Royal Society of Chemistry

[Me2C{SnCH(SiMe3)2}2]2. A [small mu ]-Me2C-bridged tetrastanna tetrahedrane

Chem. Commun. - 5 December, 2014 - 01:17

Chem. Commun., 2015, 51,153-156
DOI: 10.1039/C4CC07417C, CommunicationMichael Wagner, Michael Lutter, Bernhard Zobel, Wolf Hiller, Marc H. Prosenc, Klaus Jurkschat
A spacer-bridged bis(organostannylene) was obtained adopting the structure of a doubly capped tetrahedron in the solid state. Its reaction with elemental oxygen provided organotin suboxides.
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Dithiafulvenyl-grafted phenylene ethynylene polymers as selective and reversible dispersants for single-walled carbon nanotubes

Chem. Commun. - 5 December, 2014 - 01:17

Chem. Commun., 2015, 51,149-152
DOI: 10.1039/C4CC07239A, CommunicationKarimulla Mulla, Shuai Liang, Haseena Shaik, Eyad A. Younes, Alex Adronov, Yuming Zhao
Phenylene ethynylene-based [small pi]-conjugated polymers grafted with dithiafulvenyl groups on their side chains were found to be efficient in dispersing single-walled carbon nanotubes in a selective and controllable way.
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Phosphine complexes of lone pair bearing Lewis acceptors

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,17-29
DOI: 10.1039/C4DT02789B, PerspectiveSaurabh S. Chitnis, Neil Burford
The unique structural outcomes and reactivity modes for phosphine complexes featuring lone-pair bearing acceptors are considered.
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Integrin-targeted delivery into cancer cells of a Pt(IV) pro-drug through conjugation to RGD-containing peptides

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,202-212
DOI: 10.1039/C4DT02710H, PaperAnna Massaguer, Alejandro Gonzalez-Canto, Esther Escribano, Silvia Barrabes, Gerard Artigas, Virtudes Moreno, Vicente Marchan
Conjugation of a Pt(IV) pro-drug derivative of picoplatin to a tetrameric RGD-containing peptide leads to selective accumulation and antitumor activity in cancer cells overexpressing [small alpha]V[small beta]3 and [small alpha]V[small beta]5 integrins.
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A luminescent cadmium metal-organic framework for sensing of nitroaromatic explosives

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,230-236
DOI: 10.1039/C4DT02227K, PaperChuanqi Zhang, Libo Sun, Yan Yan, Jiyang Li, Xiaowei Song, Yunling Liu, Zhiqiang Liang
A novel metal-organic framework 1 was synthesized using a new rigid unsymmetrical tricarboxylate ligand p-terphenyl-3,4[prime or minute][prime or minute],5 tricarboxylate (H3TPT). The micrometer-sized material 1[prime or minute] dispersed in ethanol exhibits high efficiency for the detection of PA.
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Five 8-hydroxyquinolinate-based coordination polymers with tunable structures and photoluminescent properties for sensing nitroaromatics

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,401-410
DOI: 10.1039/C4DT02897J, PaperLiyan Zhang, Liying Sun, Xinyuan Li, Yulan Tian, Guozan Yuan
Five coordination polymers with different structures have been prepared. The tunable structures and photoluminescent properties for sensing nitroaromatics in five polymers were observed.
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A conformationally stressed novel ball-type perylenediimide appended zinc(II)phthalocyanine hybrid: spectroelectrochemical, electrocolorimetric and photovoltaic properties

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,158-166
DOI: 10.1039/C4DT01761G, PaperFatih Pekdemir, Sertan Kurnal[i without dot], Abdurrahman Sengul, Ahmet Alt[i without dot]ndal, Ali R[i without dot]za Ozkaya, Bekir Salih, Ozer Bekaroglu
The ZnPc-perylenediimide hybrid displayed a well-defined electrochromic behaviour and the best photovoltaic conversion efficiency observed with a Pc-based organic solar cell.
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Epitaxial growth of silver chloride crystals on bismuth oxychloride

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,176-181
DOI: 10.1039/C4DT02666G, PaperBoris B. Bokhonov
AgCl crystals precipitating on the surface of bismuth oxychloride crystals show orientation ordering with the (001)BiOCl||(100)AgCl.
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Solvent effect-driven assembly of W/Cu/S cluster-based coordination polymers from the cluster precursor [Et4N][Tp*WS3(CuBr)3] and CuCN: isolation, structures and enhanced NLO responses

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,130-137
DOI: 10.1039/C4DT02725F, PaperQuan Liu, Zhi-Gang Ren, Li Deng, Wen-Hua Zhang, Xin Zhao, Zhen-Rong Sun, Jian-Ping Lang
Solvent modulation of a W/Cu/S cluster and CuCN reaction system provides coordination polymers with enhanced nonlinear optical performances.
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Synthesis of discrete Re(I) di- and tricarbonyl assemblies using a [4 [times] 1] directional bonding strategy

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,41-45
DOI: 10.1039/C4DT03077J, CommunicationBaptiste Laramee-Milette, Christophe Lachance-Brais, Garry S. Hanan
Discrete assembly of two Re(I) squares was achieved by a simple [4 [times] 1] strategy where the complexes, [Re(4-pytpy-[small kappa]2N)(CO)3Br] and [Re(4-pytpy-[small kappa]3N)(CO)2Br], act as their own ligands. The properties of the assemblies and their precursors are described along with solid-state X-ray diffraction studies.
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The first investigation of the synthetic mechanism and lithium intercalation chemistry of Li9Fe3(P2O7)3(PO4)2/C as cathode material for lithium ion batteries

