
Layered double hydroxides (LDHs) are a family of layer materials with heightened attention. Herein a ternay NiFeMn-LDH is investigated with superior oxygen evolution activity, which is attributed to the Mn4+...
The content of this RSS Feed (c) The Royal Society of Chemistry

Azeotropic drying free [18F]FDG synthesis and its application to a lab-on-chip platform

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07106B, CommunicationSimon Lindner, Christian Rensch, Stephanie Neubaur, Manuela Neumeier, Ruben Salvamoser, Victor Samper, Peter Bartenstein
A very simple and time-saving cartridge-based drying technique for [18F]fluoride allows for an efficient [18F]FDG synthesis using protic solvents and high water content. This novel method has been adapted to...
The content of this RSS Feed (c) The Royal Society of Chemistry

Turning the Heat on Conjugated Polyelectrolytes: An Off-On Ratiometric Nanothermometer

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08541A, CommunicationGhinwa Hassan Darwish, Ali Koubeissi, Tharallah Shoker, Samir Abou Shaheen, Pierre Karam
We report a self-referenced ratiometric nanothermometer based on short conjugated polyelectrolytes (CPEs). An amphiphilic macromolecule destabilizes the polymer [small pi]-[small pi] stacking and makes it possible to shift the equilibrium between the...
The content of this RSS Feed (c) The Royal Society of Chemistry

A Strategy for Enhanced Antibacterial Activity against Staphylococus aureus by Assembly of Alamethicin with Thermo-Sensitive Polymeric Carrier

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07054F, CommunicationPing Dong, Yuan Zhou, Weiwei He, Daoben Hua
We demonstrate here a strategy for enhanced antibacterial activity against microbial strains by assembly of antimicrobial peptides with temperature-responsive polymeric carrier. The assembly complex was less toxic to human cells...
The content of this RSS Feed (c) The Royal Society of Chemistry

Dual Selective Iron Chelating Probes with a Potential to Monitor Mitochondrial Labile Iron Pools

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC06170A, CommunicationVincenzo Abbate, Olivier Reelfs, Xiaole Kong, Charareh Pourzand, Robert Hider
Mitochondria-targeted peptides incorporating dual fluorescent and selective iron chelators have been designed as novel biosensors for the mitochondrial labile iron pool. The probes were demonstrated to specifically co-localize with mitochondria...
The content of this RSS Feed (c) The Royal Society of Chemistry

Hierarchically porous anatase TiO2 coated-WO3 2D IO bilayer film and photochromic properties

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08795C, CommunicationHua Li, Huazhong Wu, Jiajia Xiao, Yanli Su, Jacques Robichaud, Ralf Bruening, Yahia Djaoued
A hierarchically porous anatase TiO2 coated-WO3 2D inverse opal (IO) bilayer film was fabricated on ITO glass using a layer by layer route with a hierarchically porous TiO2 top layer...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis, structure and bonding of hexaphenyl thorium(IV): Observation of a non-octahedral structure

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08265J, CommunicationEllizabeth Pedrick, Peter Hrobarik, Lani A Seaman, Guang Wu, Trevor W. Hayton
We report herein the synthesis of first homoleptic, 6-coordinate actinide aryl complexes, [Li(DME)3]2[Th(C6H5)6] (1) and [Li(12-crown-4)(THF)]2[Th(C6H5)6] (2), which feature an anion possessing a regular octahedral (1) or a severely distorted...
The content of this RSS Feed (c) The Royal Society of Chemistry

Chemo- and Regioselective Reductive Transposition of Allylic Alcohol Derivatives via Iridium or Rhodium Catalysis

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07993D, CommunicationRylan Lundgren, Bryce N Thomas
The selective, catalytic deoxygenation of alcohols remains a persistent challenge in organic synthesis. Pd-catalyzed formate reduction and diazene-mediated reductive transposition are both valuable strategies for the selective deoxygenation of allylic...
The content of this RSS Feed (c) The Royal Society of Chemistry

A Singlet Oxygen Photosensitizer Enables Photoluminescent Monitoring of Singlet Oxygen Doses