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,138-145
DOI: 10.1039/C4DT02498B, PaperHe Gao, Sen Zhang, Chao Deng
Li9Fe3(P2O7)3(PO4)2 with mixed-polyanion groups is introduced as a novel cathode material for Li-ion batteries.
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High nitrogen-doped carbon/Mn3O4 hybrids synthesized from nitrogen-rich coordination polymer particles as supercapacitor electrodes

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,151-157
DOI: 10.1039/C4DT02456G, PaperKuaibing Wang, Xiaobo Shi, Aiming Lu, Xiaoyan Ma, Zhiyang Zhang, Yanan Lu, Hongju Wang
High N-doped C/Mn3O4 composites are charged and discharged faster and have higher capacitance than C/Mn3O4 nanostructures with low N-amounts with 96% retained capacitance after 500 cycles at a constant current.
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TQPHEN (N,N,N[prime or minute],N[prime or minute]-tetrakis(2-quinolylmethyl)-1,2-phenylenediamine) derivatives as highly selective fluorescent probes for Cd2+

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,104-109
DOI: 10.1039/C4DT02177K, PaperYuji Mikata, Asako Kizu, Hideo Konno
The tetrakisquinoline derivatives with a 1,2-phenylenediamine (PHEN) scaffold exhibit a Cd2+-specific fluorescence enhancement, in contrast to the Zn2+-specific trans-1,2-diaminocyclohexane (DACH) counterpart.
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New heterometallic Ir(III)2-Eu(III) complexes: white light emission from a single molecule

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,37-40
DOI: 10.1039/C4DT01910E, CommunicationAndrea Baschieri, Sara Muzzioli, Elia Matteucci, Stefano Stagni, Massimiliano Massi, Letizia Sambri
Pure white light emission from a single-molecule Ir2(III)-Eu(III) complex can be achieved with appropriate ligands.
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New Heteroleptic Magnesium Complexes for MgO Thin Film Applications

Dalton Transactions - 4 December, 2014 - 06:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03497J, PaperHyo-Suk Kim, Sheby Mary George, Bo Keun Park, Seung Uk Son, Chang Kim, Taek-Mo Chung
Novel heteroleptic magnesium complexes, [Mg(dmamp)(acac)]2 (1), [Mg(dmamp)(tmhd)]2 (2), [Mg(dmamp)(hfac)]x (3), and [Mg(dmamp)(tfac)]x (4), were successfully synthesized using dmamp and [small beta]-diketonate as ligands. The thermogravimetric analyses and volatile studies of the...
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Black and Yellow Anatase Titania Formed by (H,N)-doping: Strong Visible-light Absorption and Enhanced Visible-light photocatalysis

Dalton Transactions - 4 December, 2014 - 06:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02984D, CommunicationShunhang Wei, R. Wu, jikang jian, Fengjuan Chen, Yanfei Sun
Instead of participation of hydrogen gas, we produce black and yellow anatase TiO2 doped with hydrogen and nitrogen elements using tetrabutyl titanate as titanium precursor and annealing in N2/Ar/air atmosphere....
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Grafting {Cp*Rh}2+ on the surface of Nb and Ta Lindqvist-type POM

Dalton Transactions - 4 December, 2014 - 06:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT03339F, PaperPavel A Abramov, Maksim Nailyevich Sokolov, Emmanuel Cadot, Sebastien Floquet, Mohamed Haouas, Francis Taulelle, Cristian Vicent, Vladimir P Fedin, Aleksandr Viktorovich Virovets
New hybrid POM based on Lindqvist-type polyoxometalates [M6O19]8- (M = Nb, Ta) and organometallic fragment {Cp*Rh}2+ have been isolated and characterized. X-ray quality crystals of K4[(Cp*Rh)2Nb6O19][round bullet, filled]20H2O (1) and Cs4[(Cp*Rh)2Ta6O19][round bullet, filled]18H2O (2)...
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Anion complexation, transport and structural studies of a series of bis-methylurea compounds

Dalton Transactions - 4 December, 2014 - 06:54
Dalton Trans., 2014, Accepted Manuscript
DOI: 10.1039/C4DT02893G, PaperClaudia Caltagirone, Riccardo Montis, Martina Olivari, Louise E. Karagiannidis, Simon Coles, Peter Horton, Mark E. Light, Lucy K Mapp, Philip A Gale
A new family of bis-methylureas (L1-L6) have been synthesised and their ability to bind anions both in solution and in the solid state and to transport them through lipid membrane...
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Encapsulation and stabilization of polyoxometalates in self-assembled supramolecular hydrogels

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,58-61
DOI: 10.1039/C4DT01372G, CommunicationVamangi M. Pandya, Ulrich Kortz, Sachin A. Joshi
Polyoxometalate assisted pH dependent self-assembled hydrogel formation.
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Synthesis and photoelectric properties of new Dawson-type polyoxometalate-based dimeric and oligomeric Pt(II)-acetylide inorganic-organic hybrids

Dalton Transactions - 4 December, 2014 - 06:54

Dalton Trans., 2015, 44,306-315
DOI: 10.1039/C4DT02504K, PaperLi Liu, Lei Hu, Qian Liu, Zu-Liang Du, Fa-Bao Li, Guang-Hua Li, Xun-Jin Zhu, Wai-Yeung Wong, Lei Wang, Hua Li
New polyoxometalate-based Pt(II)-acetylide hybrids were prepared and their photoelectric properties as hybrid LB films were studied.
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