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08411C, CommunicationYoungmin You, Eun Jin Cho, Hyeokseon Kwon, Jieun Hwang, Seung Eun Lee
A molecular dyad that can photosensitize and visualize singlet oxygen (1O2) was developed. The dual photofunction enables ratiometric photoluminescence monitoring of the progress of 1O2-induced cell death.
The content of this RSS Feed (c) The Royal Society of Chemistry

Rearrangement of {[small alpha]-P2W15} to {PW6} Moieties during the Assembly of Transition-Metal-Linked Polyoxometalate Clusters

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08486E, CommunicationLee Cronin, Merce Martin-Sabi, Ross S Winter, Claire Lydon, Jamie Cameron, Deliang Long
We report the formation of two polyoxotungstates of the general formula [M6(PW6O26)([small alpha]-P2W15O56)2(H2O)2]23- (M = CoII or MnII), which contain {PW6} fragments generated from the {P2W15O56]12- precursor and show for the...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis of highly white-fluorescent Cu-Ga-S quantum dots for solid-state lighting device

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC07968C, CommunicationDae-Yeon Jo, Heesun Yang
Synthesis of highly efficient, white-emitting Cu-Ga-S quantum dots (QDs), which possess not only a sufficiently wide spectral coverage of blue-to-red but an exceptional quantum yield as high as 75% is...
The content of this RSS Feed (c) The Royal Society of Chemistry

Elucidation of the resting state of a rhodium NNN-pincer hydrogenation catalyst that features a remarkably upfield hydride 1H NMR chemical shift

Chem. Commun. - 11 November, 2015 - 11:54

Chem. Commun., 2015, Advance Article
DOI: 10.1039/C5CC08348F, CommunicationMikko M. Hanninen, Matthew T. Zamora, Connor S. MacNeil, Jackson P. Knott, Paul G. Hayes
Rhodium(I) alkene complexes of an NNN-pincer ligand catalyze the hydrogenation of alkenes. The terminal or resting state of the catalyst, which exhibits an unusually upfield Rh-hydride 1H NMR chemical shift, has been identified.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis of Sterically Hindered Amines by Direct Reductive Amination of Ketones

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08577B, CommunicationNiyaz Z Yagafarov, Pavel N Kolesnikov, Dmitry Usanov, Valentin V Novikov, Yulia V. Nelyubina, Denis Chusov
An atom-economical methodology for the synthesis of sterically hindered tertiary amines was developed, which is based on complementary Rh- and Ru-catalyzed direct reductive amination of ketones with primary and secondary...
The content of this RSS Feed (c) The Royal Society of Chemistry

Synthesis and biological evaluation of a kabiramide C fragment modified with a WH2 consensus actin-binding motif as potential disruptor of the actin cytoskeleton

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC06081H, CommunicationDaniel Tetlow, Steve Winder, Christophe Aissa
The F-actin depolymerisation potency of a fragment of kabiramide C was increased when modified with a WH2 consensus actin-binding motif LKKV. Despite its low affinity for actin monomers, a shorter...
The content of this RSS Feed (c) The Royal Society of Chemistry

Mesoionic bis(Py-tzNHC) Palladium(II) Complex Catalyses "Green" Sonogashira Reaction Through an Unprecedented Mechanism

Chem. Commun. - 11 November, 2015 - 11:54
Chem. Commun., 2015, Accepted Manuscript
DOI: 10.1039/C5CC08717A, CommunicationMartin Gazvoda, Miha Virant, Andrej Pevec, Damijana Urankar, Aljosa Bolje, Marijan KOCEVAR, Janez Kosmrlj
Novel bis(pyridyl-functionalized 1,2,3-triazol-5-ylidene)-palladium(II) complex [Pd(Py-tzNHC)2]2+ catalyses copper-, amine-, phosphine-, and additive-free aerobic Sonogashira alkynylation of (hetero)aryl bromides in water as the only reaction solvent. The catalysis proceeds along two connected...
The content of this RSS Feed (c) The Royal Society of Chemistry

WebElements: the periodic table on the WWW [http://www.webelements.com/]

Copyright 1993-2015 Mark Winter [The University of Sheffield and WebElements Ltd, UK]. All rights reserved.